Engineering Commons^™

Investigation Of Different Hatch Strategies On High Entropy Alloy Fabrication By Selective Laser Melting, Joni Chandra Dhar

Theses and Dissertations

This study investigated the synthesis of CuCrFeNiTiAl high entropy alloy (HEA) from pure elements using selective laser melting (SLM). The objectives are to validate the feasibility of the HEA fabrication from elemental powder materials, and to examine the effect of various hatch strategies and energy densities on the microstructures and other materials properties. 3D samples of CuCrFeNiTiAl alloy were fabricated under different energy densities and with different scan vector lengths. The as-built samples were characterized by X-ray diffraction (XRD), and the microstructures were observed using scanning electron microscopy (SEM). The XRD results showed that face centered cubic, and body centered …

Characterization And Modeling Of The Martensite Transformation In Advanced High-Strength Steels, Stephen Roy Cluff

Theses and Dissertations

Multiple studies on the microstructures of advanced high-strength steels are presented here that seek to add to the already substantial body of knowledge on martensite in steel. These studies seek to gain additional insight into the role that the martensite transformation has on the observed mechanical properties of modern steels. Crystallographic Reconstruction of Parent Austenite Twin Boundaries in a Lath Martensitic Steel The study of post-transformation microstructures and their properties can be greatly enhanced by studying their dependence on the grain boundary content of parent microstructures. Recent work has extended the crystallographic reconstruction of parent austenite in steels to include …

Microstructural Evaluation Of Hydrogen Embrittlement And Successive Recovery In Advanced High Strength Steel, Quentin Scott Allen

Theses and Dissertations

Advanced high strength steels (AHSS) have high susceptibility to hydrogen embrittlement, and are often exposed to hydrogen environments in processing. In order to study the embrittlement and recovery of steel, tensile tests were conducted on two different types of AHSS over time after hydrogen charging. Concentration measurements and hydrogen microprinting were carried out at the same time steps to visualize the hydrogen behavior during recovery. The diffusible hydrogen concentration was found to decay exponentially, and equations were found for the two types of steel. Hydrogen concentration decay rates were calculated to be -0.355 /hr in TBF steel, and -0.225 /hr …

Microstructure, Wetting Angle And Corrosion Of Aluminum-Silicon Alloys, Shvetashva Suri

Theses and Dissertations

In this study the effect of composition, surface roughness and water droplet size on contact angle and corrosion properties of cast Aluminum-Silicon alloys containing Si from 5% to 50% have been examined. The water contact angle was measured on a given sample using a goniometer. In addition, the effect of surface roughness and droplet size on contact angle has been measured for alloys at a fixed composition. The microstructures can be found in this report with sizes of primary and eutectic Silicon as well as inter-particle spacing between Silicon. Contact angle measurements are accompanied with a photographic validation of the …

The Effect Of Microstructure On Transport Properties Of Porous Electrodes, Serena Wen Peterson

Theses and Dissertations

The goal of this work is to further understand the relationships between porous electrode microstructure and mass transport properties. This understanding allows us to predict and improve cell performance from fundamental principles. The investigated battery systems are the widely used rechargeable Li-ion battery and the non-rechargeable alkaline battery. This work includes three main contributions in the battery field listed below.

Direct Measurement of Effective Electronic Transport in Porous Li-ion Electrodes. An accurate assessment of the electronic conductivity of electrodes is necessary for understanding and optimizing battery performance. The bulk electronic conductivity of porous LiCoO2-based cathodes was measured as a …

Functionalized Graphitic Nanoreinforcement For Cement Composites, Nima Zohhadi

Theses and Dissertations

Physical and mechanical properties of graphitic nanomaterials, in particular multiwalled carbon nanotubes (MWCNTs) and graphene nano-platelets (GNPs) make them promising candidates for nanoreinforcement of cement composites. The two key challenges associated with the incorporation of MWCNTs and GNPs are to attain uniform dispersion and interfacial bonding within the composite matrix. The effects of three main-stream dispersion techniques (namely, ultrasonication, acid-etching, and surfactant-coating) on the mechanical properties and microstructure of MWCNT- and GNP-cement composites were experimentally studied. Compressive strength tests and different characterization techniques including dynamic light scattering, Raman spectroscopy, Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, and transmission …

Bio-Inspired And Low-Content Polymer Cement Mortar For Structural Rehabilitation, Nima Zohhadi

Theses and Dissertations

Use of polymers as partial replacement for Portland cement in cement mortar and concrete can diminish several drawbacks of these composites such as low tensile strength and strain capacity, high permeability and low adhesion. Main reasons for the use of polymers are to improve damage tolerance, adhesion, and resistance to water permeation. Various polymers with a wide range of physical and mechanical properties have been used in fabrication of cementitious composites. Typical polymer content for such composites is 5% to 20% (by the weight of cement) for both mortar and concrete. There are also drawbacks associated with the use of …

An Investigation Into The Mechanisms Of Formation Of The Hard Zone In Fsw X65, Jacob D. Allred

Theses and Dissertations

Friction stir welding (FSW) of HSLA steel commonly produces a hard zone (HZ) on the advancing side (AS) of the weld. Despite its detrimental effects on weld toughness, the mechanisms of its formation have not been thoroughly investigated and are not well understood. This paper investigates the various mechanisms in FSW believed to affect the weld HZ, namely: strain, strain-rate, peak temperature and cooling rate. Gleeble tests indicate that strain and strain rate have negligible effects on weld HZ with cooling rate and peak temperature as dominant effects. Jominy tests resulted in cooling rate having 270% greater influence than peak …

The Effect Of Cooling Rate Of Friction Stir Welded High Strength Low Alloy Steel, Scott Anthony Rose

Theses and Dissertations

The friction stir welding of steel has produced a hard zone in several different alloys. Despite its detrimental effects on weld toughness, the reasons behind neither its formation nor a method of reducing its size or effects have been explored. Recent advances in process control allow for direct heat input control, which combined with the use of backing plates of different thermal conductivity allows for an expansion of the process window. These control methods also affect the HAZ cooling rate by providing greater range (a 60% increase compared to a fixed backing plate) and control (five welds within 16 °C/s). …

Evolution Of Microstructure Of Haynes 230 And Inconel 617 Under Mechanical Testing At High Temperatures, Kyle Hrutkay

Theses and Dissertations

Haynes 230 and Inconel 617 are austenitic nickel based superalloys, which are candidate structural materials for next generation high temperature nuclear reactors. High temperature deformation behavior of Haynes 230 and Inconel 617 have been investigated at the microstructural level in order to gain a better understanding of mechanical properties. Tensile tests were performed at strain rates ranging from 10-3-10-5 s-1 at room temperature, 600 °C, 800 °C and 950 °C. Subsequent microstructural analysis, including Scanning Electron Microscopy, Transmission Electron Microscopy, Energy-Dispersive X-ray Spectroscopy, and X-Ray Diffraction were used to relate the microstructural evolution at high temperatures to that of room …

A Hybrid Bishop-Hill Model For Microstructure Sensitive Design, Ribeka Takahashi

Theses and Dissertations

A method is presented for adapting the classical Bishop-Hill model to the requirements of elastic/yield-limited design in metals of arbitrary crystallographic texture. The proposed Hybrid Bishop-Hill (HBH) model, which will be applied to ductile FCC metals, retains the `stress corners' of the polyhedral Bishop-Hill yield surface. However, it replaces the `maximum work criterion' with a criterion that minimizes the Euclidean distance between the applicable local corner stress state and the macroscopic stress state. This compromise leads to a model that is much more accessible to yield-limited design problems. Demonstration of performance for the HBH model is presented for an extensive …

Study On The Fracture Toughness Of Friction Stir Welded Api X80, Allan M. Tribe

Theses and Dissertations

High strength low alloy (HSLA) steels have been developed to simultaneously have high yield strength and high fracture toughness. However, in practical applications steel must be welded. Traditional arc welding has proven detrimental to the fracture toughness of HSLA steels. Friction stir welding has recently shown mixed results in welding HSLA steels. The range of welding parameters used in these recent studies however has been very limited. With only a few welding parameters tested, the effect of spindle speed, travel speed, and heat input on the fracture toughness of friction stir welded HSLA steel remains unknown. To understand how the …

A New Eulerian-Based Double Continuity Model For Predicting The Evolution Of Pair Correlation Statistics Under Large Plastic Deformations, Sadegh Ahmadi

Theses and Dissertations

A new model using a double-continuity relation for predicting the evolution of pair-correlation functions (PCFs) is presented. The proposed model was developed using statistical continuum theory and is employed to predict the viscoplastic behavior of polycrystalline materials. This model was built based upon the continuity relations and a double divergence law that guarantees the conservation of both orientation and mass; and also satisfies the field equations (equilibrium, constitutive, and compatibility) at every point of the polycrystalline material throughout the deformation process. In the presented model, motion of particles in the real space and rotation of crystallographic orientations in the Euler …

Investigation Of Heterogeneity Of Fsw Inconel 718 Coupled With Welding Thermal Cycle, Dong Fang Huang

Theses and Dissertations

In order to develop a better understanding of the property, microstructure evolution and thermal history of FSW Inconel 718's, the strain, strain rate and thermal cycles need to be determined. In order to estimate the strain field of a deformed body, a displacement function needs to be determined. A 3D deformation model was developed to determine the displacement coefficients. A rectangular box created in this model deforms following a linear displacement function. Three orthogonal planes cut this deformed box, which leads to three deformed planes. The shape parameters (L, H, θ¹ and θ²) on the three orthogonal planes can be …

Object Oriented Cae Software For The Exploration And Design Of Microstructures, Stephen D. Sintay

Theses and Dissertations

Through the use of generalized spherical harmonic basis functions a spectral representation is used to model the microstructure of cubic materials. This model is then used to predict the macroscopic elastic and plastic properties of materials with cubic crystal symmetry and various sample symmetry including triclinic and axial—symmetric. Building on the work of citeN{Barnett-FractureMechanics} the influence that anisotropy has on the fatigue response of the material is also modeled. This is accomplished through using the effective elastic stiffness tensor in the computation of crack extension force G. The resulting material model and macroscopic property calculations are the foundation for …

An Analysis Of Microstructure And Corrosion Resistance In Underwater Friction Stir Welded 304l Stainless Steel, Tad Dee Clark

Theses and Dissertations

An effective procedure and parameter window was developed for underwater friction stir welding (UWFSW) 304L stainless steel with a PCBN tool. UWFSW produced statistically significant: increases in yield strengths, decreases in percent elongation. The ultimate tensile strength was found to be significantly higher at certain parameters. Although sigma was identified in the UWFSWs, a significant reduction of sigma was found in UWFSWs compared to ambient FSWs. The degree of sensitization in UWFSWs was evaluated using double loop EPR testing and oxalic acid electro-etched metallography. Results were compared to base metal, ambient FSW, and arc welds. Upper and lower sensitization localization …

Effects Of Friction Stir Processing On The Microstructure And Mechanical Properties Of Fusion Welded 304l Stainless Steel, Colin J. Sterling

Theses and Dissertations

Friction stir processing (FSP) has been utilized to locally process regions of arc weldments in 304L stainless steel to improve the microstructure and mechanical performance. The cast microstructure and coarse delta-ferrite has been replaced with a fine-grained wrought microstructure. Furthermore, twins were introduced throughout the friction stir processed region. Although sub-surface sigma and carbides were introduced during FSP, their presence is not expected to adversely affect the resulting mechanical or corrosion properties of friction stir processed 304L arc welds. The resulting mechanical properties of FS processed weldments were also an improvement over as-welded arc welds. FSP resulted in an increase …

Effects Of Friction Stir Welding On Polymer Microstructure, Seth R. Strand

Theses and Dissertations

This work establishes the relationships between several key Friction Stir Welding process parameters and the resulting microstructural and flexural properties of the welded joint. A series of four single parameter experiments were run. The parameters investigated were pin diameter, feedrate, shoe temperature, and pressure time. Butt welds were made in 6 mm thick stress-relieved extruded polypropylene sheet. Three-point bend tests were used to determine the ultimate flexural strength and coincident strain. The maximum bend angle before failure was used to label the welds as "good or bad." An optical microscope capable of cross polarization was used to examine and photograph …

Incorporating Functionally Graded Materials And Precipitation Hardening Into Microstructure Sensitive Design, Mark Edward Lyon

Theses and Dissertations

The methods of MSD are applied to the design of functionally graded materials. Analysis models are presented to allow the design of compliant derailleur for a case study and constraints are placed on the design. Several methods are presented for relating elements of the microstructure to the properties of the material, including Taylor yield theory, Hill elastic bounds, and precipitation hardening.

Applying n-point statistics to the MSD framework is also discussed. Some results are presented for the information content of the 2-point correlation statistics that follow from the methods used to integrate functionally graded materials into MSD.

For the compliant …

Self-Assembly Of Microstructures, Paul E. Kladitis

Theses and Dissertations

Four areas are investigated in this research: erecting microstructures normal to the substrate plane without direct human intervention (self-assembled), providing low resistance electrical connections to the erected microstructure, realizing circular motion normal to the substrate plane, and implementing a micro-robot. The designs in this research concentrate on erecting and providing power to a leg designed for use with the micro-robot. The leg and the attached low resistance electrical connectors were not self-assembled because the accompanying actuators were not powerful enough. However, the novel connectors provide the most practical, versatile, and lowest possible resistance connections for the MUMPs fabrication process. The …

Investigation Of The Platinum-Rich Portion Of The Platinum-Tantalum Phase Diagram, Bob Dean Browning

Theses and Dissertations

The Pt-Ta binary system was investigated at two isotherms;1000°C and 1500°C, and at eleven alloy compositions in the range of 50 to 100 atomic percent platinum. The alloys were examined by x-ray diffraction and metallography. Three intermetallic compounds, Pt₂Ta, Pt₃Ta, and Pt₄Ta were found to exist in this composition range. The Pt₄Ta intermetallic appeared only at the 1500°C isotherm. Platinum dissolved tantalum substitutionally to 90 atomic percent at 1500 °C and to approximately 80 atomic percent at 1000 °C.