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Chemistry

Old Dominion University

Theses/Dissertations

2010

River-estuary systems

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Full-Text Articles in Physical Sciences and Mathematics

Oxygen Isotopes As A Tracer Of Dom Processes In River-Estuary Systems, Joy Ashley Matthews Jul 2010

Oxygen Isotopes As A Tracer Of Dom Processes In River-Estuary Systems, Joy Ashley Matthews

OES Theses and Dissertations

In the biogeochemical study of dissolved organic matter (DOM) in natural waters, stable isotopes are used to provide insight into both the sources of DOM and the processes affecting its alteration. Through the research presented here, oxygen isotopes are incorporated into the study of DOM through the adaptation of a pyrolysis elemental analysis isotope ratio mass spectrometer method, and sample preparation using two-stage ultrafiltration.

The application of oxygen isotopes to the study of DOM is demonstrated in two studies. First, natural abundance of δ18O in DOM is explored in the Delaware estuary. Using a two end-member mixing model, …