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Full-Text Articles in Physical Sciences and Mathematics
Amidoalkylation Of Aromatic Compounds, Mukhabbat Yuldasheva, Khurshida Turaeva, Tursunali Kholiqov
Amidoalkylation Of Aromatic Compounds, Mukhabbat Yuldasheva, Khurshida Turaeva, Tursunali Kholiqov
Bulletin of National University of Uzbekistan: Mathematics and Natural Sciences
As the result of systematical investigation of amidomethylation reaction benzene, toluene, isomeric xylenes, benzodioxane-1,4, mono- and dimethyl ethers of resorcinole, dimethyl ethers of hydroquinone with methylol and ethylol derivatives amides and imides, acetonitrile, benzonitrile and paraform the amidomethyl derivatives have been obtained and also influence of different factors on their yields and direction of investigated reactions was determined. Synthesis of amidomethyl derivatives of aromatic hydrocarbons, ethers dihydricpenols and most probable reaction mechanism was proposed.
Extraction Conductometric Determination Of Scandium And Thorium In Kaolins, Nigora Kutlimurotova, Zulayho Smanova, Habibulla Tojimuhamedov, Zuhra Yaxshiyeva, Jasur Tursunqulov
Extraction Conductometric Determination Of Scandium And Thorium In Kaolins, Nigora Kutlimurotova, Zulayho Smanova, Habibulla Tojimuhamedov, Zuhra Yaxshiyeva, Jasur Tursunqulov
Bulletin of National University of Uzbekistan: Mathematics and Natural Sciences
A method for extraction - conductometric determination of scandium and thorium with tributyl phosphate and trioctyl phosphine oxide in kaolin was developed. The equivalent electrical conductivity of the complex of scandium and thorium with 2,7-dinitrozo-1,8-dihydroxynaphthalene-3,6-disulfonic acid was found. A scheme for the separation and determination of kaolin content is proposed. The isotherms of scandium and thorium extraction are constructed. It was shown that at a concentration of nitric acid of 15.6 M they do not interfere with the determination of thorium and scandium.