Engineering Commons^™

A Theoretical Analysis Of Volatile Contaminant Removal By The Pneumatic Fracturing Process, Yuan Ding

Dissertations

A mathematical model that simulates the process of contaminant removal from a pneumatically induced fracture within a porous medium is presented. It includes: (1) model development; (2) parameter evaluation; (3) statistical sensitivity analysis; and (4) model validation.

Based on the dual porosity approach, a mathematical model for a fractured porous formation is developed for both two dimensional and axial symmetrical cases. This model constitutes a pair of coupled partial differential equations for the porous medium and discrete fracture, respectively. The initial and boundary conditions have been determined based on field considerations of a soil vapor extraction system. By means of …

Modeling The Fate Of Volatile Organic Compounds In Wastewater Treatment Facilities; Implementation Of Volatilization Models In Envirocad, Vinita Chhahira

Theses

The 1990 Clean Air Act Amendments have identified wastewater treatment facilities as a major source of volatile organic compound (VOC) emissions. VOCs present in wastewater discharges affect the quality of receiving waters, while emissions to the air affect downwind populations. The primary mechanisms involved in VOC removal from a wastewater treatment facility are volatilization and stripping, biodegradation, and sorption to either suspended or biological solids. Although many models have been developed to predict the fate of VOCs in wastewater treatment facilities, no model completely predicts emissions for an entire wastewater treatment facility. The focus of this work is to incorporate …

Volatilization Of Volatile Organic Compounds From Complex Wastewaters, Syed Sikandar Qadry

Theses

A variety of volatile organic solvents used in the pharmaceutical and specialty chemical industries end up in wastewater collection and treatment systems. EPA has classified these VOCs into groups depending on their potential to volatilize from the wastewaters. In making this classification, Henry's Law, which is valid at very low concentrations, has been used to describe the vapor-liquid equilibrium. But, in reality the concentrations observed in the wastewaters are often too high for Henry's Law to be valid and it is inappropriate to assume that equilibrium has been achieved for every compound.

This project evaluates the volatilization rates, both experimental …