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Full-Text Articles in Engineering

Electrocatalytic Oxidation Of Formic Acid On Pd/Ni Heterostructured Catalyst, Mingjun Ren, Liangliang Zou, Ju Chen, Ting Yuan, Qinghong Huang, Haifeng Zhang, Hui Yang, Songlin Feng Dec 2012

Electrocatalytic Oxidation Of Formic Acid On Pd/Ni Heterostructured Catalyst, Mingjun Ren, Liangliang Zou, Ju Chen, Ting Yuan, Qinghong Huang, Haifeng Zhang, Hui Yang, Songlin Feng

Journal of Electrochemistry

A Pd/Ni bimetallic nanostructured electrocatalyst was fabricated via a two-step reduction route. Owing to an epitaxial growth of Pd atoms on the surface of Ni nanoparticles, heterostructured Pd/Ni nanocomposites were formed and verified by high resolution transmission electron microscopy combined with energy-dispersion X-ray spectroscopy. X-ray diffraction confirmed that the as-prepared Pd/Ni nanocomposites possessed a single face-centered-cubic (fcc) Pd structure, probably due to a weaker diffraction intensity of metallic Ni and/or overlapping by that of Pd. The intrinsic catalytic activity on the Pd/Ni is higher than that on the Pd. Moreover, the durability of formic acid oxidation on the Pd/Ni was …


Durability Of Reinforced Concrete Incorporating Crushed Waste Brick As Coarse Aggregate, Matthew Adamson Dec 2012

Durability Of Reinforced Concrete Incorporating Crushed Waste Brick As Coarse Aggregate, Matthew Adamson

All Theses

Using crushed bricks as aggregates in concrete is of particular interest to preserve natural aggregate sources as well as to reduce waste, as it has been estimated that 10% to 30% of all waste in landfills in the united States comes from construction and demolition wastes. By recycling some of these wastes, the sustainability of a project can be improved. However, it is important concrete incorporating these wastes is as durable or more durable then conventional concrete, or will it have a shorter service life. Durability of concrete is its ability to resist deterioration from its external environment such as …


Efficacy Of A Ternary Blend In Improving Bridge Deck Concrete Durability In Tennessee, Robert Clark Nidiffer Aug 2012

Efficacy Of A Ternary Blend In Improving Bridge Deck Concrete Durability In Tennessee, Robert Clark Nidiffer

Masters Theses

A study related to the durability of bridge deck concrete in the state of Tennessee has been ongoing at the University of Tennessee (UT) for the past decade. The most recent phase of this research was begun in the fall of 2009 with a focus on developing assessment criteria and methodology to assess the durability of bridge deck concrete in the state of Tennessee. The methodology that was used to assess the durability of Tennessee bridge deck concrete was to determine the concrete’s resistance to chloride ion penetration by way of two test methods, the Surface Resistivity (SR) test and …


Engineering Performance Of Polymer Amended Soils, Gary E. Welling Aug 2012

Engineering Performance Of Polymer Amended Soils, Gary E. Welling

Master's Theses

A laboratory test program was undertaken to evaluate a series of engineering properties over a range of soil types; amendment types and addition rates; and moisture contents to enhance understanding of the engineering significance of polymer amendment. Four soils were manufactured and tested with varying ranges of fines and plasticity. A proprietary elastic copolymer was tested at addition rates of 0.5% to 2.5% (dry weight basis). Cement was tested at addition rates of 1% to 4%. Lime was tested at an 8% addition rate. Water addition rates ranged from 4% dry of optimum to 4% wet of optimum. Engineering properties …


Using Mercury Intrusion Porosimetry To Study The Interfacial Properties Of Cement-Based Materials, Shih-Wei Cho Jun 2012

Using Mercury Intrusion Porosimetry To Study The Interfacial Properties Of Cement-Based Materials, Shih-Wei Cho

Journal of Marine Science and Technology

Cement-based material is a typical porous composite material. Pore structures and interfacial properties of cementbased materials are influenced properties of ion transport behavior and durability. This study determines pore structure by employing mercury intrusion porosimetry (MIP), with mortar specimens manufactured with three different watercement (w/c) ratios and five volume proportions of fine aggregate to investigate interfacial properties. The experimental results show that total mercury intrusion decreases with an increase in sand volume proportion when comparing the same w/c ratio. The calculated mercury intrusion of interfacial transition zone increases with w/c and the volume proportion of fine aggregate.


Progress And Perspective Of Fuel Cell Technology, Ming Hou, Bao-Lian Yi Feb 2012

Progress And Perspective Of Fuel Cell Technology, Ming Hou, Bao-Lian Yi

Journal of Electrochemistry

Fuel cell, a clean and high-efficiency electrochemical power source, has being paid much attention worldwide recent years. In this paper, the progress and perspective of fuel cell technology are elucidated in detail. Fuel cells have been applied in some special fields such as spacecraft, shuttle and submarines. However, in the areas of transportation, stationary station and portable power source, fuel cells are still under demonstration due to the durability and cost problems. The reliability and surrounding survivability of fuel cells should be enhanced in the special application. Meanwhile, the durability and cost of fuel cells are the main issues to …


Effects Of High Volume Fly Ash And Powder Activators On Plastic And Hardened Concrete Properties, Drew Alexander Davis Jan 2012

Effects Of High Volume Fly Ash And Powder Activators On Plastic And Hardened Concrete Properties, Drew Alexander Davis

Masters Theses

This study was performed to examine the effects of high volumes of Class C fly ash modified by powder activators upon the plastic and hardened properties of concrete. In a companion study, five Missouri area cements and five Class C fly ashes were examined for incompatibilities, with the most and least reactive combinations being scaled up to full scale concrete testing. Two baseline concrete mixtures were examined, the only difference in mixtures being the sources of portland cement and fly ash. Fly ash replacement was examined at 50% and 70% replacement (by total cementitious mass). Three powder activators were used …