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Chemistry

The University of Maine

Theses/Dissertations

Extraction chemistry

Publication Year

Articles 1 - 3 of 3

Full-Text Articles in Physical Sciences and Mathematics

The Removal Of Wood Components From Hardwood By Hot Water, Rory Jara Dec 2010

The Removal Of Wood Components From Hardwood By Hot Water, Rory Jara

Electronic Theses and Dissertations

Hot-water extraction of hemicelluloses from wood is a promising technology in the integrated biorefmery concept. A particular case is where the pulp industry makes co-products such as ethanol and acetic acid besides pulp thereby maximizing the value of biomass. Similarly, the oriented strand board (OSB) industry appears to be suitable for this technical approach as it is composed of large centralized facilities. Many studies have been carried out on the kinetics and mechanism of hot-water extraction of lignocellulosics. However, most of these studies were performed in batch reactors which are not best suited to determine intrinsic kinetics of hemicellulose dissolution …


Biological Conversion Of Hemicellulose Extract Into Value-Added Fuels And Chemicals, Sara Lynn Walton Dec 2009

Biological Conversion Of Hemicellulose Extract Into Value-Added Fuels And Chemicals, Sara Lynn Walton

Electronic Theses and Dissertations

The research presented in this thesis describes the fermentation of hemicellulose extracts to produce ethanol and lactic acid. Hardwood hemicellulose extracts made at a variety of conditions using the green liquor and hot water extraction processes were characterized and then fermented by Escherichia coli K011 and Bacillus coagulans MXL-9. Hemicellulose extracts were found to contain a dilute amount of xylo-oligosaccharides and acetic acid as the major components, and many minor components including other organic acids, lignin-derived phenolics, and sugar degradation products. In order to generate ethanol economically, the fermentation must produce at least a 4% ethanol solution, which requires a …


Technical Evaluation Of Hardwood Biorefinery Using The "Near-Neutral" Hemicellulose Extraction Process, Haibo Mao Dec 2007

Technical Evaluation Of Hardwood Biorefinery Using The "Near-Neutral" Hemicellulose Extraction Process, Haibo Mao

Electronic Theses and Dissertations

A technical analysis was performed for a new process that produces ethanol and acetic acid from hardwood in addition to bleached hardwood Kraft pulp. The new process, termed the "near neutral" hemicellulose extraction process, involves the extraction of wood hemicellulose using green liquor prior to conventional Kraft pulping. This thesis assumes that the new process is located at an existing kraft pulp mill. Ancillary unit operations in the process include hydrolysis of the extracted carbohydrates using sulfuric acid, filtration of the extract to remove lignin that was extracted with the carbohydrates, liquid-liquid extraction of acetic acid and by-product furfural, liming …