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Articles 1 - 20 of 20
Full-Text Articles in Physical Sciences and Mathematics
Thin Polyimide Films Prepared By Ionic Self-Assembly, Mark Anderson, Richey Davis, C. Douglas Taylor, Michiaiah Parker, Spencer Clark, Daniela Marciu, Michael Miller
Thin Polyimide Films Prepared By Ionic Self-Assembly, Mark Anderson, Richey Davis, C. Douglas Taylor, Michiaiah Parker, Spencer Clark, Daniela Marciu, Michael Miller
Mark R. Anderson
Layer-by-layer electrostatic deposition of polyelectrolytes was used to modify a gold substrate with polydiallyl dimethylammonium chloride and an Ultem-type poly(amic acid) salt. Following deposition, heat treatment converted the poly(amic acid) salt into a polyimide. A decrease in the thin film thickness and a substantial increase in the interfacial contact angle accompanied thermal treatment. Results from cyclic voltammetry measurements also show that the imidized surface had a decreased dielectric constant relative to an unmodified or a poly(amic acid)-modified interface. Each of these results is consistent with formation of the polyimide. Infrared spectra of the thin films formed by the electrostatic deposition …
Automated, Web-Based, Second-Chance Homework, Randall W. Hall, Leslie G. Butler, Saundra Y. Mcguire, Sean P. Mcglynn, Gary L. Lyon, Ron L. Reese, Patrick A. Limbach
Automated, Web-Based, Second-Chance Homework, Randall W. Hall, Leslie G. Butler, Saundra Y. Mcguire, Sean P. Mcglynn, Gary L. Lyon, Ron L. Reese, Patrick A. Limbach
Randall W. Hall
Dopamine Adsorption At Surface Modified Carbon-Fiber Electrodes, Bradley Bath, Heidi Martin, R. Mark Wightman, Mark Anderson
Dopamine Adsorption At Surface Modified Carbon-Fiber Electrodes, Bradley Bath, Heidi Martin, R. Mark Wightman, Mark Anderson
Mark R. Anderson
Fast-scan cyclic voltammetry at high repetition rates was used to characterize adsorptive properties of dopamine (DA) at native and modified carbon-fiber microelectrode surfaces. Disk electrodes were fabricated from Thornel P55 fibers, and cylindrical electrodes, from Thornel T650 fibers. Their surfaces were modified by physisorption of 2,6-anthraquinone disulfonic acid (2,6-AQDS) or chemisorption of 4-carboxyphenyl or catechols. Chemisorption was accomplished via electrochemical reduction of diazonium salts. The degree of DA adsorption and its oxidation kinetics were found to vary for the two types of native carbon fiber electrodes and with the different chemical overlayers on the carbon surfaces. 2,6-AQDS measurably increased DA …
Teaching Analytical Chemistry To The Masses: How We Went From 2 Courses To 7 Courses In 10 Years, Gary Long, Mark Anderson, Brian Tissue, John Morris
Teaching Analytical Chemistry To The Masses: How We Went From 2 Courses To 7 Courses In 10 Years, Gary Long, Mark Anderson, Brian Tissue, John Morris
Mark R. Anderson
No abstract is currently available.
Interactive Multimedia Over The Internet For Teaching Analytical Chemistry, Mark Anderson
Interactive Multimedia Over The Internet For Teaching Analytical Chemistry, Mark Anderson
Mark R. Anderson
No abstract is currently available.
Opportunities In Computational Materials Science, Randall Hall, Juana Moreno
Opportunities In Computational Materials Science, Randall Hall, Juana Moreno
Randall W. Hall
The White House Materials Genome Initiative intends to double the speed with which we discover, develop, and manufacture new materials. In order for this initiative to be successful an unprecedented collaboration between computer scientists, applied mathematicians, computational scientists, and engineers with expertise in each of the aspects of the simulation-guided design of modern materials must be established. We must also take advantage of the enormous national investments in the next generation of hyperparallel, heterogeneous, multicore supercomputers to develop experimentally verified algorithms. In this talk I will describe new collaborative efforts in Louisiana towards developing a State-wise team of scientist to …
Live Demonstration Of The Personal Response System: A Tool For Prying Classroom Feedback From Students, Thomas Goyne
Live Demonstration Of The Personal Response System: A Tool For Prying Classroom Feedback From Students, Thomas Goyne
Thomas Goyne
No abstract provided.
A Biochemistry Laboratory Course Which Provides A 'Taste Of Research, Thomas Goyne
A Biochemistry Laboratory Course Which Provides A 'Taste Of Research, Thomas Goyne
Thomas Goyne
No abstract provided.
Kinetics Of Substitution Of Weakly Coordinating Nitrate By Chloride In (Η5-Cp)Ru(Co)(Er3)Ono2 (Er3 = Asph3, Pph3, P(P-Anisyl)3, Pph2(O-Anisyl), P(Oph)3) In Dichloromethane., Minhton Cao, Liem Do, Norris Hoffman, Man Lung Kwan, Julie Little, J. Mcgilvray, Christopher Morris, Bjorn Söderberg, Andrzej Wierzbicki, Thomas Cundari, Charles Lake, Edward Valente
Kinetics Of Substitution Of Weakly Coordinating Nitrate By Chloride In (Η5-Cp)Ru(Co)(Er3)Ono2 (Er3 = Asph3, Pph3, P(P-Anisyl)3, Pph2(O-Anisyl), P(Oph)3) In Dichloromethane., Minhton Cao, Liem Do, Norris Hoffman, Man Lung Kwan, Julie Little, J. Mcgilvray, Christopher Morris, Bjorn Söderberg, Andrzej Wierzbicki, Thomas Cundari, Charles Lake, Edward Valente
Man Lung Desmond Kwan
The d6 complexes of formula (η5-Cp)Ru(CO)(ER3)ONO2, where ER3 = AsPh3, PPh3, P(p-anisyl)3, PPh2(o-anisyl), and P(OPh)3, were prepared by reaction of their chloro analogues with AgNO3 in CH2Cl2. They underwent moderately slow substitution of the relatively weakly coordinating nitrate by chloride in dry CH2Cl2 in the presence of excess [N(PPh3)2+]Cl-. A kinetics study showed the reaction to be first order in nitrato complex and independent of chloride salt concentration under pseudo-first-order conditions. First-order rate constants for nitrate metathesis follow the trend P(OPh)3 < PPh3 < P(p-anisyl)3 < AsPh3 PPh2(o-anisyl), with k1 at 25 °C for the first four in the series from 1.4 to 4.4 × 10-5 s-1. Activation parameters for conversion of (η5-Cp)Ru(CO)(AsPh3)ONO2 to its chloride are ΔH‡ = 17(2) kcal/mol and ΔS‡ = −21(5) eu. Even use of a slightly moist solvent increased the rate of nitrate metathesis by 20−30% without changing the form of the rate law. The complex containing PPh2(o-anisyl) was approximately 2 orders of magnitude more reactive (k1 = 4.9 × 10-3 s-1). A likely explanation is stabilization of a coordinatively unsaturated intermediate by weak coordination of the potentially chelating o-OMe group. A mechanism entailing rate-limiting conversion of the neutral nitrato complex into a coordinatively unsaturated ion-paired species is consistent with this set of data. Semiempirical calculations (PM3(tm)), which model the structures of complexes in these systems quite well, supported such behavior. X-ray crystal structures were determined for the AsPh3 nitrato and chloro complexes and for the PPh3 chloro complex.
Spectra And Geometries Of Ar+ N (N = 30 - 60) [Invited], Jose Gascon, Randall W. Hall
Spectra And Geometries Of Ar+ N (N = 30 - 60) [Invited], Jose Gascon, Randall W. Hall
Randall W. Hall
Stereoselective One-Pot Synthesis Of Vinylsilanes From Aromatic Aldehydes, Man Lung Kwan, Chiu Yeung, Kerry Breno, Kenneth Doxsee
Stereoselective One-Pot Synthesis Of Vinylsilanes From Aromatic Aldehydes, Man Lung Kwan, Chiu Yeung, Kerry Breno, Kenneth Doxsee
Man Lung Desmond Kwan
Vinylsilanes serve as convenient vinyl anion equivalents, but procedures for their stereoselective synthesis from aldehydes are scarce. A variety of aromatic aldehydes are converted to the corresponding vinylsilanes in a one-pot procedure involving the addition of (trimethylsilylmethyl)lithium to the aldehyde followed by treatment with Cp2TiCH2·AlMe2Cl (‘Tebbe's reagent’). Halide and alkoxide substituents are tolerated, and (E)-vinylsilanes are formed exclusively in good yield.
Simple Relationships For The Estimation Of Melting Temperatures Of Homologous Series, James S. Chickos, Gary Nichols
Simple Relationships For The Estimation Of Melting Temperatures Of Homologous Series, James S. Chickos, Gary Nichols
James Chickos
No abstract provided.
Using Flash Animation And Streaming Video For Laboratory/Lecture Demonstrations In Large Enrollment Courses, Mark Anderson
Using Flash Animation And Streaming Video For Laboratory/Lecture Demonstrations In Large Enrollment Courses, Mark Anderson
Mark R. Anderson
No abstract is currently available.
Metal Binding Studies With Macrocyclic Hexathioethers: Transition Metal Complexes Of 22s6 And 20s6”,, Gregory Grant, Christopher Brandow, Chrystal Bruce, Mark Brandt, Rebecca Kirk, Sabrina Lee, Kerry Robinson, Larry Mehne
Metal Binding Studies With Macrocyclic Hexathioethers: Transition Metal Complexes Of 22s6 And 20s6”,, Gregory Grant, Christopher Brandow, Chrystal Bruce, Mark Brandt, Rebecca Kirk, Sabrina Lee, Kerry Robinson, Larry Mehne
Chrystal D. Bruce
No abstract provided.
Structural Characterization Of Mao And Related Aluminum Complexes. 1. Solid-State 27al Nmr With Comparison To Efg Tensors From Ab Initio Molecular Orbital Calculations, Pamela L. Bryant, Chris R. Harwell, Anthony A. Mrse, Earl F. Emery, Zhehong Gan, Tod Caldwell, Arneil P. Reyes, Philip Kuhns, David W. Hoyt, Larry S. Simeral, Randall W. Hall, Leslie G. Butler
Structural Characterization Of Mao And Related Aluminum Complexes. 1. Solid-State 27al Nmr With Comparison To Efg Tensors From Ab Initio Molecular Orbital Calculations, Pamela L. Bryant, Chris R. Harwell, Anthony A. Mrse, Earl F. Emery, Zhehong Gan, Tod Caldwell, Arneil P. Reyes, Philip Kuhns, David W. Hoyt, Larry S. Simeral, Randall W. Hall, Leslie G. Butler
Randall W. Hall
The Discovery-Oriented Approach To Organic Chemistry. 5. Stereochemistry Of E2 Elimination: Elimination Of Cis- And Trans-2-Methylcyclohexyl Tosylate, Ram S. Mohan, Marcus E. Cabay, Brad J. Ettlie, Adam J. Tuite, Kurt A. Welday
The Discovery-Oriented Approach To Organic Chemistry. 5. Stereochemistry Of E2 Elimination: Elimination Of Cis- And Trans-2-Methylcyclohexyl Tosylate, Ram S. Mohan, Marcus E. Cabay, Brad J. Ettlie, Adam J. Tuite, Kurt A. Welday
Ram S. Mohan
Deprotection Of Ketoximes Using Bismuth(Iii) Nitrate Pentahydrate, Ram S. Mohan, Bryce A. Nattier, Kyle J. Eash
Deprotection Of Ketoximes Using Bismuth(Iii) Nitrate Pentahydrate, Ram S. Mohan, Bryce A. Nattier, Kyle J. Eash
Ram S. Mohan
The Discovery-Oriented Approach To Organic Chemistry. 4. Epoxidation Of P-Methoxy-Trans-Β-Methylstyrene. An Exercise In 1H Nmr And 13C Nmr Spectroscopy For Sophomore Organic Laboratories, Ram S. Mohan, Rebecca S. Centko
The Discovery-Oriented Approach To Organic Chemistry. 4. Epoxidation Of P-Methoxy-Trans-Β-Methylstyrene. An Exercise In 1H Nmr And 13C Nmr Spectroscopy For Sophomore Organic Laboratories, Ram S. Mohan, Rebecca S. Centko
Ram S. Mohan
A Facile And Efficient Method For The Rearrangement Of Aryl-Substituted Epoxides To Aldehydes And Ketones Using Bismuth Triflate, Ram S. Mohan, Kaushik A. Bhatia, Kyle J. Eash, Nicholas M. Leonard, Matthew C. Oswald
A Facile And Efficient Method For The Rearrangement Of Aryl-Substituted Epoxides To Aldehydes And Ketones Using Bismuth Triflate, Ram S. Mohan, Kaushik A. Bhatia, Kyle J. Eash, Nicholas M. Leonard, Matthew C. Oswald
Ram S. Mohan
An Efficient Method For The Chemoselective Synthesis Of Acylals From Aromatic Aldehydes Using Bismuth Triflate, Ram S. Mohan, Marc D. Carrigan, Kyle J. Eash, Matthew C. Oswald
An Efficient Method For The Chemoselective Synthesis Of Acylals From Aromatic Aldehydes Using Bismuth Triflate, Ram S. Mohan, Marc D. Carrigan, Kyle J. Eash, Matthew C. Oswald
Ram S. Mohan