Physical Sciences and Mathematics Commons^™

Aircraft-Based Measurements For The Identification And Quantification Of Sources And Sinks In The Carbon Cycle, Dana R Caulton

Open Access Dissertations

Improved quantification of carbon-cycle sources and sinks is an important requirement for determining mitigation strategies and modeling future climate interactions. Analytically robust measurements require high-precision instrumentation and thoughtful experimental design to produce rigorous and reproducible results despite complex and quickly changing meteorological and environmental conditions. Here, an aircraft platform equipped with a high-precision cavity ring-down spectrometer for CO₂, CH₄ and H₂O quantification was used to acquire data from previously un-sampled sources. The aircraft mass-balance technique was used to quantify CH4 emissions from natural gas well pads in the drilling stage, which were 2-3 orders of …

Towards A Paradigm Shift In The Modeling Of Soil Organic Carbon Decomposition For Earth System Models, Yujie He

Open Access Dissertations

Soils are the largest terrestrial carbon pools and contain approximately 2200 Pg of carbon. Thus, the dynamics of soil carbon plays an important role in the global carbon cycle and climate system. Earth System Models are used to project future interactions between terrestrial ecosystem carbon dynamics and climate. However, these models often predict a wide range of soil carbon responses and their formulations have lagged behind recent soil science advances, omitting key biogeochemical mechanisms. In contrast, recent mechanistically-based biogeochemical models that explicitly account for microbial biomass pools and enzyme kinetics that catalyze soil carbon decomposition produce notably different results and …

Upscale Feedbacks Observed And Modeled During The Mesoscale Predictability Experiment, Joseph M. Woznicki

Open Access Theses

All modes of deep convective storms perturb their local environment on temporal and spatial scales that are larger than the storm itself. Such upscale feedbacks associated with the mesoscale convective systems (MCSs) are well known; much less is known about the feedbacks associated with supercell thunderstorms that, like MCSs, represent a highly organized convective mode. Data from the Mesoscale Predictability Experiment (MPEX), in addition to CM1 model simulations, provide the means to quantify these upscale feedbacks and determine their relative influence on the subsequent predictability of the atmosphere. The 700-500 mb lapse rate (MLR), mean-layer CAPE up to 475 mb …

Assessing Inland Hazards Associated With Hurricanes In The U.S. Atlantic Basin, Dereka Latrese Carroll

Open Access Theses

The skill of tropical-cyclone (TC) track forecasts has steadily improved over the past decades, as has the understanding of TC risk in coastal regions. However, there is still much to be learned about the TC risk in inland regions, which is complicated by the presence of coastal evacuees, and includes hazards such as inland flash flooding and tornadoes. This was exemplified by Hurricane Ivan (2004), which spawned 118 tornadoes and produced significant rainfall amounts contributing to flooding inland. Ivan was responsible for 25 deaths in the U.S. and $18.8 billion (2004 USD) in damages. As part of a larger effort …

Cosmogenic Beryllium Cycling In A Natural Forest Setting, Grace Conyers

Open Access Theses

10 Bemet , or cosmogenic beryllium, has a long half-life of 1.4 million years and quick adsorption on soil particles, which may make it ideal for dating soil erosion in historical context. However, there are questions on about the fundamental assumptions of the retentivity of 10 Bemet . This manuscript explores these assumptions and the context of nutrient cycling in a natural forest setting.

To see if 10 Bemet was being cycled through the trees, and at what rate, we looked at the[10 Bemet ] in the soil, 4 species of trees, and their leaves. The isotopic ratio 10 Be/9 …

Investigation Of Isotope Effects Of Ozone As A Function Of Temperature, Daniel J. Mcmahon

Open Access Theses

Ozone is an important oxidizer in the atmosphere and plays a crucial role as a cleanser, removing various compounds such NOx and SOx. It also is intriguing to those that study stable isotopes as it has a unique signature found in no other oxygen containing molecule. Ozone is observed to fractionate mass independently, which means it does not follow the typical δ 17 O /δ18 O = 0.52 ratio expected for molecules enriched with 17 O and 18 O. The magnitude of ozone's mass independent enrichment has been studied in laboratory experiments and atmospheric observations but its explanation is still …

Evaluation And Economic Value Of Winter Weather Forecasts, Derrick William Snyder

Open Access Theses

State and local highway agencies spend millions of dollars each year to deploy winter operation teams to plow snow and de-ice roadways. Accurate and timely weather forecast information is critical for effective decision making. Students from Purdue University partnered with the Indiana Department of Transportation to create an experimental winter weather forecast service for the 2012-2013 winter season in Indiana to assist in achieving these goals. One forecast product, an hourly timeline of winter weather hazards produced daily, was evaluated for quality and economic value.

Verification of the forecasts was performed with data from the Rapid Refresh numerical weather model. …