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Physical Sciences and Mathematics Commons

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Full-Text Articles in Physical Sciences and Mathematics

Technical Note: Molecular Characterization Of Aerosol-Derived Water Soluble Organic Carbon Using Ultrahigh Resolution Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry, As Wosniak, Je Bauer, Rl Sleighter, Rm Dickhut, Pg Hatcher Jan 2008

Technical Note: Molecular Characterization Of Aerosol-Derived Water Soluble Organic Carbon Using Ultrahigh Resolution Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry, As Wosniak, Je Bauer, Rl Sleighter, Rm Dickhut, Pg Hatcher

VIMS Articles

Despite the acknowledged relevance of aerosol-derived water-soluble organic carbon (WSOC) to climate and biogeochemical cycling, characterization of aerosol WSOC has been limited. Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS) was utilized in this study to provide detailed molecular level characterization of the hi(,h molecular weight (HMW; m/z>223) component of aerosol-derived WSOC collected from rural sites in Virginia and New York, USA. More than 3000 peaks were detected by ESI FT-ICR MS within a m/z range of 223-600 for each sample. Approximately 86% (Virginia) and 78% (New York) of these peaks were assigned molecular formulas …


Community Dynamics In Submersed Aquatic Vegetation: Intermediate Consumers As Mediators Of Environmental Change, James G. Douglass Jan 2008

Community Dynamics In Submersed Aquatic Vegetation: Intermediate Consumers As Mediators Of Environmental Change, James G. Douglass

Dissertations, Theses, and Masters Projects

Natural ecosystems are strongly affected by changes in resource supply (bottom-up forces) and by changes in upper trophic levels (top-down forces). The extent to which these processes impact a system depends largely on the responses of organisms at middle trophic levels. In seagrass beds, a group of mid-level consumers known as mesograzers form a critical link in the chain of impact, connecting seagrass and epiphytic algae with predatory fishes and crustaceans. I observed dramatic seasonal and interannual changes in mesograzer abundance and species composition in eelgrass (Zostera marina) beds of lower Chesapeake Bay, Virginia, and endeavored to explain the top-down …