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Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

Arts and Humanities

2017

Butler University

Prussian white formation

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Spectroscopic Analysis Of The Traditional Cyanotype Process And Its Impact On Art, Jacob Applegarth Jan 2017

Spectroscopic Analysis Of The Traditional Cyanotype Process And Its Impact On Art, Jacob Applegarth

Undergraduate Honors Thesis Collection

Reflectance spectroscopy was used to study the cyanotype printing process. Originally this process was used to make photocopies of building designs, but today it is used for art. The cyanotype process is a photo catalyzed oxidation-reduction reaction. This study altered the concentrations and reagents involved in the printing process, and it included the use of ammonium ferricyanide and ammonium iron(III) oxalate along with the traditional potassium ferricyanide and ammonium iron(III) citrate. The impact of these changes on the rate of formation of Prussian blue was observed and quantified. Rate laws and general trends were determined for the reagents involved. Qualitative …