Physical Sciences and Mathematics Commons^™

Analyses Of Densely Crosslinked Phenolic Systems Using Low Field Nmr, Jigneshkumar Patel

Doctoral Dissertations

A uniform dispersion of reactants is necessary to achieve a complete reaction involving multi-components, especially for the crosslinking of rigid high-performance materials. In these reactions, miscibility is crucial for curing efficiency. This miscibility is typically enhanced by adding a third component, a plasticizer. For the reaction of the highly crystalline crosslinking agent hexamethylenetetramine (HMTA) with a strongly hydrogen-bonded phenol formaldehyde resin, furfural has been traditionally used as the plasticizer. However, the reason for its effectiveness is not clear. In this doctoral thesis work, miscibility and crosslinking efficiency of plasticizers in phenolic curing reactions are studied by thermal analysis and spectroscopic …

Alternative Mission Concepts For The Exploration Of Outer Planets Using Small Satellite Swarms, Andrew Gene Blocher

Master's Theses

Interplanetary space exploration has thus far consisted of single, expensive spacecraft missions. Mission costs are particularly high on missions to the outer planets and while invaluable, finite budgets limit our ability to perform extensive and frequent investigations of the planets. Planetary systems such as Jupiter and Saturn provide extremely complex exploration environments with numerous targets of interest. Exploring these targets in addition to the main planet requires multiple fly-bys and long mission timelines. In LEO, CubeSats have changed the exploration paradigm, offering a fast and low cost alternative to traditional space vehicles. This new mission development philosophy has the potential …

Computational Methods For Nonlinear Systems Analysis With Applications In Mathematics And Engineering, Geoffrey Kenneth Rose

Mechanical & Aerospace Engineering Theses & Dissertations

An investigation into current methods and new approaches for solving systems of nonlinear equations was performed. Nontraditional methods for implementing arc-length type solvers were developed in search of a more robust capability for solving general systems of nonlinear algebraic equations. Processes for construction of parameterized curves representing the many possible solutions to systems of equations versus finding single or point solutions were established. A procedure based on these methods was then developed to identify static equilibrium states for solutions to multi-body-dynamic systems. This methodology provided for a pictorial of the overall solution to a given system, which demonstrated the possibility …

Integrated Environment And Proximity Sensing For Uav Applications, Shawn S. Brackett

Electronic Theses and Dissertations

As Unmanned Aerial Vehicle (UAV), or “drone” applications expand, new methods for sensing, navigating and avoiding obstacles need to be developed. The project applies an Extended Kalman Filter (EKF) to a simulated quadcopter vehicle though Matlab in order to estimate not only the vehicle state but the world state around the vehicle. The EKF integrates multiple sensor readings from range sensors, IMU sensors, and radiation sensors and combines this information to optimize state estimates. The result is an estimated world map to be used in vehicle navigation and obstacle avoidance.

The simulation handles the physics behind the vehicle flight. As …

Improved Ballistic Wind Prediction Using Projectile Tracking Data, William Arthur Kenney

Computational Modeling & Simulation Engineering Theses & Dissertations

The United States Air Force AC-130 gunships have been in operation since the Vietnam War and have seen frequent use during recent conflicts. They are able to employ gun weapon systems from above a target in a way that maximizes possible time on target. When firing, the gun operators must deal with miss distances caused by winds acting on the projectile in flight. Operators currently perform a “tweak” to predict a ballistic wind affecting fired rounds which is then used in the fire-control to correct for the real winds and bring shots onto target. This correction, a single-point wind prediction, …

Improving Predictive Capabilities Of Classical Cascade Theory For Nonproliferation Analysis, David Allen Vermillion

Doctoral Dissertations

Uranium enrichment finds a direct and indispensable function in both peaceful and nonpeaceful nuclear applications. Today, over 99% of enriched uranium is produced by gas centrifuge technology. With the international dissemination of the Zippe archetypal design in 1960 followed by the widespread illicit centrifuge trafficking efforts of the A.Q. Khan network, traditional barriers to enrichment technologies are no longer as effective as they once were. Consequently, gas centrifuge technology is now regarded as a high-priority nuclear proliferation threat, and the international nonproliferation community seeks new avenues to effectively and efficiently respond to this emergent threat.

Effective response first requires an …

Time Domain Sar Processing With Gpus For Airborne Platforms, Dustin Lagoy

Masters Theses

A time-domain backprojection processor for airborne synthetic aperture radar (SAR) has been developed at the University of Massachusetts’ Microwave Remote Sensing Lab (MIRSL). The aim of this work is to produce a SAR processor capable of addressing the motion compensation issues faced by frequency-domain processing algorithms, in order to create well focused SAR imagery suitable for interferometry. The time-domain backprojection algorithm inherently compensates for non-linear platform motion, dependent on the availability of accurate measurements of the motion. The implementation must manage the relatively high computational burden of the backprojection algorithm, which is done using modern graphics processing units (GPUs), programmed …

Quantifying The Characteristic Length Of A Combustor For An Ionic Liquid Monopropellant Thruster, Kimberly Marie Hogge

Open Access Theses & Dissertations

Ionic liquid monopropellants are currently being researched as a promising alternative to hydrazine in propulsion systems. This report presents a flame study that delineates the flame length of the expected decomposition products from an ionic liquid monopropellant. Through these studies, the characteristic length of a combustion chamber will be defined through calculations and empirical correlations. There is limited information on designing a propulsion system for an ionic liquid monopropellant. Therefore, defining the magnitude for an effective characteristic length serves as beneficial in designing a propulsion system for an ionic liquid monopropellant thruster.

Investigation Of Pyrolysis Gas Chemistry In An Inductively Coupled Plasma Facility, Corey Tillson

Graduate College Dissertations and Theses

The pyrolysis mechanics of Phenolic Impregnated Carbon Ablators (PICA) makes it a valued material for use in thermal protection systems for spacecraft atmospheric re-entry. The present study of the interaction of pyrolysis gases and char with plasma gases in the boundary layer over PICA and its substrate, FiberForm, extends previous work on this topic that has been done in the UVM 30 kW Inductively Coupled Plasma (ICP) Torch Facility. Exposure of these material samples separately to argon, nitrogen, oxygen, air, and carbon dioxide plasmas, and combinations of said test gases provides insight into the evolution of the pyrolysis gases as …

Influence Of Magnetic Nanoparticles And Magnetic Stress On An Ionic Liquid Electrospray Source, Kurt Joseph Terhune

Dissertations, Master's Theses and Master's Reports

Two electrospray sources were developed to operate on an ionic liquid ferrofluid; one source was a pressure‑fed capillary electrospray source and the other was a novel electrospray source which used a magnetically‑induced instability to produce a peak from which an electric field could extract electrospray. Multiple characteristics of electrospray operation were examined for both sources using faraday plates/cups, a quartz crystal microbalance, a retarding potential analyzer, and a time-of-flight mass spectrometer. The ILFF electrosprays for a capillary source were shown to operate in a mixed ion/droplet regime. The mass flow of the electrospray beam was primarily transported by larger particles …

Variable Structure Feedback Control With Application To Spacecraft With Small Thrust Propulsion Systems, Samuel J. Kitchen-Mckinley

Doctoral Dissertations and Master's Theses

Small spacecrafts requiring small propulsion systems are becoming more popular for low Earth orbit. It is important for these research satellites to have accurate guidance and control systems. Small propulsion systems will also be beneficial for multiple small spacecrafts used future exploration expeditions beyond low Earth orbit. These small spacecrafts benefit from the simplicity of low thrust cold gas propulsion systems. Additionally, large spacecrafts using low thrust, high specific impulse propellants for main propulsion systems, such as ion engines, allow longer and more flexible missions, including Earth orbiting spacecraft and interplanetary spacecraft.

In order to extend the life of future …

Autonomous Quadrotor Collision Avoidance And Destination Seeking In A Gps-Denied Environment, Thomas C. Kirven

Theses and Dissertations--Mechanical Engineering

This thesis presents a real-time autonomous guidance and control method for a quadrotor in a GPS-denied environment. The quadrotor autonomously seeks a destination while it avoids obstacles whose shape and position are initially unknown. We implement the obstacle avoidance and destination seeking methods using off-the-shelf sensors, including a vision-sensing camera. The vision-sensing camera detects the positions of points on the surface of obstacles. We use this obstacle position data and a potential-field method to generate velocity commands. We present a backstepping controller that uses the velocity commands to generate the quadrotor's control inputs. In indoor experiments, we demonstrate that the …

The Experimental Determination Of The Moment Of Inertia Of A Model Airplane, Michael Koken

Williams Honors College, Honors Research Projects

The objective of this project is to suggest that the moment of inertia for irregular shaped objects can easily be determined experimentally. The objects considered in this experiment were a solid wooden block and a model airplane. To ensure that the method and configuration is sufficient a wooden block with known moments of inertia was first tested, and the results from the experiment were compared to the known and accepted values. For this particular experiment, the periods were determined by timing how long 10 oscillations lasted for 10 different trials, and then taking the average of those 10 trials to …