Physical Sciences and Mathematics Commons^™

Development Of A High-Resolution Mid-Infrared Spectroscopy Apparatus For The Study Of Methane And Other Astrochemical Molecules., S M Shah Riyadh

Electronic Theses and Dissertations

This research documents steps towards building a novel spectroscopic technique, namely, cavity-enhanced double-resonance (CEDR) spectroscopy, for investigating methane (CH₄) and other molecules with significance in astrochemistry. These efforts focus on tackling the complexities of their ro-vibrational energy levels and the inefficiencies in analyzing vibrational spectra, particularly for molecules with high symmetry and strong intramolecular interactions. In the CEDR spectroscopy, the first photon, generated by a continuous-wave optical parametric oscillator (CW-OPO) locked to a Doppler-free saturation absorption line, excites the molecule from its ground level to a selected excited ro-vibrational (rotational-vibrational) level, e.g., that of the asymmetric CH-stretch mode. …

Filaments And Their Application To Air Lasing, Spectroscopy, And Guided Discharge, Ali Rastegari

Optical Science and Engineering ETDs

Laser filamentation is a fascinating phenomenon that occurs when an intense laser beam travels through transparent materials, in particular air. At sufficiently high power (TW in the near IR, GW in the UV), instead of spreading out like a regular laser beam, something remarkable happens: the laser beam becomes tightly focused, creating a thin and intense column of light called a laser filament. Laser filamentation is characterized by two main properties: (I) a high-intensity core that remains narrow over long distances beyond the Rayleigh range and (II) a low-density plasma channel within the core. In recent years, laser filamentation has …

Sigesn Light-Emitting Devices: From Optical To Electrical Injection, Yiyin Zhou

Graduate Theses and Dissertations

Si photonics is a fast-developing technology that impacts many applications such as data centers, 5G, Lidar, and biological/chemical sensing. One of the merits of Si photonics is to integrate electronic and photonic components on a single chip to form a complex functional system that features compact, low-cost, high-performance, and reliability. Among all building blocks, the monolithic integration of lasers on Si encountered substantial challenges. Si and Ge, conventional epitaxial material on Si, are incompetent for light emission due to the indirect bandgap. The current solution compromises the hybrid integration of III-V lasers, which requires growing on separate smaller size substrates …

Optimization Of An Injection Locked Laser System For Cold Neutral Atom Traps, Elliot M. Lehman

Physics

Many types of quantum systems are being explored for use in quantum computers. One type of quantum system that shows promise for quantum computing is trapped neutral atoms. They have long coherence times, since they have multiple stable ground states and have minimal coupling with other atoms and their environment, and they can be trapped in arrays, making them individu- ally addressable. Once trapped, they can be initialized and operated on using laser pulses. This experiment utilizes a pinhole diffraction pattern, which can trap atoms in both bright and dark areas. To maximize trap strength, an injection-locked laser amplification system …

Development Of A Compact Broadband Optical Parametric Oscillator For Ultra-Sensitive Molecular Detection, Sean O. Crystal

Honors Undergraduate Theses

Every gas molecule has a unique absorption spectrum that can be captured using optical spectroscopy to identify an unknown sample's composition. Frequency combs systems can provide an extremely broad mid-infrared spectrum that is very useful for molecular detection. A degenerate optical parametric oscillator (OPO) was built to generate the down-converted and shifted frequency comb spectrum. This system utilizes an ultra-short pulse 1.56µm pump laser and a never before used orientation patterned gallium-phosphide crystal. Periodically polled lithium niobate (PPLN), Gallium Arsenide (GaAs) and Gallium Phosphide are all crystals used to accomplish this task. GaP, in comparison to PPLN, has (i) a …

Cavity Ringdown Spectroscopy In Nitrogen/Oxygen Mixtures In The Presence Of Alpha Radiation, Sidney John Gautrau

Master's Theses

This research was part of an effort to experimentally validate computational models under development for radiation-induced atmospheric effects. Cavity Ringdown Spectroscopy (CRDS) was used to measure the concentration of chemical products generated as a result of radiation interactions in a controlled atmosphere. Experiments were conducted in a vacuum chamber interfaced with a gas introduction system that controlled the initial atmospheric composition. A quadrupole mass spectrometer and tunable dye laser were integrated to confirm initial atmospheric composition, and provide wavelength flexibility for detecting a variety of chemical products generated by radiation interactions. CRDS measurements were made for ozone production resulting from …

Construction And Optimization Of A Tapered Amplifier System For Applications In Ultra-Cold Plasma Research, Ryan Cole

Honors Theses

The number density of cold atoms confined in a magneto-optical trap (MOT) is critically dependent on the intensity of the lasers used to cool the sample. To generate large optical powers while retaining the practicality of homemade external cavity diode lasers (ECDLs), a tapered amplifier (TA) system was designed and constructed to amplify the output of an existing 780 nm, continuous-wave ECDL. The amplifier’s performance is discussed in terms of its gain and power output. Under standard operating conditions, optical amplification of 12 dB is achieved, with a maximum power output of 0.75 W. The completed amplifier is installed into …

Laser-Induced Breakdown Spectroscopy For Analysis Of High Density Methane-Oxygen Mixtures, Matthew Dackman

Masters Theses

The applicability of laser-induced breakdown spectroscopy (LIBS) toward greater than atmospheric density combustion diagnostics is examined. Specifically, this involves ascertaining the feasibility of measuring chemical equivalence ratios directly from atomic emission spectra at high density. The need for such measurement arises from the desire to quantify real time, localized combustion performance in weakly mixed flows. Insufficiently mixed flows generally result in unwanted byproducts, possess the propensity for overall combustion instability, and are increasingly likely to experience localized flame extinction.

We simulate methane/oxygen combustion in ambient pressures ranging 1 to 4 atmospheres, demonstrating these results to be analogous to what would …

The Talbot Effect, Malia Kawamura

Honors Theses

The goal of this project is to experimentally investigate the optical Talbot effect and the electron Talbot effect. The Talbot effect is a near-field diffraction effect which occurs when plane waves are incident upon a grating. The Talbot effect creates full grating revivals at integral Talbot lengths and revivals with greater spatial periodicity at fractional Talbot lengths. We use a green helium neon laser and Ronchi rulings to take CCD camera images of the fractional Talbot revivals directly. Additionally, a photodiode records light intensity as a function of time as a second identical grating is moved to verify the presence …

Forcing Mutual Coherence In Diode Laser Stacks, Jonathan R. Wurtz

Honors Theses and Capstones

This paper will discuss both theoretical and experimental attempts to improve the spatial beam quality of diode laser stacks using an external optical system. An overview and derivation of the mathematics of both the optical system and diode lasers will be discussed. The experimental setup will be presented, as well as the fundamental theoretical and experimental results that suggest the external optical system used for this thesis fails to improve the beam quality of a diode laser stack.

Laser-Induced Breakdown Spectroscopy, Connor Drake

Physics

The goal of this work is to use a Neodymium-Doped Yttrium Aluminum Garnet (Nd:YAG) Laser, spectrometer, and computer to create a Laser Induced Breakdown Spectroscopy (LIBS) system. LIBS utilizes a focused, high-powered, pulsed laser whose peak electric field ionizes materials at the beam focal point, creating localized plasma. The plasma state includes broken molecular bonds, atom/electron-ionization, and excited electrons, which on the macroscopic level is a loud “snap” and a bright spark. In this project, a fiber optic cable is used to capture light emitted from the spark, and direct it into a spectrometer which tallies the number of photons …

Constructing A Magneto-Optical Trap For Cold Atom Trapping, Eric S. Muckley

Physics

A magneto-optical trap, or MOT, is a device that traps atoms between three pairs of opposing perpendicular laser beams for cooling the atoms to temperatures near absolute zero. The MOT uses Doppler cooling and a magnetic quadrupole field to trap the atoms; in our case, Rb87 atoms. In the future, the MOT will be used in experiments pertaining to the advancement of quantum computing. In this paper, I explain some of the processes required for construction and operation of the MOT.