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Full-Text Articles in Life Sciences
Evaluation Of Uncertainty For The Determination Of Thiocyanate In Cheese By Inhibited Conductivity Ion Chromatography, Pan Can-Sheng, Zhang Zhi-Zhou, Xia Bing, Zhang Fei, Wu Ping, Wu Ling-Tao
Evaluation Of Uncertainty For The Determination Of Thiocyanate In Cheese By Inhibited Conductivity Ion Chromatography, Pan Can-Sheng, Zhang Zhi-Zhou, Xia Bing, Zhang Fei, Wu Ping, Wu Ling-Tao
Food and Machinery
Objective: To evaluate the uncertainty of the determination of thiocyanate in cheese by inhibition conductance ion chromatography. Methods: The content of thiocyanate in cheese was determined by inhibition conductance ion chromatography and a mathematical model was established. The source of uncertainty introduced in the process of the experiment was described, and the synthetic uncertainty was calculated for each uncertainty component. Results: The determination of thiocyanate was （10.2±0.56） mg/kg, k=2, p=95%. Conclusion: The uncertainty in the measurement process mainly comes from the concentration of thiocyanate in the test solution, followed by sample recovery and repeatability experiments.
Evaluation Of Uncertainty In Determination Of Enrofloxacin And Ciprofloxacin Residues In Bean Sprouts By Ultra Performance Liquid Chromatography-Tandem Mass Spectrometry, Yuan-Xu Shi, Shui-Feng Zhang, Xiang-Jie Pan, Ting-Ting Feng, Lu-Lu Wang
Evaluation Of Uncertainty In Determination Of Enrofloxacin And Ciprofloxacin Residues In Bean Sprouts By Ultra Performance Liquid Chromatography-Tandem Mass Spectrometry, Yuan-Xu Shi, Shui-Feng Zhang, Xiang-Jie Pan, Ting-Ting Feng, Lu-Lu Wang
Food and Machinery
A method for the determination of trace-enrofloxacin and ciprofloxacin in bean sprouts by using ultra- performance liquid chromatography-tandem mass spectrometry was established. The mathematical model was established and used to evaluate the uncertainty components of this method. The sample was extracted with 0.1% acid acetonitrile directly, and purified by prime HLB (SPE), then analyzed by UPLC-MS/MS. The results showed that the main sources of uncertainty arose from the standard curve fitting and standard solution. The expanded uncertainty was 1.5 and 2.3 μg/kg for enrofloxacin and ciprofloxacin contents of 8.6 and 11.0 μg/kg in bean sprouts (k=2), respectively.
Evaluation Of Uncertainty In Chemical Analysis Laboratory Using Control Chart, Jing Li, Xin-Xin Xiao, Xian-Jin Guo
Evaluation Of Uncertainty In Chemical Analysis Laboratory Using Control Chart, Jing Li, Xin-Xin Xiao, Xian-Jin Guo
Food and Machinery
According to the test method of GB/T 5750.6—2006, the cadmium content in drinking water was measured by graphite furnace atomic absorption spectroscopy, and the accumulated data was statistically analyzed based on the Top-down control chart method. The extended uncertainty was 0.30 μg/L (k=2,P=95%). Using Top-down control chart method to assess the uncertainty is statistically rigorous, and has a wide range of application prospects.
Uncertainty Evaluation For Determination Of Isocarbophos Residues In Tea By Quechers-Gas Chromatography-Tandem Mass Spectrometry, Lu Zhenhua, Yu Lifang, Cai Danping, Li Cheng
Uncertainty Evaluation For Determination Of Isocarbophos Residues In Tea By Quechers-Gas Chromatography-Tandem Mass Spectrometry, Lu Zhenhua, Yu Lifang, Cai Danping, Li Cheng
Food and Machinery
Objective:The uncertainty of determination of Isocarbophos residues in tea by using QuEChERS-gas chromatography-tandem mass spectrometry techniqne was evaluated. Methods:Isocarbophos residues in tea was determined by using "GB 23200.113—2018 National food safety Standard-Determination of 208 pesticides and metabolites residues in plant origin-Gas chromatography-tandem mass spectrometry method", and factors in the determination of isocarbophos were analyzed by establishing a mathematical model, including sample weighing, volume, calibration of standard solutions, repeatability and recovery rate, etc.. Results:When the residual amount of isocarbophos in tea was 0.050 mg/kg, the expanded uncertainty was 0.007 mg/kg, and the determination result was expressed as:ω …
Uncertainty Evaluation For The Determination Of Natural Capsaicin, Dihydrocapsaicin And Synthetic Capsaicin In Edible Oils And Fats By Lc-Ms/Ms, Huang Hui, Liao Yan-Zhi
Uncertainty Evaluation For The Determination Of Natural Capsaicin, Dihydrocapsaicin And Synthetic Capsaicin In Edible Oils And Fats By Lc-Ms/Ms, Huang Hui, Liao Yan-Zhi
Food and Machinery
Objective: Uncertainty assessment of the content of synthetic capsaicin, natural capsaicin and dihydrocapsaicin in edible oils and fats by liquid chromatography-mass spectrometry was carried out, and the sources of uncertainty and the key factors affecting the test results were analyzed, so as to improve the accuracy of test results.Methods: To establish a mathematical model for the uncertainty of the content of synthetic capsaicin, natural capsaicin and dihydrocapsaicin in edible oils and fats, to analyze the factors that may introduce uncertainty in the detection process, and to evaluate each uncertainty component.Results: The contents of synthetic capsaicin, natural capsaicin and …
Evaluation On Uncertainty Of Advantame In Syrups Determined By High Performance Liquid Chromatography, Lei De-Qing, Zhong Fei-Fei, Zhou Jin-Sha, Liu Bo, Wang Zi-Qian, Zhou Ya-Min
Evaluation On Uncertainty Of Advantame In Syrups Determined By High Performance Liquid Chromatography, Lei De-Qing, Zhong Fei-Fei, Zhou Jin-Sha, Liu Bo, Wang Zi-Qian, Zhou Ya-Min
Food and Machinery
Objective: This study aimed to evaluate the uncertainty of determination by high performance liquid chromatography (HPLC) for the content of adevantame, a synthetic sweetener illegally added in syrup drugs. Methods: The sample is diluted with solvent, and the content of adevantame in the sample was determined by HPLC. Through the analysis of the factors affecting the uncertainty, such as the preparation of the reference solution, curve fitting, sample weighing, sample volumetric determination and instrument precision, the uncertainty was synthesized of each component, and the extended uncertainty is calculated. Results: The expanded uncertainty is 1.8 μg/mL. The influence …
Evaluation Of Uncertainty In Determination Of Five Kinds Of Carbamate Pesticide Residues In Apple By Liquid Chromatography-Post-Column Derivatization, Yu Xing, Chang Wei, Wang Yong-Lin, Yao Zeng
Evaluation Of Uncertainty In Determination Of Five Kinds Of Carbamate Pesticide Residues In Apple By Liquid Chromatography-Post-Column Derivatization, Yu Xing, Chang Wei, Wang Yong-Lin, Yao Zeng
Food and Machinery
Objective: This study aimed to analyze the accuracy of determination results of five kinds of carbamate pesticide residues in apple. Methods: Five kinds of carbamate pesticide residues in apples were detected according to NY/T 761—2008, and the uncertainty of the determination process was evaluated and analyzed. Results: The contents of carbosulfur, methomyl, 3-hydroxycarbamate, aldicarb and isoprocarb in apples are expressed in the form of expanded uncertainty as (0.105 7±0.007 8), (0.107 7±0.006 2), (0.109 2±0.005 8), (0.103 9±0.008 4), (0.106 1±0.007 6) mg/kg (k=2). Conclusion: The main sources of uncertainty in the experiment are standard material, …
Evaluation Of Uncertainty In The Determination Of Acid Scarlet Gr In Orange Juice By High Performance Liquid Chromatography, Yuan Yuan, Zeng Hui, Xiao Yan, Yang Li-Xia, Cui Xiao-Jiao, Yang Yun, Wu Hou-Lu
Evaluation Of Uncertainty In The Determination Of Acid Scarlet Gr In Orange Juice By High Performance Liquid Chromatography, Yuan Yuan, Zeng Hui, Xiao Yan, Yang Li-Xia, Cui Xiao-Jiao, Yang Yun, Wu Hou-Lu
Food and Machinery
Objective:The uncertainty of the determination of acid scarlet GR in orange juice by high performance liquid chromatography (HPLC) was evaluated. The source of uncertainty and the key factors affecting the test results were analyzed, so as to improve the accuracy of the test results.Methods:The mathematical model of uncertainty of acid scarlet GR content in orange juice was established. The factors that may introduce uncertainty in the detection process were analyzed, and the uncertainty components were evaluated.Results:The content of acid scarlet GR in self-made positive orange juice was 1.46 mg/kg, the expanded uncertainty was 0.11 mg/kg …
Uncertainty Evaluation On Determination Of Statins In Health Food By Gas Chromatography Mass Spectrometry (Gc-Ms), Zhang Li-Xia, Guo Qing-Yuan, Hua Qi-Cheng, Li Xiang-Mei
Uncertainty Evaluation On Determination Of Statins In Health Food By Gas Chromatography Mass Spectrometry (Gc-Ms), Zhang Li-Xia, Guo Qing-Yuan, Hua Qi-Cheng, Li Xiang-Mei
Food and Machinery
Objective:In presence of measurement uncertainty evaluation, the detection methods, with water-sodium chloride pretreatment, for health food was evaluated.Methods:A mathematical model was established to analysis of uncertainty sources. Then the individual components of uncertainty were evaluated. Finally, the combined uncertainty and extended uncertainty were calculated.Results:The uncertainty caused by several factors, including the fitting of the standard curve, the preparation of solution and standard, the repeatability of measurement, and the weigh of sample.The contents of mevastatin, lovastatin and simvastatin were 0.099 2, 0.101 0, 0.099 5 mg/kg in health foods, respectively. The relative combined standard uncertainties were …
Uncertainty Evaluation Of Cadmium Content In Kelp (Laminaria Japonica) By Graphite Furnace Atomic Absorption Spectrometry, Liu Lan-Ying, Lu Xin, Li Ying, Luo Tu-Yan
Uncertainty Evaluation Of Cadmium Content In Kelp (Laminaria Japonica) By Graphite Furnace Atomic Absorption Spectrometry, Liu Lan-Ying, Lu Xin, Li Ying, Luo Tu-Yan
Food and Machinery
Objective: To improve the accuracy of the results of cadmium (Cd) content in kelp (Laminaria japonica) by graphite furnace atomic absorption spectrometry (GF-AAS). Methods: The concentration of Cd element in kelp sample was measured by using GF-AAS after microwave digestion according to the standard of GB 5009.15—2014. Combining with the experimental process and mathematical model, the possible sources of measurement uncertainty were firstly identified, then the components of each standard uncertainties were calculated, and finally each parameter of uncertainties was synthesized, and the whole uncertainty was evaluated. Results: when the value of Cd concentration in kelp was 0.202 …
Evaluation Of Uncertainty In The Determination Of Ethyl Carbamate In Chinese Spirits By Isotope Dilution Gc-Ms Method, Wang Kai-Yu, Zuo Hui-Jun, Yu Xin-Xin, Du Yun, Ma Yan-Ling, Wu Shuai
Evaluation Of Uncertainty In The Determination Of Ethyl Carbamate In Chinese Spirits By Isotope Dilution Gc-Ms Method, Wang Kai-Yu, Zuo Hui-Jun, Yu Xin-Xin, Du Yun, Ma Yan-Ling, Wu Shuai
Food and Machinery
According to GB 5009.223—2014 "National Standard for Food Safety, Determination of Ethyl Carbamate in Foods", the ethyl carbamate in liquor was determined, and the uncertainty of the measuring result was evaluated according to JJF 1059.1—2012 "Measurement Uncertainty Evaluation and Expression". Analysis found that the uncertainty of the measurement results was independent of not only the internal standard concentration of the isotope or the volumetric volume of the standard solution series, but also the volume of the sample after processing. Moreover, the uncertainty component introduced by the internal standard solution only related to the volume of the internal standard liquid. The …
Uncertainty Evaluation Of The Determination Of Vitamin C In Fruits And Vegetables By High Performance Liquid Chromatography, Wang Xia, Zhang Wei-Yi, Han Yi-Yi, Chen Mei-Lian, Feng Dong-Sheng
Uncertainty Evaluation Of The Determination Of Vitamin C In Fruits And Vegetables By High Performance Liquid Chromatography, Wang Xia, Zhang Wei-Yi, Han Yi-Yi, Chen Mei-Lian, Feng Dong-Sheng
Food and Machinery
To evaluate the uncertainty of the determination of vitamin C in fruits and vegetables by high performance liquid chromatography, a mathematical model was established to evaluate each uncertainty component, and the standard uncertainty and extended uncertainty of the synthesis were calculated. The results showed that the amounts of vitamin C in samples was 33.7 mg/100 g, and the expanded uncertainty was 1.4 mg/100 g (k=2). The uncertainties of the determination mainly come from the preparation of standard solution and the repeatability of determination.
Uncertainty Evaluation For Determination Of Sibutramine In Health Foods By Liquid Chromatography-Tandem Mass Spectrometry, Wang Sai-Nan, Deng Ying-Chun, Gao Tian-Lan-Xing, Ren Meng-Ke, Wei Hua-Lin, Zhi Wen-Li, Guo Xu-Guang
Uncertainty Evaluation For Determination Of Sibutramine In Health Foods By Liquid Chromatography-Tandem Mass Spectrometry, Wang Sai-Nan, Deng Ying-Chun, Gao Tian-Lan-Xing, Ren Meng-Ke, Wei Hua-Lin, Zhi Wen-Li, Guo Xu-Guang
Food and Machinery
To evaluate the uncertainty of the determination of sibutramine content in health foods by liquid chromatography-tandem mass spectrometry. Methods according to BJS 201701 Determination of sibutramine in food,and the content of sibutramine in health foods was detected. According to the approach in measurement uncertainty and results indication(JJF 1059.1 2012), the uncertainty was analyzed, quantified and synthesized. When sibutramine content was 7.04 μg/g,the extended uncertainty was 0.197 μg/g (k=2) under the 95% confidence interval. The main influence factors of the uncertainties in the determination were standard curve fitting process.
Evaluation Of Uncertainty In Determination Of Inorganic Arsenic In Aquatic Products Of Tassle Filefish By High Performance Liquid Chromatography-Inductively Coupled With Plasma Mass Spectrometry, Zhou Tan-Chun, Wang Hui, Cui Xiao-Jiao, Zhou Peng, Li Ying, Deng Nan
Evaluation Of Uncertainty In Determination Of Inorganic Arsenic In Aquatic Products Of Tassle Filefish By High Performance Liquid Chromatography-Inductively Coupled With Plasma Mass Spectrometry, Zhou Tan-Chun, Wang Hui, Cui Xiao-Jiao, Zhou Peng, Li Ying, Deng Nan
Food and Machinery
The uncertainty evaluation in the determination of inorganic arsenic in tassle filefish by using High Performance Liquid Chromatography-Inductively Coupled with Plasma Mass Spectrometry was investigated, based on the GB 5009.11 2014 “national food safety standards on the determination of total arsenic and inorganic arsenic in food”. A mathematical model was established, referring to CNAS-GL006 Guidelines for “the Assessment of uncertainty in Chemical Analysis and JJF 1059.1 2012 Evaluation and Expression of Measurement Uncertainty”. The precision and recovery of As (III) and As (V) in maomile fish were verified. Meanwhile, the sources of uncertainty measurement of the experiment were analyzed and …