Physical Sciences and Mathematics Commons^™

Experimental Study On The Production Of Negative Ion Copper Clusters And Applications, Ran Chu

Masters Theses

At the Holifield Radioactive Ion Beam Facility (HRIBF) at Oak Ridge National Laboratories (ORNL), we investigated the formation, production and potential application of negative-ion copper clusters using mass distributions of negative-ion copper clusters obtained by bombarding various copper samples with Cs ions. The Cu samples – in very large mass-selected clusters Cu (e.g. n=54) – included natural Cu, isotopically enriched copper-63 and copper-65, and electroformed ultra-clean Cu. Mass spectra of negative copper cluster produced by Cs sputter source size up to 50 are shown for the first time.

Three main features were observed for all four copper samples: the intensity …

Cavity Ringdown Spectroscopy In Nitrogen/Oxygen Mixtures In The Presence Of Alpha Radiation, Sidney John Gautrau

Master's Theses

This research was part of an effort to experimentally validate computational models under development for radiation-induced atmospheric effects. Cavity Ringdown Spectroscopy (CRDS) was used to measure the concentration of chemical products generated as a result of radiation interactions in a controlled atmosphere. Experiments were conducted in a vacuum chamber interfaced with a gas introduction system that controlled the initial atmospheric composition. A quadrupole mass spectrometer and tunable dye laser were integrated to confirm initial atmospheric composition, and provide wavelength flexibility for detecting a variety of chemical products generated by radiation interactions. CRDS measurements were made for ozone production resulting from …

Investigation Of Multi-Photon Excitation In Argon With Applications In Hypersonic Flow Diagnostics, Jack L. Mills

Physics Theses & Dissertations

Non-intrusive flow diagnostics are essential for studying the physics of hypersonic flow wake regions. To advance the development of next generation hypersonic vehicles and to improve computational fluid dynamics techniques in the hypersonic regime, NASA needs a suitable non-intrusive diagnostic technique to measure velocity, density, and temperature. We will present our work on developing a seedless, non-intrusive diagnostic technique using excited state argon atoms, prepared via multi-photon excitation. In this dissertation, we report results on the first phase of this hypersonic wake measurement project. In particular, we have redesigned and characterized the performance of a high energy, nanosecond pulsed Ti:Sapphire …

Control Of Spontanous Emission From Quantum Emitters Using Hyperbolic Metamaterial Substrates, Tal Galfsky

Dissertations, Theses, and Capstone Projects

Hyperbolic metamaterials (HMMs) are so named for possessing a hyperboloid-shaped dispersion which gives rise to a large photonic density of states. Quantum emitters placed inside or in the near-field of a HMM have been shown to exhibit strong enhancement of spontaneous emission due to the increase in available states. This thesis focuses on enhancing spontaneous emission of quantum emitters in optical frequencies by utilizing multilayered metal/dielectric composites that form these highly anisotropic metamaterials. In conjunction with the enhanced decay rate we experimentally demonstrate two methods for shaping and directing radiation trapped in the HMM into free space by employing a …

Fractional Charge Methods For Correcting Approximate Kohn-Sham Potentials, Darya N. Komsa

Electronic Thesis and Dissertation Repository

The Kohn-Sham density functional theory relies on approximating the exchange-correlation energy functional or the corresponding potential. The behavior of the exchange-correlation potential as a function of position in a system can be used to detect and correct deficiencies of the parent functional. The too-fast decay of the potentials derived from common density functionals is a major problem, because it causes inaccurate Rydberg excitation energies and erroneous fractional charges in dissociating molecules. An efficient method to correct the shape of the exchange-correlation potential was proposed by Gaiduk et al. [A. P. Gaiduk, D. S. Firaha, and V. N. Staroverov, Phys. Rev. …

Spectroscopic Imaging Of Aluminum Containing Plasma, David Michael Surmick

Doctoral Dissertations

This dissertation aims to characterize laser-induced plasma from a physics point of view as warm, dense matter. Use of nominal nanosecond pulsed laser radiation initiates a plasma with electron temperatures of the order of 10 electron volts and electron densities of the order of air species densities at standard ambient temperature and pressure. For laser ablation and/or optical breakdown at or near a solid surface, the electron density can amount to be 1000 times greater. Spectroscopic investigations of the plasma emissions provide a method by which the electron density, temperature, and shockwave expansion may be determined. Of particular interest are …

Hyperpolarized 3he Magnetic Resonance Imaging Phenotypes Of Chronic Obstructive Pulmonary Disease, Damien Pike

Electronic Thesis and Dissertation Repository

Chronic obstructive pulmonary disease (COPD) is the third leading cause of death in the world. Identifying clinically relevant COPD phenotypes has the potential to reduce the global burden of COPD by helping to alleviate symptoms, slow disease progression and prevent exacerbation by stratifying patient cohorts and forming targeted treatment plans. In this regard, quantitative pulmonary imaging with hyperpolarized 3He magnetic resonance imaging (MRI) and thoracic computed tomography (CT) have emerged as ways to identify and measure biomarkers of lung structure and function. 3He MRI may be used as a tool to probe both functional and structural properties of the lung …

Emergence Of Collective Light Scattering In Atomic 87Rb Samples, Kasie Jean Kemp

Physics Theses & Dissertations

Over the past half century, atomic ensembles have been used to create sensors, clocks, and quantum information systems. As these devices become more compact, and as the number of atoms increases to improve the sensitivity for detection, the atomic samples are increasing in density and optical depth. As such, the spectroscopic properties of the atomic media are modified due to interactions among the particles in the ensemble. We report investigation of near-resonance light scattering from a cold atomic sample of 87Rb. Initially prepared in a magneto-optical trap, the atoms are loaded into a far-off-resonance optical dipole trap (FORT) in which …

Vector Beams For Fundamental Physics And Applications, Giovanni Milione

Dissertations, Theses, and Capstone Projects

Lights salient degrees of freedom are the independent parameters that completely de- scribe an electromagnetic wave (in the paraxial approximation) and include polarization, wavelength, and time. Most recently, lights space degree of freedom has received sig- nificant attention via the sub-discipline of optics that can be referred to as complex light or structured light. The study of complex light is a veritable renaissance of optics; us- ing lights space degree of freedom many classical optics phenomena have been revisited with novel results. In this thesis, a novel form of structured light referred to as vector beams will be investigated. It …

Theoretical Analysis Of Single Molecule Spectroscopy Lineshapes Of Conjugated Polymers, Murali Devi

Dissertations, Theses, and Capstone Projects

Conjugated Polymers(CPs) exhibit a wide range of highly tunable optical properties. Quantitative and detailed understanding of the nature of excitons responsible for such a rich optical behavior has significant implications for better utilization of CPs for more efficient plastic solar cells and other novel optoelectronic devices. In general, samples of CPs are plagued with substantial inhomogeneous broadening due to various sources of disorder. Single molecule emission spectroscopy (SMES) offers a unique opportunity to investigate the energetics and dynamics of excitons and their interactions with phonon modes. The major subject of the present thesis is to analyze and understand room temperature …

Atomic Force Microscopy Of Poly(Ethylane-Oxide) Crystalization, Xavier Capaldi

Honors Theses

Polymer crystallization is a complex process which is influenced by a variety of factors. Atomic force microscopy is used to explore the material properties of polymer crystals. Poly(ethylene-oxide) is used in a variety of molecular weights as the sample. In addition, a variety of sample preparation methods and microscopy modes were tested. A relatively new imaging technique was identified for the characterization of polymer crystals: amplitude modulation-frequency modulation viscoelastic mapping. This mode was used to measure material properties such as stiffness and dissipation.

A Case For Chiral Contributions To Nondipole Effects In Photoionization Using Linearly Polarized Soft X-Rays, Kyle Patrick Bowen

UNLV Theses, Dissertations, Professional Papers, and Capstones

Modelling angular distributions of photoelectrons requires making accurate approximations of both the incoming light and the behavior of bound electrons. The experimental determination of photoelectron angular distributions is crucial to the development of accurate theoretical models governing the light-matter interaction. To date, many models have relied upon the dipole approximation, which assumes a constant electric field as the source of ionization. Despite knowing that the dipole approximation would break down as photon energy increased, the precise limit was unclear. Over the past two decades, a strong case has been made that corrections to the dipole approximation are necessary for accurately …

Spontaneous Parametric Down Conversion Of Photons Through Β-Barium Borate, Luke Horowitz

Physics

An apparatus for detecting pairs of entangled 405nm photons that have undergone Spontaneous Parametric Down Conversion through β-Barium Borate is described. By using avalanche photo-diodes to detect the low-intensity converted beam and a coincidence module to register coincident photons, it is possible to create an apparatus than can be used to perform quantum information experiments under a budget appropriate for an undergraduate physics lab.

Quantum Mechanical Interference In The Field Ionization Of Rydberg Atoms, Jacob A. Hollingsworth

Physics and Astronomy Honors Papers

Rydberg atoms are traditionally alkali metal atoms with their valence electron excited to a state of very large principle quantum number. They possess exaggerated properties, and are consequently an attractive area of study for physicists. An example of their exaggerated properties is seen in their response to the presence of an applied electric field. In this work, we study the energy distribution of Rydberg atoms when subjected to a dynamic electric field intended to ionize them.

We excite ⁸⁵Rb atoms to a superposition of the 46D_5/2 |m_j| = 1/2 and |m_j| = 3/2 states …

Using A Genetic Algorithm To Optimize An Electric Field Ionization Pulse, Tamas Budner

Physics and Astronomy Honors Papers

Experimentally, we would like to demonstrate the process of selective field ionization of electrons as evidence of quantum control in a system of ultracold rubidium-85 Rydberg atoms. In order to accomplish this, an electric field pulse which is optimized to take an initial Rydberg electron state and produce the desired ionization spectra is necessary. We utilize techniques from artificial intelligence to develop a genetic algorithm for the optimization process. Our algorithm is computationally tested on an artificially constructed quantum system consisting of four energy states. In evaluating the viability of any given field pulse, we calculate the probability of an …

The Role Of Continuum States In The Field Ionization Of Rydberg Atoms, Michael P. Vennettilli

Physics and Astronomy Honors Papers

In an experiment performed by our collaborators at Bryn Mawr, we excite rubidium-85 to a coherent superposition of the different |m_j| splittings of the 37d_5/2 state induced by a small electric field. After waiting for some variable delay time, we apply a time-dependent electric field to ionize the atom and record the ionized current that arrives at the detector. Due to the initial superposition, we observe an interference pattern that depends on the delay time. This thesis describes my continued work with Dr. Carroll to develop a computational model of this experiment. Our initial method …

Optical Characterization Of Anisotropic Interfaces, Renjie Hou

Electronic Thesis and Dissertation Repository

The understanding of optical properties of surfaces and interfaces are critical for the development of new technologies ranging from photonics to molecular electronics. Knowing for example the orientation of molecules functionalized onto a surface yields valuable information about the macroscopic properties of the resulting surface. The optical properties can be tuned using various strategies such as molecular functionalization or patterning of meta-structures that ultimately interact with light in a rational way. Advanced optical and spectroscopy methods allowing one to probe such surfaces are therefore key to correlate properties and surface functionalization.

In this thesis, multiple approaches have been taken to …

Tunable Controlled Release Of Molecular Species From Halloysite Nanotubes, Divya Narayan Elumalai

Doctoral Dissertations

Encouraged by potential applications in rust coatings, self-healing composites, selective delivery of drugs, and catalysis, the transport of molecular species through Halloysite nanotubes (HNTs), specifically the storage and controlled release of these molecules, has attracted strong interest in recent years. HNTs are a naturally occurring biocompatible nanomaterial that are abundantly and readily available. They are alumosilicate based tubular clay nanotubes with an inner lumen of 15 nm and a length of 600-900 nm. The size of the inner lumen of HNTs may be adjusted by etching. The lumen can be loaded with functional agents like antioxidants, anticorrosion agents, flame-retardant agents, …

Cebaf Upgrade Bunch Length Measurements, Mahmoud Mohamad Ali Ahmad

Physics Theses & Dissertations

Many accelerators use short electron bunches and measuring the bunch length is important for efficient operations. CEBAF needs a suitable bunch length because bunches that are too long will result in beam interruption to the halls due to excessive energy spread and beam loss. In this work, bunch length is measured by invasive and non-invasive techniques at different beam energies. Two new measurement techniques have been commissioned; a harmonic cavity showed good results compared to expectations from simulation, and a real time interferometer is commissioned and first checkouts were performed. Three other techniques were used for measurements and comparison purposes …

Plasma Processing Of Superconducting Radio Frequency Cavities, Janardan Upadhyay

Physics Theses & Dissertations

The development of plasma processing technology of superconducting radio frequency (SRF) cavities not only provides a chemical free and less expensive processing method, but also opens up the possibility for controlled modification of the inner surfaces of the cavity for better superconducting properties. The research was focused on the transition of plasma etching from two dimensional flat surfaces to inner surfaces of three dimensional (3D) structures. The results could be applicable to a variety of inner surfaces of 3D structures other than SRF cavities. Understanding the Ar/Cl₂ plasma etching mechanism is crucial for achieving the desired modification of Nb …

Ultrafast Spectroscopy And Energy Transfer In An Organic/Inorganic Composite Of Zinc Oxide And Graphite Oxide, Jeff A. Secor

Dissertations, Theses, and Capstone Projects

The energy transfers and nature of defect levels of an organic/inorganic composite of Zinc Oxide and Graphite are studied with multidimensional spectroscopy. The edge and surface states of each composite are uncovered using excitation emission experiments showing which defect states are mediating the energy transfer from the metal oxide to the graphite oxide. Multidimensional time resolved spectroscopy further describes the effect of the carbon phase on the energy transfer pathways in the material.

Zncdmgse As A Materials Platform For Advanced Photonic Devices: Broadband Quantum Cascade Detectors And Green Semiconductor Disk Lasers, Joel De Jesus

Dissertations, Theses, and Capstone Projects

The ZnCdMgSe family of II-VI materials has unique and promising characteristics that may be useful in practical applications. For example they can be grown lattice matched to InP substrates with lattice matched bandgaps that span from 2.1 to 3.5 eV, they can be successfully doped n-type, have a large conduction band offset (CBO) with no intervalley scattering present when strained, they have lower average phonon energies, and the InP lattice constant lies in the middle of the ZnSe and CdSe binaries compounds giving room to experiment with tensile and compressive stress. However they have not been studied in detail for …

Fully Differential Study Of Projectile Coherence Effects In Ionization Of Molecular Hydrogen And Atomic Helium, Thusitha Priyantha Arthanayaka

Doctoral Dissertations

"It has been well established, that projectile coherent properties are important for the study of atomic fragmentation processes. Recent studies of ionization of molecular hydrogen had demonstrated that measured double differential cross sections (DDCS) are very sensitive to the coherent length of the projectile. These measurements have been performed with varied coherence length of the projectiles by controlling the geometry of the collimating slits, which are placed before the target. Later, fully differential cross sections (FDCS) for a coherent and an incoherent projectile beam has been study for the same collision system and the results confirmed the important role of …

Non-Conventional Approaches To Syntheses Of Ferromagnetic Nanomaterials, Dustin M. Clifford

Theses and Dissertations

The work of this dissertation is centered on two non-conventional synthetic approaches to ferromagnetic nanomaterials: high-throughput experimentation (HTE) (polyol process) and continuous flow (CF) synthesis (aqueous reduction and the polyol process). HTE was performed to investigate phase control between Fe_xCo_1-x and Co_3-xFe_xO_y. Exploration of synthesis limitations based on magnetic properties was achieved by reproducing M_s=210 emu/g. Morphological control of Fe_xCo_1-x alloy was achieved by formation of linear chains using an H_ext. The final study of the Fe_xCo_1-x chains used DoE to …

Force Field Development With Gomc A Fast New Monte Carlo Molecular Simulation Code, Jason Richard Mick

Wayne State University Dissertations

In this work GOMC (GPU Optimized Monte Carlo) a new fast, flexible, and free molecular Monte Carlo code for the simulation atomistic chemical systems is presented. The results of a large Lennard-Jonesium simulation in the Gibbs ensemble is presented. Force fields developed using the code are also presented. To fit the models a quantitative fitting process is outlined using a scoring function and heat maps. The presented n-6 force fields include force fields for noble gases and branched alkanes. These force fields are shown to be the most accurate LJ or n-6 force fields to date for these compounds, capable …

Resonant Collisions Of Potassium Atoms, Philip Michael Adamson

Honors Theses

This thesis discusses an approach to excite potassium atoms to very highly excited states (Rydberg states), and then tune their energy levels to induce resonant collisions between atoms. Potassium gas is super-cooled to 1 mK and confined to a small volume in a magneto-optical trap. A 405 nm laser diode, electronically locked to a potassium vapor cell via Doppler free spectroscopy, excites these atoms from the 4s_1/2 state (ground state) to the 5p_3/2 state. A 978 nm laser then excites the 5p_3/2 to nd_3/2 or nd_5/2 transition, creating Rydberg atoms. Since there is no ground …

Photovoltaics: An Investigation Into The Origins Of Efficiency On All Scales, Jeremy Alexander Bannister

Senior Projects Spring 2016

This project is comprised of a set of parallel investigations, which share the common mo- tivation of increasing the efficiency of photovoltaics. First, the reader is introduced to core concepts of photovoltaic energy conversion via a semi-classical description of the phys- ical system. Second, a key player in photovoltaic efficiency calculations, the exciton, is discussed in greater quantum mechanical detail. The reader will be taken through a nu- merical derivation of the low-energy exciton states in various geometries, including a line segment, a circle and a sphere. These numerical calculations are done using Mathematica, a computer program which, due to …

Beyond Conventional C-Plane Gan-Based Light Emitting Diodes: A Systematic Exploration Of Leds On Semi-Polar Orientations, Morteza Monavarian

Theses and Dissertations

Despite enormous efforts and investments, the efficiency of InGaN-based green and yellow-green light emitters remains relatively low, and that limits progress in developing full color display, laser diodes, and bright light sources for general lighting. The low efficiency of light emitting devices in the green-to-yellow spectral range, also known as the “Green Gap”, is considered a global concern in the LED industry. The polar c-plane orientation of GaN, which is the mainstay in the LED industry, suffers from polarization-induced separation of electrons and hole wavefunctions (also known as the “quantum confined Stark effect”) and low indium incorporation efficiency that …

Electronic Structure And Stability Of Ligated Superatoms And Bimetallic Clusters, William H. Blades

Theses and Dissertations

Quantum confinement in small metal clusters leads to a bunching of states into electronic shells reminiscent of shells in atoms. The addition of ligands can tune the valence electron count and electron distribution in metal clusters. A combined experimental and theoretical study of the reactivity of methanol with Al_nI_m⁻ clusters reveals that ligands can enhance the stability of clusters. In some cases the electronegative ligand may perturb the charge density of the metallic core generating active sites that can lead to the etching of the cluster. Also, an investigation is conducted to understand how the bonding …

Up-Converted Emissions Of Er3+ Doped Gd2(Wo4)3 Phosphors, Grayson L. Wiggins

Electronic Theses and Dissertations

In this work, the up-conversion (UC) emissions of Er3+ in a gadolinium tungstate host was investigated to analyze the possible processes of up-conversion by 1500 nm and 980 nm excitation. Studies were conducted to see how the 4S3/2 -> 4I15/2 transition changed with varying current through the excitation source, varying excitation wavelength, and doping concentration. Power dependent studies revealed that under 1500 nm excitation the 4S3/2 -> 4I15/2 transition needed 3 photons, while 980 nm excitation could do the same transition with 2 photons. It was found that 1500 nm could produce more efficient red emission due to the 4I9/2 …