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Full-Text Articles in Physical Sciences and Mathematics
Generation And Reactivity Of A One-Electron Oxidized Manganese(V) Imido Complex Bearing A Macrocyclic Tetraamido Ligand, Huatian Shi, Jianhui Xie Xie, William W. Y. Lam, Wai‐Lun Man, Chi‐Keung Mak, Shek‐Man Yiu, Hung Kay Lee, Tai‐Chu Lau
Generation And Reactivity Of A One-Electron Oxidized Manganese(V) Imido Complex Bearing A Macrocyclic Tetraamido Ligand, Huatian Shi, Jianhui Xie Xie, William W. Y. Lam, Wai‐Lun Man, Chi‐Keung Mak, Shek‐Man Yiu, Hung Kay Lee, Tai‐Chu Lau
Faculty of Science & Technology (THEi)
The synthesis and X‐ray structure of a new manganese(V) mesitylimido complex with a tetraamido macrocyclic ligand (TAML), [MnV(TAML)(N‐Mes)]− (1), are reported. Compound 1 is oxidized by [(p‐BrC6H4)3N]+.[SbCl6]− and the resulting MnVI species readily undergoes H‐atom transfer and nitrene transfer reactions.