Open Access. Powered by Scholars. Published by Universities.®
Physical Sciences and Mathematics Commons™
Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 4 of 4
Full-Text Articles in Physical Sciences and Mathematics
Biological Degredation Of Acetaldehyde In Southern California Wetlands, Anthony Castagnola, Brandon Lamb, Mary Senstad, Sovandara Hok
Biological Degredation Of Acetaldehyde In Southern California Wetlands, Anthony Castagnola, Brandon Lamb, Mary Senstad, Sovandara Hok
Student Scholar Symposium Abstracts and Posters
Oxygenated hydrocarbons are ubiquitous in the atmosphere with levels ranging from low ppt (acetaldehyde) to low ppb(methanol). As an OH sink and an atmospheric HOx source, oxygenated hydrocarbons have a direct impact on the oxidative capacity of the atmosphere. A better understanding of the processes that produce and destroy these species in natural water would improve our understanding of the role that these systems play in cycling these species into or out of the atmosphere. These species can be lost to chemical, photochemical, and partical mediated (abiotic and biotic) processes in natural waters. Chemical loss and photochemical loss are believed …
Biological Degradation Of Acetaldehyde In Southern California Coastal Waters, Mary Senstad, Sovanndara Hok, Ori Barashy, Catherine D. Clark, Warren J. De Bruyn
Biological Degradation Of Acetaldehyde In Southern California Coastal Waters, Mary Senstad, Sovanndara Hok, Ori Barashy, Catherine D. Clark, Warren J. De Bruyn
Student Scholar Symposium Abstracts and Posters
Oxygenated hydrocarbons are ubiquitous in the atmosphere with levels ranging from low ppt (acetaldehyde) to low ppb (methanol). As an OH sink and an atmospheric HOx and ozone source, oxygenated hydrocarbons have a direct impact on the oxidative capacity of the atmosphere. The oceans are one of the largest sources of uncertainty in current atmospheric budget estimates of these species. A better understanding of the processes that produce and destroy these species in seawater would improve our understanding of the role of the oceans in cycling these species into or out of the atmosphere. We have measured the degradation rate …
Theoretical Examination Of Solvent And R Group Dependence In Gold Thiolate Nanoparticle Synthesis, Suzanne M. Neidhart, Brian M. Barngrover, Christine M. Aikens
Theoretical Examination Of Solvent And R Group Dependence In Gold Thiolate Nanoparticle Synthesis, Suzanne M. Neidhart, Brian M. Barngrover, Christine M. Aikens
Faculty Publications
The growth of gold thiolate nanoparticles can be affected by the solvent and the R group on the ligand. In this work, the difference between methanol and benzene solvents as well as the effect of alkyl (methyl) and aromatic (phenyl) thiols on the reaction energies and barrier heights is investigated theoretically. Density functional theory (DFT) calculations using the BP86 functional and a triple ζ polarized basis set show that the overall reaction favors methylthiol over phenylthiol with reaction energies of −0.54 and −0.39 eV in methanol, respectively. At the same level of theory, the methanol solvent is favored over the …
Prediction Of Nonradical Au (0)-Containing Precursors In Nanoparticle Growth Processes, Brian M. Barngrover, Timothy J. Manges, Christine M. Aikens
Prediction Of Nonradical Au (0)-Containing Precursors In Nanoparticle Growth Processes, Brian M. Barngrover, Timothy J. Manges, Christine M. Aikens
Faculty Publications
This density functional theory (DFT) investigation examines the formation of nonradical Au(0) species from the reduction of Au(I) species. The Au(I) complexes of interest are AuCl2–, AuBr2–, AuI2–, AuClPH3, and AuCl(H)SCH3(−), which are precursors for gold nanoparticle and cluster formation. Reaction of two of the Au(I) species with a hydride results in ejection of two of the ligands and formation of Au2 with two ligands still attached. AuX2– (where X = Cl, Br, or I) reactions eject two halides and form Au2 …