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Physical Sciences and Mathematics Commons

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Atomic, Molecular and Optical Physics

University of Tennessee, Knoxville

2020

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Laser-Induced Breakdown Spectroscopy And Plasmas Containing Cyanide, Christopher Matthew Helstern Dec 2020

Laser-Induced Breakdown Spectroscopy And Plasmas Containing Cyanide, Christopher Matthew Helstern

Doctoral Dissertations

This dissertation focuses on laser-induced plasma of diatomic molecular cyanide. Optical breakdown plasma generation is produced by high-peak-power 1064 nm Q-switched nanosecond pulsed radiation. Laser-induced breakdown is performed on a 1:1 molar gas mixture of carbon dioxide and nitrogen held at a fixed pressure of 760 Torr, a 1:1 molar gas mixture of carbon dioxide and nitrogen held at a fixed pressure of 2069 Torr, and a flowing 1:1 molar gas mixture of carbon dioxide and nitrogen flowing at a rate of 100 mL per minute. Plasma shockwave measurements in laboratory air are shown to determine the shock front geometry …