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Biological Conversion Of Hemicellulose Extract Into Value-Added Fuels And Chemicals, Sara Lynn Walton Dec 2009

Biological Conversion Of Hemicellulose Extract Into Value-Added Fuels And Chemicals, Sara Lynn Walton

Electronic Theses and Dissertations

The research presented in this thesis describes the fermentation of hemicellulose extracts to produce ethanol and lactic acid. Hardwood hemicellulose extracts made at a variety of conditions using the green liquor and hot water extraction processes were characterized and then fermented by Escherichia coli K011 and Bacillus coagulans MXL-9. Hemicellulose extracts were found to contain a dilute amount of xylo-oligosaccharides and acetic acid as the major components, and many minor components including other organic acids, lignin-derived phenolics, and sugar degradation products. In order to generate ethanol economically, the fermentation must produce at least a 4% ethanol solution, which requires a …


Room Temperature Tunable Energy Transfer Systems In Different Solvents, Zhonghua Guo Aug 2009

Room Temperature Tunable Energy Transfer Systems In Different Solvents, Zhonghua Guo

Electronic Theses and Dissertations

The focus of this thesis is on d8 and d10 metal-metal interactions, e.g. weak bonding in homometallic and heterometallic systems in liquid solutions, the tunability of luminescent energy due to the variation of metal-metal interaction strength in different solvents and different concentrations, as well as energy transfer from the luminescent energy tunable d8 and d10 metal ions clusters as donor ions to the lanthanide ions as acceptor ions at room temperature. First, energy transfer has been studied between dicyanoaurate(I) luminescent nanocluster donor ions and Eu3+ and Tb3+ acceptor ions in aqueous solutions. The emission …