Physical Sciences and Mathematics Commons^™

Hot Methane Line Lists For Exoplanet And Brown Dwarf Atmospheres, Robert J. Hargreaves, Christopher A. Beale, Laurent Michaux, Melis Irfan, Peter F. Bernath

Chemistry & Biochemistry Faculty Publications

We present comprehensive experimental line lists of methane (CH₄) at high temperatures obtained by recording Fourier transform infrared emission spectra. Calibrated line lists are presented for the temperatures 300-1400°C at twelve 100°C intervals spanning the 960-5000 cm^-1 (2.0-10.4 μm) region of the infrared. This range encompasses the dyad, pentad, and octad regions, i.e., all fundamental vibrational modes along with a number of combination, overtone and hot bands. Using our CH₄ spectra, we have estimated empirical lower state energies (E_low in cm^-1) and our values have been incorporated into the line lists along …