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Full-Text Articles in Physical Sciences and Mathematics

Virtual Inorganic Pedagogical Electronic Resource Learning Objects In Organometallic Chemistry, Barbara Reisner, Joanne Stewart, B Williams, Laurel Goj, Patrick Holland, Hilary Eppley, Adam Johnson Oct 2014

Virtual Inorganic Pedagogical Electronic Resource Learning Objects In Organometallic Chemistry, Barbara Reisner, Joanne Stewart, B Williams, Laurel Goj, Patrick Holland, Hilary Eppley, Adam Johnson

Hilary J. Eppley

Four Virtual Inorganic Pedagogical Electronic Resource (VIPEr) learning objects featuring organometallicChemistry are highlighted.


Inorganic Chemistry And Ionic: An Online Community Bringing Cutting-Edge Research Into The Classroom, Elizabeth Jamieson, Hilary Eppley, Margret Geselbracht, Adam Johnson, Barbara Reisner, Sheila Smith, Joanne Stewart, Lori Watson, B Williams Oct 2014

Inorganic Chemistry And Ionic: An Online Community Bringing Cutting-Edge Research Into The Classroom, Elizabeth Jamieson, Hilary Eppley, Margret Geselbracht, Adam Johnson, Barbara Reisner, Sheila Smith, Joanne Stewart, Lori Watson, B Williams

Hilary J. Eppley

This Viewpoint highlights creative ways that members of the Interactive Online Network of Inorganic Chemists (IONiC) are using journal articles from InorganicChemistry to engage undergraduate students in the classroom. We provide information about specificEducational materials and networking features available free of charge to the inorganic community on IONiC's web home, the Virtual Inorganic Pedagogical Electronic Resource (VIPEr, www.ionicviper.org) and describe the benefits of joining this community.


Ionic: A Cyber-Enabled Community Of Practice For Improving Inorganic Chemicaleducation, Hilary Eppley, Adam Johnson, Ethan Benatan, Margret Geselbracht, Joanne Stewart, Barbara Reisner, Lori Watson, B. Williams Oct 2014

Ionic: A Cyber-Enabled Community Of Practice For Improving Inorganic Chemicaleducation, Hilary Eppley, Adam Johnson, Ethan Benatan, Margret Geselbracht, Joanne Stewart, Barbara Reisner, Lori Watson, B. Williams

Hilary J. Eppley

IONiC’s purpose is to enhance the inorganicChemistry classroom and laboratory experience for students and faculty members through the development of a vibrant virtual “community of practice”.


Jce Viper: An Inorganic Teaching And Learning Community, Ethan Benatan, Jezmynne Dene, Hilary Eppley, Margret Gesebracht, Elizabeth Jamieson, Adam Johnson, Barbara Reisner, Joanne Stewart, Lori Watson, B. Williams Oct 2014

Jce Viper: An Inorganic Teaching And Learning Community, Ethan Benatan, Jezmynne Dene, Hilary Eppley, Margret Gesebracht, Elizabeth Jamieson, Adam Johnson, Barbara Reisner, Joanne Stewart, Lori Watson, B. Williams

Hilary J. Eppley

To facilitate the effective sharing of teaching tools among faculty and the development of deep subject knowledge in support of teaching, a group of faculty from predominantly undergraduate institutions has established a virtual community of inorganic chemists, IONiC (Interactive Online Network of Inorganic Chemists). Our mission is to enhance the inorganicChemistry classroom and laboratory experience for students and faculty members through the development of a vibrant, collaborative, and open community. VIPEr, the Virtual Inorganic Pedagogical Electronic Resource, is a Web site that forms the online home for our community. VIPEr is an interactive Web resource that combines a repository of …


Viper: An Online Academic Resource Enhancing Undergraduate Research, Sheila Smith, Sibrina Collins, Hilary Eppley, Margaret Geselbracht, Elizabeth Jamieson, Adam Johnson, Chip Nataro, Barbara Reisner, Joanne Stewart, B. Williams, Lori Watson Oct 2014

Viper: An Online Academic Resource Enhancing Undergraduate Research, Sheila Smith, Sibrina Collins, Hilary Eppley, Margaret Geselbracht, Elizabeth Jamieson, Adam Johnson, Chip Nataro, Barbara Reisner, Joanne Stewart, B. Williams, Lori Watson

Hilary J. Eppley

No abstract provided.


Kinetic And Mechanistic Studies Of The Deuterium Exchange In Classical Keto−Enol Tautomeric Equilibrium Reactions, Mark Waner, Michael Nichols Dec 2009

Kinetic And Mechanistic Studies Of The Deuterium Exchange In Classical Keto−Enol Tautomeric Equilibrium Reactions, Mark Waner, Michael Nichols

Mark J. Waner

An extension of the classic keto−enol tautomerization of β-dicarbonyl compounds into a kinetic analysis of deuterium exchange is presented. It is shown that acetylacetone and ethyl acetoacetate undergo nearly complete deuterium exchange of the α-methylene carbon when dissolved in methanol-d4. The extent of deuteration may be monitored via NMR spectroscopy as a function of time. A mechanism for deuterium exchange is presented and shown to be consistent with a consecutive first-order process. The data for acetylacetone are consistent with steady-state kinetics, whereas those of ethyl acetoacetate illustrate nonsteady-state behavior, offering an accessible example where students might collect and analyze real …