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Full-Text Articles in Physical Sciences and Mathematics

Nanocarbon Immobilized Membrane For Separation And Analysis, Madhuleena Bhadra May 2014

Nanocarbon Immobilized Membrane For Separation And Analysis, Madhuleena Bhadra

Dissertations

Membrane processes classically cover a wide range of applications associated with various aspects of separation and purification. Over the last few years, membrane based processes have received much interest due to their compact and modular architecture, low energy consumption and cost effective separation. With the development of diverse nanomaterials which can serve as nanosorbents, or provide specific morphology for selective solute transport, recent years have witnessed the emergence of nanocarbon based membranes that can address some of the limitations of conventional membrane processes and make feasible the next generation of breakthroughs.

The objective of this research is the exploration of …


Nanocarbons As Charge Carriers In Organic Solar Cells, Xinbo C. Lau Jan 2014

Nanocarbons As Charge Carriers In Organic Solar Cells, Xinbo C. Lau

Dissertations

Organic photovoltaics (OPV) are an alternate to conventional silicon and thin film solar cells. They have several advantages such as simple fabrication, low material cost, light weight, and the ability to cover large areas. Typical OPV are based on bulk heterojunction structure consisting of a blend of an electron-donating semiconductor polymer and an electron-accepting molecule. Various approaches have been pursued to improve the performance of OPV: low bandgap polymers, new electron acceptors, processing additives, and tandem cell architecture.

Nanocarbons possess unique physical and chemical properties that can contribute to the enhancement of OPV performance, such as charge carrier mobility, thermal …


Thermochemical Properties Of C3 To C5 Unsaturated Carbonyl Alkenes: Enthalpies Of Formation, Entropy, Heat Capacity, Bond Enthalpy, Ruiqi Jian Jan 2014

Thermochemical Properties Of C3 To C5 Unsaturated Carbonyl Alkenes: Enthalpies Of Formation, Entropy, Heat Capacity, Bond Enthalpy, Ruiqi Jian

Theses

α,β and α-γ unsaturated carbonyl compounds are important classes of carbonyl compounds with the general structure R-(O=C)-Cα=Cβ-R’ and R-(O=Cγ)-Cβ-Cα=Cβ-R’. These compounds are utilized in industry and are also produced as intermediates of hydrocarbon oxidation in chemistry of the atmosphere and in combustion. These unsaturated carbonyls are common environmental pollutants, are frequently associated with adverse effects, and are considered to play an important role in human cancer. Their stability, thermochemical properties are important to understanding their reaction paths in atmospheric, combustion and bio related environments. Enthalpy, entropy, and heat capacity of unsaturated alkene molecules, and radicals corresponding to hydrogen atom …