Physical Sciences and Mathematics Commons^™

Spectroscopy Of Atmospheres, Randika Dodangodage

Physics Theses & Dissertations

Spectroscopic methods are used to study planetary and stellar atmospheres. The information obtained from spectroscopic studies provides insight into atmospheric compositions and dynamics, which can be used to model and characterize atmospheres and climates. Laboratory-recorded absorption cross-sections are needed to interpret the recorded spectra of planets and stars. High resolution ethane, neopentane, propene, and n-butane spectra have been recorded, and absorption cross-sections have been provided for different temperatures and total pressures with different broadening gases, including hydrogen, helium, and nitrogen. The Atmospheric Chemistry Experiment (ACE) satellite orbits Earth and records spectra through solar occultation limb observations. HOCl is a chlorine …

A Comparative Study Of Vinti-Based Orbit Propagation And Estimation For Cubesats In Very Low Earth Orbits, Ethan Michael Senecal

Mechanical & Aerospace Engineering Theses & Dissertations

In recent years, there has been a growing interest in CubeSats and very low Earth orbit (VLEO) space missions. Mission SeaLion, a collaborative CubeSat mission between Old Dominion University, the U.S. Coast Guard Academy, and U.S. Air Force Institute of Technology, planned to launch a 3U CubeSat into VLEO. The VLEO mission is a particularly challenging environment for navigation and orbit propagation because drag introduces a significant perturbation for orbit models such as SGP4. Additionally, mission requirements left no capacity for attitude determination or control, further reducing knowledge of drag behavior of the satellite in flight. This deficiency is a …

Spectra Of Atmospheric And Astronomical Molecules, W. D. Cameron

Physics Theses & Dissertations

Spectroscopy techniques are focused on spectra of molecules of interest to the Earth’s atmosphere and/or astronomy and astrophysics. Laboratory spectroscopy as well as remote satellite sensing are applied. Using the Fourier transform spectrometer aboard the Atmospheric Chemistry Experiment (ACE) satellite to measure the absorption spectra of the Earth’s atmosphere through solar occultation limb observation demonstrates that volcanic eruption plumes can be located and tracked through their SO₂ content. The presence of those plumes is corroborated by overlaying infrared atmospheric aerosol extinction observed by the 1 μm imager on the same satellite. Tracking atmospheric aerosol movement with the ACE …

A New Method For Estimating The Physical Characteristics Of Martian Dust Devils, Shelly Cahoon Mann

Mechanical & Aerospace Engineering Theses & Dissertations

Critical to the future exploration of Mars is having a detailed understanding of the atmospheric environment and its potential dangers. The dust devil is one of these potential dangers. The transport of dust through saltation is believed to be the driving mechanism responsible for Martian weather patterns. The two primary mechanisms for dust transport are dust storms and dust devils. Dust devils on Mars are a frequent occurrence with one in five so called giant dust devils being large enough to leave scars on the surface that are visible from space. Due to the thin atmosphere, winds of 60 mph …

Trend Analyses Of The Abundances Of Atmospheric Molecules, Anton Fernando

Physics Theses & Dissertations

A new line list for the A³Π - X³Σ- electronic transition of NH has been prepared using line positions from the literature and calculated line intensities. High level ab initio calculations were performed with the MOLPRO program to obtain the A - X transition dipole moment function. Potential energy curves and line strengths were calculated with Le Roy's RKR1 and LEVEL programs. Line intensities and Einstein A values were calculated with Western's PGOPHER program after converting the Hund's case (b) output of LEVEL to Hund's case (a) input needed for PGOPHER. The Herman- Wallis effect is …

Statistical Analysis And Comparison Of Optical Classification Of Atmospheric Aerosol Lidar Data, Kwasi Gyening Afrifa

Electrical & Computer Engineering Projects for D. Eng. Degree

This dissertation presents a new study for the analysis and classification of atmospheric aerosols in remote sensing LIDAR data. Information on particle size and associated properties are extracted from these remote sensing atmospheric data which are collected by a ground-based LIDAR system. This study first considers optical LIDAR parameter-based classification methods for clustering and classification of different types of harmful aerosol particles in the atmosphere. Since accurate methods for aerosol prediction behaviors are based upon observed data, computational approaches must overcome design limitations, and also consider appropriate calibration and estimation accuracy. Consequently, two statistical methods based on generalized linear models …

Improved Ballistic Wind Prediction Using Projectile Tracking Data, William Arthur Kenney

Computational Modeling & Simulation Engineering Theses & Dissertations

The United States Air Force AC-130 gunships have been in operation since the Vietnam War and have seen frequent use during recent conflicts. They are able to employ gun weapon systems from above a target in a way that maximizes possible time on target. When firing, the gun operators must deal with miss distances caused by winds acting on the projectile in flight. Operators currently perform a “tweak” to predict a ballistic wind affecting fired rounds which is then used in the fire-control to correct for the real winds and bring shots onto target. This correction, a single-point wind prediction, …

Observations Of Greenhouse Gas Isotopologues With Ace-Fts And Waccm, Eric Michael Buzan

Chemistry & Biochemistry Theses & Dissertations

Increases in greenhouse gas concentrations in the atmosphere are the major driver of climate change. Quantifying the sources and sinks of these gases is a major focus of research. Measuring isotopologues, or molecules that differ in isotopic composition, is one useful way of constraining the budget of a molecule as they are highly sensitive to different sources and sinks. However, measurements above the surface have been restricted to a few locations and have only reached the lower stratosphere. Satellite-based remote sensing can achieve nearly global measurement coverage, but so far no satellites have measured isotopologues.

Presented here are measurements of …

High Resolution Spectra Of Carbon Monoxide, Propane And Ammonia For Atmospheric Remote Sensing, Christopher Andrew Beale

OES Theses and Dissertations

Spectroscopy is a critical tool for analyzing atmospheric data. Identification of atmospheric parameters such as temperature, pressure and the existence and concentrations of constituent gases via remote sensing techniques are only possible with spectroscopic data. These form the basis of model atmospheres which may be compared to observations to determine such parameters. To this end, this dissertation explores the spectroscopy of three molecules: ammonia, propane and carbon monoxide.

Infrared spectra have been recorded for ammonia in the region 2400-9000 cm^-1. These spectra were recorded at elevated temperatures (from 293-973 K) using a Fourier Transform Spectrometer (FTS). Comparison between …

A Predictor Analysis Framework For Surface Radiation Budget Reprocessing Using Design Of Experiments, Patricia Allison Quigley

Engineering Management & Systems Engineering Theses & Dissertations

Earth’s Radiation Budget (ERB) is an accounting of all incoming energy from the sun and outgoing energy reflected and radiated to space by earth’s surface and atmosphere. The National Aeronautics and Space Administration (NASA)/Global Energy and Water Cycle Experiment (GEWEX) Surface Radiation Budget (SRB) project produces and archives long-term datasets representative of this energy exchange system on a global scale. The data are comprised of the longwave and shortwave radiative components of the system and is algorithmically derived from satellite and atmospheric assimilation products, and acquired atmospheric data. It is stored as 3-hourly, daily, monthly/3-hourly, and monthly averages of 1°x1° …

Source-Specific Molecular Signatures For Light-Absorbing Organic Aerosols, Amanda Susan Willoughby

Chemistry & Biochemistry Theses & Dissertations

Organic aerosols (OA) are universally regarded as an important component of the atmosphere based on quantitative significance as well as the far-reaching impact they have on global climate forcing and human health. Despite the acknowledged importance, OA amounts and impacts remain the largest uncertainties regarding radiative forcing estimates. Incomplete chemical characterization of aerosol organic matter (OM) and a lack of concrete source apportionment is a major source of this uncertainty. The primary focus of this study is to provide much needed molecular details regarding ambient OA from key emission sources, and establish links between molecular and optical properties.

Complete chemical …

The Effect Of An Offshore Wind Turbine Array On Circulation In An Idealized Coastal Ocean, Mahmoud Kamel

OES Theses and Dissertations

The effect of arrays of wind turbines on circulation in the coastal ocean is analyzed with a coastal numerical model applied to a shallow coastal area like the Mid Atlantic Bight (MAB). A simplified model domain is specified with a linearly deepening shelf along a straight coastline. The initial density structure is a quasi-two layer situation with a sharp thermocline. Wind stress in most of the cases is either upwelling or downwelling favorable with constant amplitude continuing after a smooth start. There are two cases where oscillating wind forcing is used. Simulations consider wind arrays having different widths, different locations …

Balloon Borne Mars Research Platforms, Sean Michael Hancock

Mechanical & Aerospace Engineering Theses & Dissertations

Aerial platforms can fill a measurement gap between orbiters and rovers, providing planetary scale high resolution in situ measurements, access to scientifically interesting terrain that is either inaccessible or hazardous to rovers, and serve as a planet-wide delivery platforms to deploy surface probes and rovers to areas inaccessible given existing entry, descent, and landing systems. A permanent robotic outpost on the Martian surface can utilize locally-derived hydrogen as a lifting gas for balloon systems deployed from Mars. That approach can simplify the inflation and launch of aerial vehicles while allowing for a long duration deployment campaign that is not constrained …

Measurement Of Proton Transfer Reaction Rates In A Microwave Cavity Discharge Flowing Afterglow, George M. Brooke Iv

Physics Theses & Dissertations

The reaction rate coefficients between the hydronium ion and the molecules ethene (C₂H₄), propene (C₃H₆), 1-butene (C₄H₈) and hydrogen sulfide (H₂S) were measured at 296 K. The measured reaction rates were compared to collision rates calculated using average dipole orientation (ADO) theory. Reaction efficiency depends primarily upon the proton affinity of the molecules. All the measurements were obtained using the newly developed microwave cavity discharge flowing afterglow (MCD-FA) apparatus. This device uses an Asmussen-type microwave cavity discharge ion source that is …

Sea Level Slopes And Volume Fluxes Produced By Atmosphere Forcing In Chesapeake Bay, David Salas Monreal

OES Theses and Dissertations

Year long time series at eight stations in the Chesapeake Bay and inner shelf were used to determine the relative influence of wind, barometric pressure and thermosteric effects on subtidal sea level variability and slopes. Special emphasis was placed on the lower Chesapeake Bay, where inverse barometric effects accounted for up to 33% of the subtidal sea level variations and thermosteric effects accounted for less than 1 % of the variations. The greatest thermosteric influence was noted at the southernmost, saltier and shallower location (Chesapeake Bay Bridge Tunnel). Wind forcing accounted for most of this station's variability, making up more …

Coherent Differential Absorption Lidar For Combined Measurement Of Wind And Trace Atmospheric Gases, Grady James Koch

Electrical & Computer Engineering Theses & Dissertations

A lidar system was developed for making combined range-resolved measurements of wind speed and direction, water vapor concentration, and carbon dioxide concentration in the atmosphere. This lidar combines the coherent Doppler technique for wind detection and the differential absorption lidar (DIAL) technique to provide a multifunctional capability. DIAL and coherent lidars have traditionally been thought of and implemented as separate instruments, but the research reported here has shown a demonstration of combining the coherent and DIAL techniques into a single instrument using solid-state lasers. The lasers used are of Ho:Tm:YLF, which operates at a wavelength of 2 μm. This wavelength …

Advanced Atmospheric Water Vapor Dial Detection System, Tamer Refaat

Electrical & Computer Engineering Theses & Dissertations

Measurement of atmospheric water vapor is very important for understanding the Earth's climate and water cycle. The remote sensing Differential Absorption Lidar (DIAL) technique is a powerful method to perform such measurement from aircraft and space. This thesis describes a new advanced detection system, which incorporates major improvements regarding sensitivity and size. These improvements include a low noise advanced avalanche photodiode detector, a custom analog circuit, a 14-bit digitizer, a microcontroller for on board averaging and finally a fast computer interface.

This thesis describes the design and validation of this new water vapor DIAL detection system which was integrated onto …

Inversion And Analysis Of Remotely Sensed Atmospheric Water Vapor Measurements At 940nm, Jack Cutler Larsen

Mechanical & Aerospace Engineering Theses & Dissertations

The understanding and acceptance of remotely sensed atmospheric data depends strongly on the steps taken to characterize experiment error and validate observations through comparisons to other independent measurements. A formal error analysis of the Stratospheric Aerosol and Gas Experiment II (SAGE II) water vapor operational inversion algorithm is performed and compared to previous results. Random measurement errors were characterized by segmented least-squares profile fitting of the slant path absorption which found the error to be uncorrelated in the stratosphere with estimated variances significantly smaller than expected from 18-30 km. Estimates of null space error were developed from radiosonde hygrometers in …

A Feasibility Study Of Dynamical Assimilation Of Tide Gauge Data In The Chesapeake Bay, Yvette H. Spitz

OES Theses and Dissertations

The feasibility of dynamical assimilation of surface elevation from tide gauges is investigated to estimate the bottom drag coefficient and surface stress as a first step in improving modeled tidal and wind-driven circulation in the Chesapeake Bay. A two-dimensional shallow water model and an adjoint variational method with a limited memory quasi-Newton optimization algorithm are used to achieve this goal.

Assimilation of tide gauge observations from ten permanent stations in the Bay and use of a two-dimensional model adequately estimate the bottom drag coefficient, wind stress and surface elevation at the Bay mouth. Subsequent use of these estimates in the …

Dynamics Of Dipoles In The Middle Atlantic Bight, Bruce L. Lipphardt Jr.

OES Theses and Dissertations

Beginning with the observations made by the Warm-Core Rings program in the early 1980's, several Gulf Stream warm-core rings (WCR's) in the Middle Atlantic Bight (MAB) have been observed with one or more cyclones around their periphery. These ring systems are observed in the slope water between the Gulf Stream's western boundary and the shelf break. Observations of ring systems have motivated a reanalysis of existing satellite surface temperature imagery, which revealed that multipole structure is common for both warm and cold core rings. This suggests that rings are better characterized as one part of multipole systems rather than as …

A Diffuse Reflectance Infrared Fourier Transform Spectroscopic Investigation Of The Oxidation Of Co On Platinum/Tin(Iv) Oxide-Based Catalysts, Julie Christi Stiltner Patrick

Chemistry & Biochemistry Theses & Dissertations

Platinum/tin(IV) oxide-based catalysts have been developed for the oxidation of carbon monoxide at 55 °C and 1 atmosphere pressure. A diffuse reflectance infrared fourier transform spectroscopic (DRIFTS) investigation of this oxidation has been performed. Four catalyst samples have been subjected to a 5% carbon monoxide pretreatment at 125 °C, helium exposure at 55 °C, bottled air (20% oxygen) exposure at 55 °c, and exposure to a 2:1 stoichiometric mixture of carbon monoxide and oxygen at 55 °C. During the course of these exposures, evidence for the development of two different surface carbon monoxide configurations has been found: one that is …

Invariant Manifolds Of A Toy Climate Model, Michael Toner

Mathematics & Statistics Theses & Dissertations

According to astronomical theory, ice ages are caused by variations in the Earth's orbit. However, ice core data shows strong fluctuations in ice volume at a low frequency not significantly present in orbital variations. To understand how this might occur, the dynamics of a two dimensional nonlinear differential equation representing glacier/temperature interaction of an idealized climate was studied. Self sustained oscillation of the autonomous equation was used to model the internal mechanisms that could produce these fluctuations. Periodic parametric modulation of a damped internal oscillation was used to model periodic climate response at double the external modulation period. Both phenomena …

Heat Storage And Transport Processes In The Tropical Atlantic Ocean, Andras Kapolnai

OES Theses and Dissertations

Heat storage and transport processes of the tropical Atlantic play an important role in the climate of three continents. The exploration of how the warm water mass maintenance in the equatorial basin depends on various external factors is therefore an important task. This study examines the annual cycle of the warm water mass formation and its transport in the equatorial Atlantic through the interaction of the atmospheric and oceanic boundary layers. Key features of the model are the sea level wind field, equatorial upwelling rate and escape transport of the formed warm water out of the equatorial basin.

The model …

Optimization Of The Tungstic Acid Denuder Technique For The Measurement Of Atmospheric Ammonia, Patricia Diane Roberts

Chemistry & Biochemistry Theses & Dissertations

Measurement of - atmospheric ammonia with the tungstic acid denuder technique is discussed. Characterization of denuder tubes for manual sampling in terms of, repeatability, reliability and the development of ammonia blank signals was determined. Field testing of the manual sampling apparatus was performed at ground test sites and in a biomass burn smoke plume. Ammonia emissions from biomass burning are discussed.

Storm Surge Predictions At Sewell's Point With Local Wind, Pressure, And Previous Surge As Surge Predictors In Chesapeake Bay, Joy Elaine Moses

OES Theses and Dissertations

The statistical model used to predict storm surge. which is defined as the difference between observed water level and predicted astronomical tide. at Sewell's Point. Virginia. for the last ten years relies on forecast surface air pressures interpolated over a large portion of the Atlantic Ocean. A variation on this method is developed which adds previous station surge and local wind and pressure terms with time leads up to 18 hours to the Pore prediction for surge. and develops surge prediction equations for three substations eight to 65 miles (13 to 105 km) from Sewell's Point. The Sewell's Point surge …

The Apparent Dissociation Constants Of Carbonic Acid In Low Salinity Waters, Ching-Hui Hsu

OES Theses and Dissertations

The first and second apparent dissociation constants of carbonic acid in artificial seawater and diluted artificial seawater, K₁ ' and K₂ 1 were determined at selected combinations of temperatures and salinities between 2 to 30° C and 0 to 35 o/oo with special attentions to waters with salinities below 20 o/oo at atmospheric pressure by measuring K₁ ' and the product of K₁ ' and K₂.

The results can be expressed as functions of temperature and salinity by the following equations, pK₁ '=3360.206T^-1 +0. 033331 T-14.8303-0.09633x (Cl^1/2) pK₂ '=14911.671 …

A Study Of Increased Flow Off The Eastern Seaboard Of The United States Within Four Synoptic Flow Patterns During The Winter Months, John Dale Liechty

OES Theses and Dissertations

A study of increased winds during the winter season off the United States Eastern Seaboard was made in each of four synoptic flow patterns: prefrontal; postfrontal; northeast; and southerly. Eight years of synoptic data for the months October through March from two pairs of stations were utilized. Each pair consisted of one land and one sea station; of the sea stations, Frying Pan Light was located in or near the warmer water of the Gulf Stream while Chesapeake Light was situated in colder, coastal water. Both land stations were situated in the vicinity of the coast.

A statistical analysis was …

Variability Of Atmospheric Hydrocarbon Concentrations And Deposition Rates, Charles Thomas Farmer

OES Theses and Dissertations

The atmospheric hydrocarbon concentration was determined at various locations throughout Southeastern Virginia from July 1981 to February 1983. During this period the concentration ranged from 0.4 to 5.5 μg/m³ . From October 1982 to February 1983, WET and dry deposition samples were collected in conjunction with these air samples. Total hydrocarbon dry deposition rates ranged from deposition rates ranged from 4 to 189 μg/m² /day, while WET 22 to 670 μg/m² /day. Hydrocarbon concentrations found were within the ranges reported in the literature for wet, dry and atmospheric hydrocarbon concentrations.

Linear trend analysis revealed no correlation between …

The Temporal And Spatial Distribution Of Hydrocarbons In Atmospheric Deposition From Stations Surrounding Lower Chesapeake Bay, David Benjamin Webber

OES Theses and Dissertations

Hydrocarbon concentrations were determined in bulk, wet, and dry deposition samples from urban and non-urban locations surrounding lower Chesapeake Bay. Mean hydrocarbon concentrations in bulk deposition samples were over three times greater at the urban station indicating a localized source. The major hydrocarbons present were n-alkanes, polycyclic aromatic hydrocarbons (PAH), and the unresolved complex mixture (UCM). The PAH and the UCM were an indication of significant anthropogenic inputs while the odd/even distribution of the n-alkanes was an indication of biogenic sources. These findings indicated seasonal trends of highest biogenic hydrocarbon inputs in the spring and summer months and highest anthropogenic …

Numerical Model Simulation Of Offshore Flow During The Winter Season, Maria Cintia Piccolo

OES Theses and Dissertations

Because of the step function variability of heat and moisture flux in coastal zones, adequate descriptive models of mesoscale coastal circulation and weather patterns demand high spatial resolution in the analysis of wind, temperature and moisture patterns. To obtain realistic concepts of offshore flow the sparse offshore data networks need to be supplemented by mesoscale numerical models. The problems associated with the modeling of offshore flow across the east coast of the United States during the winter season have been investigated with a simple two dimensional numerical model of the planetary boundary layer.

The model has two predictive equations for …