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Physical Sciences and Mathematics Commons

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Chemistry

The University of Southern Mississippi

Theses/Dissertations

2008

Cationic poly(vinylpyridinium hydrochloride) polymers

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Full-Text Articles in Physical Sciences and Mathematics

Investigation Of The Interactions Of Cationic Polyelectrolytes With Anionic Surfactants: Effects Of Polymer, Surfactant And Solution Properties, Lisa Renee Huisinga Dec 2008

Investigation Of The Interactions Of Cationic Polyelectrolytes With Anionic Surfactants: Effects Of Polymer, Surfactant And Solution Properties, Lisa Renee Huisinga

Dissertations

The intent of this research is to explore and understand the effects that a range of polymer, surfactant and solution parameters have on the interaction of oppositely-charged polymers and surfactants. Cationic polysaccharides were chosen for this research because they are known to interact with anionic surfactants, and they offer a wide range of adjustable polymer properties, including molecular weight, charge substitution, and backbone structure. Cationic poly(vinylpyridinium hydrochloride) polymers were chosen for these studies because they provide the opportunity to explore the effects of charge position on the interaction of cationic polymers with anionic surfactants and how this influences the mechanism …