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Full-Text Articles in Life Sciences

The Effect Of Microbial Growth On The Spectral Induced Polarization Response In Hanford Vadose Zone Sediment In The Presence Of Autunite, Alejandro Garcia Jun 2018

The Effect Of Microbial Growth On The Spectral Induced Polarization Response In Hanford Vadose Zone Sediment In The Presence Of Autunite, Alejandro Garcia

FIU Electronic Theses and Dissertations

Uranium contamination of the subsurface remains a significant problem at the Department of Energy Hanford site. A series of column experiments were conducted on Hanford sediment saturated with simulated groundwater to study the effects of aqueous bicarbonate and microbial growth on the mobility of Uranium. Spectral induced polarization (SIP) measurements in the columns were conducted concurrently with pore water sampling in order to monitor changes occurring inside the sediment after the initiation of microbial growth induced by glucose injection. The microbial growth caused significant increases in the real component of the complex conductivity and is the result of ion release …


Developing Ocean Color Algorithm Using Moderate Resolution Imaging Spectroradiometer (Modis) Sensor For Shallow Coastal Water Bodies, Mohd Manzar Abbas Jun 2018

Developing Ocean Color Algorithm Using Moderate Resolution Imaging Spectroradiometer (Modis) Sensor For Shallow Coastal Water Bodies, Mohd Manzar Abbas

FIU Electronic Theses and Dissertations

This study analyses the spatial and temporal variability of chlorophyll-a in Chesapeake Bay; assesses the performance of Ocean Color 3M (OC3M) algorithm; and develops a novel algorithm to estimate chlorophyll-a for coastal shallow water. The OC3M algorithm yields an accurate estimate of chlorophyll-a concentration for deep ocean water (RMSE=0.016), but it failed to perform well in the coastal water system (RMSE=23.17) of Chesapeake Bay. A novel algorithm was developed which utilizes green and red bands of the Moderate Resolution Imaging Spectroradiometer (MODIS) sensor. The novel algorithm derived the chlorophyll-a concentration more accurately in Chesapeake Bay (RMSE=4.20) than the OC3M algorithm. …


The Cyclodextrin-Perfluorinated Surfactant Host-Guest Complex: Fundamental Studies For Potential Environmental Remediation And Therapeutic Applications, Mary J. Errico May 2018

The Cyclodextrin-Perfluorinated Surfactant Host-Guest Complex: Fundamental Studies For Potential Environmental Remediation And Therapeutic Applications, Mary J. Errico

FIU Electronic Theses and Dissertations

Perfluoroalkyl substances (PFASs) are contaminants of emerging concern, and have been detected in drinking water, wildlife, humans, and the environment. Cyclodextrins (CDs), cyclic sugars composed of glucose monomers, are proposed as a potential remediation strategy. CDs can form host-guest complexes with hydrophobic molecules; this complexation could be capitalized on for PFAS removal and sequestration. These dissertation projects aim to study the fundamental host-guest interactions between a variety of PFASs and CDs for eventual applications in environmental and biological remediation. 1D and 2D Nuclear magnetic resonance (NMR) spectroscopic methods were employed to determine the strength, dynamics, and structure of the CD:PFAS …