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Full-Text Articles in Engineering
Increase In The Reduction Potential Of Uranyl Upon Interaction With Graphene Oxide Surfaces, V. N. Bliznyuk, N. Conroy, Y. Xie, R. Podila, A. Rao, Brian A. Powell
Increase In The Reduction Potential Of Uranyl Upon Interaction With Graphene Oxide Surfaces, V. N. Bliznyuk, N. Conroy, Y. Xie, R. Podila, A. Rao, Brian A. Powell
Publications
Coordination of uranyl (U(VI)) with carboxylate groups on functionalized graphene oxide (GO) surfaces has been shown to alter the reduction potential of the sorbed uranium ion. A quantitative measure of the reduction potential and qualitative estimation of sorption/desorption processes were conducted using cyclic voltammetry, and the proposed coordination environment was determined using the surface sensitive attenuated total reflection mode of infrared spectroscopy (ATR-FTIR). GO is a nanostructured material possessing a large amount of oxygen-containing functional groups both on basal planes and at the edges, which can form strong surface complexes with radionuclides. The presence of these functional groups on the …
A Decision Support Tool For Building Integrated Renewable Energy Microgrids Connected To A Smart Grid, Damilola A. Asaleye, Michael D. Murphy, Michael Breen
A Decision Support Tool For Building Integrated Renewable Energy Microgrids Connected To A Smart Grid, Damilola A. Asaleye, Michael D. Murphy, Michael Breen
Publications
The objective of this study was to create a tool that will enable renewable energy microgrid (REμG) facility users to make informed decisions on the utilization of electrical power output from a building integrated REμG connected to a smart grid. A decision support tool for renewable energy microgrids (DSTREM) capable of predicting photovoltaic array and wind turbine power outputs was developed. The tool simulated users’ daily electricity consumption costs, avoided CO2 emissions and incurred monetary income relative to the usage of the building integrated REμG connected to the national electricity smart grid. DSTREM forecasted climate variables, which were used …
Influence Of Activated Carbon Surface Oxygen Functionality On Elemental Mercury Adsorption From Aqueous Solution, Emily K. Faulconer, David W. Mazyck
Influence Of Activated Carbon Surface Oxygen Functionality On Elemental Mercury Adsorption From Aqueous Solution, Emily K. Faulconer, David W. Mazyck
Publications
Mercury (Hg), though naturally occurring, is a toxic element. Exposure to various forms of mercury can be harmful for humans and ecosystems. Mercury-contaminated wastewater can be treated using activated carbon to adsorb the mercury, allowing for safe discharge. Wet chemical oxidation of activated carbon was performed to enhanced surface oxygen functionality, with the objective of enhancing aqueous ionic (Hg(II)) and elemental (Hg(0)) mercury adsorption. Characterization of the modified carbons included nitrogen adsorption-desorption, elemental analysis, point of zero charge, and total acidity titration. The concentration and identity of the modifying reagent influenced the characteristics of the carbons, including the surface oxygen …