Open Access. Powered by Scholars. Published by Universities.®

Engineering Commons

Open Access. Powered by Scholars. Published by Universities.®

Model

2005

Chemical Engineering

Articles 1 - 2 of 2

Full-Text Articles in Engineering

Thermo And Kinetic Studies On The Sorption And Desorption Of Hydrophobic Organic Contaminants In Sediments, Yunzhou Chai Jan 2005

Thermo And Kinetic Studies On The Sorption And Desorption Of Hydrophobic Organic Contaminants In Sediments, Yunzhou Chai

LSU Doctoral Dissertations

This study investigated the correlation of desorption resistance of hydrophobic organic contaminants (HOCs) in sediment and the heterogeneity of sediment organic matter (SOM). The amorphous and condensed phase organic carbon contents were defined by the method of Gustafsson et al. (1997) using thermal oxidation of sediment under 375°C. The desorption-resistant fraction of contaminants in sediments was operationally defined as the fraction that could not be removed by the adsorbent XAD-2. The correlation of the desorption-resistant fraction with sediment organic carbon characteristics was evaluated for both laboratory-inoculated and field-contaminated sediments. No strong correlation between the desorption resistant fraction in laboratory-inoculated sediments …


Mathematical Models For Estimating Volatile Chemical Emissions From Dredging Operations, Kenneth Alexander Fountain Jan 2005

Mathematical Models For Estimating Volatile Chemical Emissions From Dredging Operations, Kenneth Alexander Fountain

LSU Master's Theses

Dredging operations have been a common remediation for contaminated sediment in an effort to reduce the harmful impact on the environment. The objective of this research was to create models used for estimating chemical release to air from remediating the Indiana Harbor and Canal (IHC) as three separate dredging operations; the Dredge Site, Exposed DM CDF, and Ponded CDF. The evaporative flux estimations are based on a two-resistance mass transport path inclusive of both the molecular diffusion in porous media and interfacial airside mass transport resistances. Several chemodynamic algorithms were used in calculating key transport parameters. Laboratory tests were performed …