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Full-Text Articles in Physical Sciences and Mathematics
Solid Phase Extraction Of Copper(Ii) By Modified Octadecyl Silica Membrane Disks With 3-{2-[2-(2-Hydroxyimino-1-Methyl-Propylideneamino)- Ethylamino]-Ethyl-Imino}-Butan-2-One~Oxime, Ömer Dalman, Serdar Karaböcek, Ahmet Demi̇rak, Mehmet Tüfekçi̇
Solid Phase Extraction Of Copper(Ii) By Modified Octadecyl Silica Membrane Disks With 3-{2-[2-(2-Hydroxyimino-1-Methyl-Propylideneamino)- Ethylamino]-Ethyl-Imino}-Butan-2-One~Oxime, Ömer Dalman, Serdar Karaböcek, Ahmet Demi̇rak, Mehmet Tüfekçi̇
Turkish Journal of Chemistry
A simple, selective and rapid method for determining trace amounts of copper(II) ions in various types of water samples using atomic absorption spectrophotometry was investigated. Copper(II) ions from water samples were preconcentrated by solid phase extraction using octadecyl silica membrane disks modified with 3-{2-[2-(2-hydroxyimino- 1-methyl-propylideneamino)-ethylamino]-ethyl-imino}-butan-2-one oxime, (H_{2}mdo). The experimental conditions were optimized by changing several parameters such as volume of eluting solvent, the effect of pH, eluent flow rates, the amount of H_2mdo, breakthrough the volume, limit of detection and maximum capacity of the disks for Cu^{2+} recovery. The method was applied to the recovery of Cu(II) ions from seven …
Determination Of Manganese, Copper, Cadmium And Lead By Faas After Solid-Phase Extraction Of Their Phenylpiperazine Dithiocarbamate Complexes On Activated Carbon, Hasan Cesur
Turkish Journal of Chemistry
A solid-phase extraction method was developed for the pre-concentration of manganese, copper, cadmium and lead in water samples prior to their determination by flame atomic absorption spectrometry using phenylpiperazine dithiocarbamate as a new reagent. The optimum pre-concentration conditions have been investigated such as pH, volume of sample solution and the effects of some matrix elements. The obtained recovery was nearly 90 to 100, while the enrichment factor was 400 for metal spiked solutions.
Simultaneous Determination Of Copper, Zinc And Selenium In Chicken Liver By Differential Pulse Polarography, Güler Ekmekci̇, Güler Somer, Olcay Şendi̇l
Simultaneous Determination Of Copper, Zinc And Selenium In Chicken Liver By Differential Pulse Polarography, Güler Ekmekci̇, Güler Somer, Olcay Şendi̇l
Turkish Journal of Chemistry
A differential pulse polarographic method for the determination of copper, zinc and selenium in chicken liver is described. It was possible to determine these elements in a single sample solution after acid digestion. Dried liver samples weighing about 3 g were digested using HNO_{3} and HClO_{4} acids. Britton-Robinson or acetate buffer has been found suitable as the supporting electrolyte. For the determination of selenium, the hydrogen catalytic peak was used after the addition of molybdenum(VI) to the buffer solution at about pH 3. Then the pH of the same solution was increased to 4 and zinc was determined. For the …