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Full-Text Articles in Physical Sciences and Mathematics
A Diffuse Reflectance Infrared Fourier Transform Spectroscopic Investigation Of The Oxidation Of Co On Platinum/Tin(Iv) Oxide-Based Catalysts, Julie Christi Stiltner Patrick
A Diffuse Reflectance Infrared Fourier Transform Spectroscopic Investigation Of The Oxidation Of Co On Platinum/Tin(Iv) Oxide-Based Catalysts, Julie Christi Stiltner Patrick
Chemistry & Biochemistry Theses & Dissertations
Platinum/tin(IV) oxide-based catalysts have been developed for the oxidation of carbon monoxide at 55 °C and 1 atmosphere pressure. A diffuse reflectance infrared fourier transform spectroscopic (DRIFTS) investigation of this oxidation has been performed. Four catalyst samples have been subjected to a 5% carbon monoxide pretreatment at 125 °C, helium exposure at 55 °C, bottled air (20% oxygen) exposure at 55 °c, and exposure to a 2:1 stoichiometric mixture of carbon monoxide and oxygen at 55 °C. During the course of these exposures, evidence for the development of two different surface carbon monoxide configurations has been found: one that is …
Periodic And Homoclinic Orbits In A Toy Climate Model, M. Toner, A. D. Kirwan Jr.
Periodic And Homoclinic Orbits In A Toy Climate Model, M. Toner, A. D. Kirwan Jr.
Mathematics & Statistics Faculty Publications
A two dimensional system of autonomous nonlinear ordinary differential equations models glacier growth and temperature changes on an idealized planet. We apply standard perturbative techniques from dynamical systems theory to study small amplitude periodic orbits about a constant equilibrium. The equations are put in cononical form and the local phase space topology is examined. Maximum and minimum periods of oscillation are obtained and related to the radius of the orbit. An adjacent equilibrium is shown to have saddle character and the inflowing and outflowing manifolds of this saddle are studied using numerical integration. The inflowing manifolds show the region of …
Invariant Manifolds Of A Toy Climate Model, Michael Toner
Invariant Manifolds Of A Toy Climate Model, Michael Toner
Mathematics & Statistics Theses & Dissertations
According to astronomical theory, ice ages are caused by variations in the Earth's orbit. However, ice core data shows strong fluctuations in ice volume at a low frequency not significantly present in orbital variations. To understand how this might occur, the dynamics of a two dimensional nonlinear differential equation representing glacier/temperature interaction of an idealized climate was studied. Self sustained oscillation of the autonomous equation was used to model the internal mechanisms that could produce these fluctuations. Periodic parametric modulation of a damped internal oscillation was used to model periodic climate response at double the external modulation period. Both phenomena …