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Electrochemiluminescence Of A Di-Boron Complex, Perovskite And Carbon Quantum Dots, Jonathan M. Wong

Electronic Thesis and Dissertation Repository

The electrochemiluminescence (ECL) of three novel materials was explored in this thesis. A di-boron complex exhibiting crystallization-induced blue shift emission was detected utilizing photoluminescence. This phenomenon was successfully observed in the annihilation pathway, resulting in crystallization-induced blue shift ECL. The effects of coreactant and crystallization-induced enhancements were distinguished utilizing two testing systems. Undoped and Mn-doped CsPbCl₃ perovskites were investigated, as the latter exhibits a dual emissive photoluminescence pathway due to host and dopant emission mechanics. It was discovered that the electrochemiluminescence of Mn-doped CsPbCl₃ proceeds through a triplet-triplet annihilation pathway. Furthermore, the relaxation of the electrochemically generated Mn-doped …