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Theses/Dissertations

2006

University of Central Florida

Oxidation

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Full-Text Articles in Engineering

Polymer-Derived Si-Al-C-N Ceramics:Oxidation, Hot-Corrosion, And Structural Evolution, Yiguang Wang Jan 2006

Polymer-Derived Si-Al-C-N Ceramics:Oxidation, Hot-Corrosion, And Structural Evolution, Yiguang Wang

Electronic Theses and Dissertations

Polymer-derived ceramics are a new class of materials synthesized by thermal decomposition of polymer precursors. Previous studies have shown that the materials exhibit excellent thermo-mechanical properties and can be stable at temperatures up to 2000oC. Furthermore, the novel polymer-to-ceramics process enables the manipulation of the ceramic structures at the atomic/nano level by designing the chemistry of polymer precursors and controlling the pyrolysis conditions, thereby, the properties of ceramics. In this dissertation, oxidation/hot-corrosion behavior and the structural evolution of Si-Al-C-N ceramics have been studied. The structural evolution and crystallization behavior of the SiCN and SiAlCN ceramics are investigated using FT-IR, XRD, …


A Non-Isolated Half Bridge Buck-Based Converter For Vrm Application And Small Signal Modeling Of A Non-Conventional Two Phase Bu, Majd Batarseh Jan 2006

A Non-Isolated Half Bridge Buck-Based Converter For Vrm Application And Small Signal Modeling Of A Non-Conventional Two Phase Bu, Majd Batarseh

Electronic Theses and Dissertations

This dissertation is about treatment of the nonbiodegradable organic content of landfill leachate by chemical oxidation combined with biological treatment. It is divided into three parts. In the first part, ferrate was compared to Fenton's reagent for the purpose of removing non-biodegradable organic compounds from mature leachate. Oxidation conditions (time, pH, and dose) were optimized to yield maximum organic removal using two leachate samples from 20 and 12-year old solid waste cells. Results from this research demonstrated that ferrate and Fenton's reagent had similar optimum pH ranges (3-5), but different organic removal capacities, ranging from 54 to 79 % of …