Physical Sciences and Mathematics Commons^™

Strontium Monoxide Measurements In Methane-Air Flames, Bobby J. Wimberly

Masters Theses

The spectroscopy of alkaline earth metal compounds has been an area of active research for several decades. This is at least in part stimulated by the application of these compounds to practical areas ranging from technology to medicine. The use of these compounds in the field of pyrotechnics was the motivation for a series of flame emission spectroscopy (FES) experiments with strontium containing compounds. Specifically, strontium monoxide (SrO) is studied as a candidate radiator for the diagnostic of methane-air flames.

SrO emissions have been observed in flames with temperatures in the range of 1200-1600-K for two compounds: strontium hydroxide and …

Measurements Of Methyl Radicals And Temperatures By Using Coherent Microwave Rayleigh Scattering From Resonance Enhanced Multiphoton Ionization, Yue Wu

Doctoral Dissertations

This thesis includes two main parts: (I) The CH₃[methyl radical] detection in methane/air flames and (II) the rotational temperature measurement of O₂[molecular oxygen] in a variety of environments by using coherent microwave Rayleigh scattering from resonance enhanced multiphoton ionization (Radar REMPI).

In first the part, from Chapter I to Chapter III, the methyl radical detection and quantitative measurements have been conducted in hydrocarbon flame with one-dimensional and two-dimensional spatial-resolved concentration distribution. Due to the proximity of the argon resonance state (4+1 REMPI by 332.5 nm) with the CH₃ state (2+1 REMPI by 333.6 nm), in …

Diatomic Carbon Measurements With Laser-Induced Breakdown Spectroscopy, Michael Jonathan Witte

Masters Theses

In this thesis, investigation of well-known carbon Swan spectra is of primary interest. Combustion processes and/or explosion of hydrocarbon fuels cause occurrence of the Swan band system that originates from diatomic carbon. Physical characteristics of low-temperature stars and the interstellar medium can also reveal the Swan bands. The diatomic carbon molecule shows that its lowest rotational levels are sensitive to temperature variation, and higher rotational levels are sensitive to the surrounding gas density and the radiation field. In addition, carbon is a crucial element for life and is the 4th most abundant element; therefore, it is important to ascertain accurately …