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Physical Sciences and Mathematics Commons™
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Full-Text Articles in Physical Sciences and Mathematics
Structural Diversity In Crystal Chemistry: Rational Design Strategies Toward The Synthesis Of Functional Metal-Organic Materials, Amy J. Cairns
Structural Diversity In Crystal Chemistry: Rational Design Strategies Toward The Synthesis Of Functional Metal-Organic Materials, Amy J. Cairns
USF Tampa Graduate Theses and Dissertations
Metal-Organic Materials (MOMs) represent an important class of solid-state crystalline materials. Their countless attractive attributes make them uniquely suited to potentially resolve many present and future utilitarian societal challenges ranging from energy and the environment, all the way to include biology and medicine. Since the birth of coordination chemistry, the self-assembly of organic molecules with metal ions has produced a plethora of simple and complex architectures, many of which possess diverse pore and channel systems in a periodic array. In its infancy however this field was primarily fueled by burgeoning serendipitous discoveries, with no regard to a rational design approach …
Metal-Organic Materials: From Design Principles To Practical Applications, Mohamed H. Alkordi
Metal-Organic Materials: From Design Principles To Practical Applications, Mohamed H. Alkordi
USF Tampa Graduate Theses and Dissertations
The works presented herein outline rational design approaches towards construction of solid state materials with great potentials to answer some of current demanding applications. Specifically, the materials targeted are metal−organic materials with desirable structural features and functional properties. Metal−organic materials are constructed from organic linker molecules and metal ions under relatively mild solvothermal reaction conditions that preserve the structural features of the relatively simple building blocks. Therefore, it is feasible to conceive a retrospective pathway of the reaction and thus deconstruct the desirable structures into simple, chemicallyrelevant, building blocks in an approach known as the molecular building block approach. Due …