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Full-Text Articles in Physical Sciences and Mathematics
Synthesis Of Novel Chiral Bisoxazoline Ligands With A Norbornadiene Backbone: Use In The Copper-Catalyzed Enantioselective Henry Reaction, Rabi̇a Deli̇kuş, Emi̇ne Çakir, Nadi̇r Demi̇rel, Meti̇n Balci, Betül Karataş
Synthesis Of Novel Chiral Bisoxazoline Ligands With A Norbornadiene Backbone: Use In The Copper-Catalyzed Enantioselective Henry Reaction, Rabi̇a Deli̇kuş, Emi̇ne Çakir, Nadi̇r Demi̇rel, Meti̇n Balci, Betül Karataş
Turkish Journal of Chemistry
Novel chiral bisoxazoline ligands based on norbornadiene were synthesized and used for the asymmetric Henry reaction. Various aromatic aldehydes were converted into chiral $\beta $-nitro alcohols with high yields and moderate to acceptable enantioselectivities under the optimized reaction conditions.
Analytical Capabilities Of Two-Phase Hollow-Fiber Liquid Phase Microextraction For Trace Multielement Determination In Aqueous Samples By Means Of Portable Total Reflection X-Ray Instrumentation, Eva Margui, Manuela Hidalgo
Analytical Capabilities Of Two-Phase Hollow-Fiber Liquid Phase Microextraction For Trace Multielement Determination In Aqueous Samples By Means Of Portable Total Reflection X-Ray Instrumentation, Eva Margui, Manuela Hidalgo
Turkish Journal of Chemistry
Liquid phase microextraction (LPME) procedures have been widely used in combination with atomic and emission spectroscopic techniques for the isolation and preconcentration of trace elements. However, its application in combination with total reflection X-ray spectrometry (TXRF) is still scarce. In this paper, we evaluate the possibilities and drawbacks of a two-phase hollow fiber LPME procedure in combination with TXRF for the simultaneous determination of trace amounts of Cr, Ni, Cu, Zn, Pb, and Cd in aqueous samples. After extraction of the analytes by using the optimum conditions (sample volume: 25 mL, complexing agent: APDC, organic solvent: hexylbenzene, extraction time: 2 …