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Full-Text Articles in Engineering

Reversible Addition - Fragmentation Chain Transfer In Microemulsions: Effect Of Chain Transfer Agent Aqueous Solubility, Jennifer M. O'Donnell, Eric W. Kaler Jan 2010

Reversible Addition - Fragmentation Chain Transfer In Microemulsions: Effect Of Chain Transfer Agent Aqueous Solubility, Jennifer M. O'Donnell, Eric W. Kaler

Jennifer M. Heinen

Microemulsion polymerizations are attractive for investigating compartmentalization effects in heterogeneous reversible addition - fragmentation chain transfer (RAFT) polymerizations because the propagating radicals are segregated into surfactant stabilized polymer particles, which drastically reduces the effects of biradical termination, Also, microemulsion polymerizations do not involve the large monomer droplets that are present in emulsion and miniemulsion polymerizations. RAFT microemulsion polymerizations of butyl aery late with a high water solubility chain transfer agent, methyl-2-(O-ethylxanthyl)propionate (MOEP), and a low water solubility chain transfer agent, methyl-2-(O-dodecylxanthyl)propionate (MODP), were investigated to determine the effect of chain transfer agent compartmentalization on the control of the polymerization. The …


Transient Study Of The Wetting Films In Porous Media Using 3d X-Ray Computed Micro-Tomography: Effect Of Imbibition Rate And Pore Geometry, Pradeep Bhattad Jan 2010

Transient Study Of The Wetting Films In Porous Media Using 3d X-Ray Computed Micro-Tomography: Effect Of Imbibition Rate And Pore Geometry, Pradeep Bhattad

LSU Doctoral Dissertations

Imbibition in porous media is governed by the complex interplay between viscous and capillary forces, pore structure and fluid properties. Understanding and predicting imbibition is important in many natural and engineered applications; it affects the efficiency of oil production operations, the moisture and contaminant transport in soil science, and the formation of defects in certain types of composite materials. Majority of the studies published on the transient imbibition behavior in a porous medium were conducted in the simplified 2D transparent micromodels or the 2D projection visualization (X-ray or visible light) of the 3D porous medium. However, the pore level transient …