Open Access. Powered by Scholars. Published by Universities.®
Physical Sciences and Mathematics Commons™
Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 1 of 1
Full-Text Articles in Physical Sciences and Mathematics
Palladium-Catalyzed Carboxylation Of Allyl Stannanes And Carboxylative Coupling Of Allyl Stannanes And Allyl Halides [Abstract], Russell J. Franks
Palladium-Catalyzed Carboxylation Of Allyl Stannanes And Carboxylative Coupling Of Allyl Stannanes And Allyl Halides [Abstract], Russell J. Franks
Faculty Publications
The reaction of allyl stannanes with CO2 to form stannyl carboxylates (esters) is catalyzed by Pd(PR3)4 complexes. Thus, R3SnCH2CH=CH2 [R=Me and Ph]are converted to R3SnO2 CCH2CH=CH2 and R3SnO2CCH=CHCH3 under 33 atm of CO2 (70°C, THF) in moderate to excellent yield in the presence of 8 mol% Pd(PPh3)4 ; polycarboxylation of diallyldibutyltin and tetraallyltin also is effected, producing the respective di- and tetracarboxylates, Bu2Sn(O2CCH2CH=CH2)2 and Sn(O2CCH …