Physical Sciences and Mathematics Commons^™

Catalytic Transfer Hydrogenation Reactions Of Lipids, Alexander Asiedu

Civil & Environmental Engineering Theses & Dissertations

Catalytic transfer hydrogenation (CTH) of lipids was investigated using 2-propanol as hydrogen donor for producing liquid hydrocarbons, e.g. jet fuels. The main sources of lipids selected in this study were waste cooking oil (WCO) and oil-laden algae-derived biofuel intermediate (BI). Two different catalysts were employed in this study, namely activated carbon and trimetallic-doped zeolite.

The CTH reaction was between WCO and 2-propanol in a continuous flow reactor over a packed-bed activated carbon at near atmospheric pressure. Results revealed a high level of alkenes and aromatics compounds, which are not stable and are not environmentally unfriendly. To reduce these compounds in …

Diffuse-Charge Dynamics Of Ionic Liquids In Electrochemical Systems, Hui Zhao

Mechanical Engineering Faculty Research

We employ a continuum theory of solvent-free ionic liquids accounting for both short-range electrostatic correlations and steric effects (finite ion size) [Bazant et al., Phys. Rev. Lett. 106, 046102 (2011)] to study the response of a model microelectrochemical cell to a step voltage. The model problem consists of a 1-1 symmetric ionic liquid between two parallel blocking electrodes, neglecting any transverse transport phenomena. Matched asymptotic expansions in the limit of thin double layers are applied to analyze the resulting one-dimensional equations and study the overall charge-time relation in the weakly nonlinear regime. One important conclusion is that our …