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Full-Text Articles in Physical Sciences and Mathematics
Nitrogen Retention And Denitrification In Reservoirs, Erin Grantz
Nitrogen Retention And Denitrification In Reservoirs, Erin Grantz
Graduate Theses and Dissertations
Studies coupling direct measurements of micro-scale nitrogen (N) cycle processes with ecosystem-scale flux estimates are needed to determine N retention hotspots within river networks, where up to 50% of terrestrial loading to aquatic systems is retained. This study examined the role of denitrification, a microbially-mediated reactive N removal pathway, in ecosystem-scale N retention in 3 small (< 1 km2), shallow flood-control reservoirs. Annual reservoir N retention was estimated through mass balance modeling of system inputs and outputs. Annual denitrification rates were estimated by combining multiple measurements of seasonal, habitat-specific dinitrogen gas (N2) fluxes. Annual reservoir N retention ranged from 14 - 19 g m-2 in the reservoirs, while reactive N removal through denitrification was 13 - 25 g m-2. Denitrification efficiency, or the portion of the retained N load that was denitrified, was high relative to other lentic systems and was > 100% at 2 sites. Previous lentic denitrification studies may have underestimated denitrification efficiency by not considering water column denitrification, which was 50% of total denitrification at one study reservoir. However, not all potential inputs, most importantly biological N2 fixation, were included in this …
Geochemical Controls On Mercury Methylation In Backwaters Of A Gulf Coastal Plain River System, Implications For Water Column Processes, Liam N. Schenk
Geochemical Controls On Mercury Methylation In Backwaters Of A Gulf Coastal Plain River System, Implications For Water Column Processes, Liam N. Schenk
Graduate Theses and Dissertations
The abundance and distribution of mercury and methyl mercury were investigated at three sites in the lower Ouachita River in the summer of 2010 in an effort to provide the first characterization of the extent of mercury contamination in this river system, and to investigate the potential for mercury methylation in the water column of backwaters off of the main channel. Results showed that filtered methyl mercury was positively correlated to dissolved organic carbon (r2=0.76) for water samples taken from the bottom 1 ft of the water column at three sites, suggesting the importance of dissolved organic carbon in mercury …