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Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

Chemistry

Clemson University

2009

Electrolyte grafting

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Synthesis, Modification Of Mesoporous Carbons And Their Application In Polymer Electrolyte Membrane Fuel Cells, Bing Liu Dec 2009

Synthesis, Modification Of Mesoporous Carbons And Their Application In Polymer Electrolyte Membrane Fuel Cells, Bing Liu

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Mesoporous carbon materials of carbon xerogel (CX) and silica-templated carbon (MC) were synthesized and explored as catalyst supports alternative to the most-commonly-used carbon black (CB) support, for polymer-electrolyte-membrane fuel cell (PEMFC) application. Pt catalyst was loaded on these carbons and electrodes were fabricated from them. These Pt-loaded carbon supports were characterized with XRD, TEM, ex-situ and in-situ cyclic voltammetry, etc. The fabricated electrodes were evaluated in single-cell testing in comparison with commercial CB-supported Pt catalyst fabricated electrodes. The experimental results showed that CX-supported Pt catalyst had close or better performance than that of CB-supported Pt, possibly due to CX's 3-D …