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Physical Sciences and Mathematics Commons

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Chemistry

Florida Institute of Technology

2013

Articles 1 - 2 of 2

Full-Text Articles in Physical Sciences and Mathematics

The Catalytic Behaviour Of Nanoag@Montmorillonite Composite Materials, Martina Karlíková, Libor Kvítek, Robert Prucek, Aleš Panáček, Jan Filip, Jirí Pechoušek, Nathaniel F. Adegboyega Nov 2013

The Catalytic Behaviour Of Nanoag@Montmorillonite Composite Materials, Martina Karlíková, Libor Kvítek, Robert Prucek, Aleš Panáček, Jan Filip, Jirí Pechoušek, Nathaniel F. Adegboyega

Chemistry and Chemical Engineering Faculty Publications

The preparation of nanoAg@montmorillonite composite materials and their catalytic activity is reported in this article. The nanoAg@montmorillonite composite materials were prepared by the adsorption of silver NPs, with an average size about 30 nm, from their aqueous dispersion onto two types of montmorillonite with different chemical composition. Silver NPs were prepared via modified Tollens process, which involves the reduction of [Ag(NH 3)2]+complex cation by maltose. The amount of silver NPs anchored onto the MMT surfaces was determined by UV-VIS spectroscopy; the decrease in absorbance of the dispersion after the adsorption was monitored. Prepared nanocomposite materials were subsequently characterized by means …


Visible-Light Activatable Organic Co-Releasing Molecules (Photocorms) That Simultaneously Generate Fluorophores, Ping Peng, Chaoming Wang, Zheng Shi, Valentine K. Johns, Liyuan Ma, Jeremiah Oyer, Alicja Copik, Robert Igarashi, Yi Liao Jul 2013

Visible-Light Activatable Organic Co-Releasing Molecules (Photocorms) That Simultaneously Generate Fluorophores, Ping Peng, Chaoming Wang, Zheng Shi, Valentine K. Johns, Liyuan Ma, Jeremiah Oyer, Alicja Copik, Robert Igarashi, Yi Liao

Chemistry and Chemical Engineering Faculty Publications

Novel organic photoCORMs based on micelle-encapsulated unsaturated cyclic α-diketones were designed and synthesized. These photoCORMs can be activated by visible light, have potentially low toxicity, allow the delivery of carbon monoxide to be monitored by fluorescence imaging techniques, and thus are useful tools for the study of the biological function of CO.