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Physical Sciences and Mathematics Commons

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Chemistry

The University of Southern Mississippi

Theses/Dissertations

2011

High explosives

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Sensitive Detection Of High Explosives Using Electrogenerated Chemiluminescence, Suman Parajuli May 2011

Sensitive Detection Of High Explosives Using Electrogenerated Chemiluminescence, Suman Parajuli

Dissertations

The core of this dissertation lies in the search of analytical tools which can be used to detect and quantify the high explosives confiscated from suspects in transportation hubs and from soil and water bodies where these explosives pose a greater threat to public health and safety. High explosives, namely, hexamethylene triperoxide diamine (HMTD), triacetone triperoxide (TATP), trinitrotoluene (TNT), and pentaerythritol tetranitrate (PETN), were detected and quantified by electrochemical methods such as electrogenerated chemiluminescence (ECL) and cyclic voltammetry (CV).

Sensitive detection and quantification of HMTD, one commonly used explosive by terrorists, was presented first in this dissertation on the basis …