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Full-Text Articles in Life Sciences

A Modelling Approach: Effects Of Exuded Organic Acids And Exogenous Chelating Ligands On Bioavailability And Uptake Of Metals By Radishes (Raphanus Sativus) Grown In Hydroponics., Sergio A. Dominguez Romero Aug 2017

A Modelling Approach: Effects Of Exuded Organic Acids And Exogenous Chelating Ligands On Bioavailability And Uptake Of Metals By Radishes (Raphanus Sativus) Grown In Hydroponics., Sergio A. Dominguez Romero

Electronic Thesis and Dissertation Repository

Metal contamination of soil can be reduced by adding chelators to improve the efficiency of metal uptake in phytoremediation, but optimal concentrations and types of chelators have not been determined. A geochemical model (Visual MINTEQ3.1) was used to estimate the effects of four chelators on the solubility of four metals in hydroponic solution. The model showed that no iron was soluble in the absence of a chelator, while the solubilities of cadmium, copper and zinc were high with or without chelators. Despite low iron uptake in all treatments, symptoms of iron-deficiency were not visible. High concentrations of exuded organic acids …


Metalation And Structural Properties Of Apo-Metallothioneins, Gordon W. Irvine Apr 2017

Metalation And Structural Properties Of Apo-Metallothioneins, Gordon W. Irvine

Electronic Thesis and Dissertation Repository

Metals are required by a quarter of all proteins to achieve their biological function, whether in an active site involved in catalytic chemistry or in a structural capacity. Metals are tightly regulated at the cellular level due to their propensity to cause unwanted side reactions and to be scavenged for use by pathogens. One of the proteins involved in this regulation of metal homeostasis is metallothionein (MT) which is a small, cysteine rich protein primarily involved in the regulation of zinc and copper homeostasis and heavy metal detoxification. MT is unique in its high cysteine content (~30% of the residues), …