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Full-Text Articles in Physical Sciences and Mathematics
Stepwise Synthesis And Structural Characterization Of The Molybdenum-Iron-Sulfur {[Mofe3s4cl2(Cl4cat)]2(.Mu.2-S)2}6- And {[Mofe3s4cl2(Cl4cat)]2(.Mu.2-S)(.Mu.2-Oh}5- Doubly Bridged Double Cubanes Obtained By The Coupling Of [Mofe3s4] Clusters, Dimitri Coucouvanis, Paul Challen, Sang Koo, W. Davis, W. Butler, W. Dunham
Stepwise Synthesis And Structural Characterization Of The Molybdenum-Iron-Sulfur {[Mofe3s4cl2(Cl4cat)]2(.Mu.2-S)2}6- And {[Mofe3s4cl2(Cl4cat)]2(.Mu.2-S)(.Mu.2-Oh}5- Doubly Bridged Double Cubanes Obtained By The Coupling Of [Mofe3s4] Clusters, Dimitri Coucouvanis, Paul Challen, Sang Koo, W. Davis, W. Butler, W. Dunham
Paul R. Challen
No abstract provided.
Thermochemistry Of A Structurally Defined Aldol Reaction., Edward Arnett, Franklin Fisher, Michael Nichols, Anthony Ribeiro
Thermochemistry Of A Structurally Defined Aldol Reaction., Edward Arnett, Franklin Fisher, Michael Nichols, Anthony Ribeiro
Michael A Nichols
No abstract provided.
The Activation Of Carbon-Fluorine Bonds By Oxidative Addition At Tungsten(O): An Electrochemical Study, Andrea Russell, Carolyn Osterberg, Daniel Blackwood, Mark Anderson, Thomas Richmond, Stanley Pons
The Activation Of Carbon-Fluorine Bonds By Oxidative Addition At Tungsten(O): An Electrochemical Study, Andrea Russell, Carolyn Osterberg, Daniel Blackwood, Mark Anderson, Thomas Richmond, Stanley Pons
Mark R. Anderson
We have investigated the anodic oxidation reactions of W(CO)4Et,F5 (I), where Et,F5 is the ligand N,N'-bis(pentafluorophenylidine)ethylenediamine, by cyclic voltammetry and infrared spectroelectrochemistry. The results in both acetonitrile and methylene chloride indicate an ece type mechanism, with the product of the first electron transfer stabilized by the more coordinating solvent.