Engineering Commons^™

Novel Investigation Of Catalytic Hydrogenation And Oxidation Of 1,3-Butadiene, Ali M. Alabedkhalil

Theses

The hydrogenation of 1,3 Butadiene (BD) is an important industrial process that is generally used to generate butene, which is a key feedstock to produce a variety of chemicals such as polymers, plastic, and synthetic rubber. This process involves reacting BD with hydrogen using different metallic Ni-based catalysts. In this study, Ni/Al₂O₃ and Ni/Nb₂O5 catalysts were used and investigated to perform the hydrogenation reaction because of their commercial availability, effective hydrogenation activity, and affordability compared to Platinum Group Metal (PGM) catalysts.

The catalytic reactions were conducted using a quartz tube reactor between a temperature range …

Utilizing Date Pits In Microencapsulation: Effect Of Different Variations On Probiotic Survivability Under In Vitro Digestion, Asmaa Samir Al Hamayda

Theses

This work deals with the medicinal use of date pit powder, which turns it from a waste product to a useful stabilizer for the release of beneficial probiotics in the human intestine. The main objective of this work is to encapsulate probiotics with date pit beads and their subsequent release in the human intestine. The beads were formed using gravitational dripping technique, while INFOGEST protocol was used to test the digested beads and the release of viable probiotic cells. For the three date varieties Raziz, Naghal and Khadrawy, it was found that 0.1 g of date pit powder per 0.2 …

Effects Of Wettability, Lithology, And Permeability On The Optimum Slug Size Of Low Salinity Water Flooding In Carbonates: An Experimental Approach, Hala Khaled Hasan Alshadafan

Theses

Low salinity water flooding has attracted academic and industry communities due to its relatively simple and applicable technology. One of the drawbacks of applying the IOR/EOR technique is the lack of the availability of low salinity water in large quantities at the reasonable cost required for a technically and environmentally successful project. To overcome this problem, the industry proposed to use produced water/sea water after dilution, and reverse osmosis filter technology to achieve the required salinity. Both techniques are quite costly and might hinder the project's economic success. Low salinity water as slug size followed by high salinity water was …

Desalination Waste Revitalization Using Carbon Capture: Process Optimization Using Machine Learning, Ahmed Mohamed Elsayed

Theses

Over the next five to ten years, desalination will play an ever-important role in our society. Developing nations will look at desalination from the point of water scarcity, while developed nations will consider the perspective of the Water-Energy-Food nexus. With current technology, for every liter of freshwater produced, one and a half liters is thrown away as waste. This body of research proposes to employ chemical precipitation in ammoniated brine solutions, that have reasonably high ionic concentrations. CO2 absorption in Bubble Column Reactors can reduce sodium ions by precipitating NaHCO3. Also, the absorbed CO2 can reduce chloride ions and induce …

Possible Storage Of Co₂ In Saline Aquifer: Storage Factor Estimation, Sarah Abdul Aziz Al-Tamimi

Theses

The objective of this study is to perform laboratory measurements and a CO₂ underground storage study to cover the knowledge gap on CO₂-Brine relative permeability and assess various variables on the storage of CO₂ in a selected aquifer. Several factors that affect CO₂ storage have been discussed in the literature. These include both macroscopic and microscopic displacement efficiency of brine as a function of CO₂ pore volume injected. It is clear from the literature that there is still more work needed to investigate the effect of various variables such as formation temperature, brine viscosity, and the possible presence of free …

The Effect Of Carbonate Rock Wettability On The Performance Of Low Salinity Water Flooding: An Experimental Approach, Hildah Nantongo

Chemical and Petroleum Engineering Theses

The performance of low salinity waterflooding (LSWF) in different wettability environment is still unclear for the oil industry. The concessions among researchers are that low salinity does not work in water-wet carbonate oil reservoirs. In this project carbonate core flooding experiments on cores with different wettability’s conditions, including water-wet, oil-wet, and intermediate wettability were performed at reservoir conditions of pressure and temperature. Seawater was selected as a base water and its concentration & composition were modified through dilution and/or spiking with sulfate. The base water was diluted with water 10 and 50 times and spiked with sulfate to 2 and …

Developing A New Formula For Predicting Oil Recovery Factor In Water Flooded-Heterogeneous Reservoirs, Mohamed Khaled Aljifri

Theses

In this work, two sets of empirical correlations were developed for predicting the recovery factor (RF) in water-flooded layered oil reservoirs. The first set of these correlations encompasses four key parameters believed to have a significant impact on waterflooding performance, namely, reservoir heterogeneity (permeability variation coefficient), injected water viscosity, permeability anisotropy (ratio of vertical permeability to horizontal permeability), and water injection rate. This first set consists of two expanded forms, one for predicting the RF at water breakthrough time (BT) and the other for predicting the RF at the end of the project (EOP). Out of the aforementioned four key …

Optimization Of Low Salinity Water Flooding In Low Permeability Oil Reservoir Yang Li, Yang Li

Chemical and Petroleum Engineering Theses

In recent decades, the demand of energy is growing sharply. Oil plays a very important role among all of the energy resources. Low permeability oil reservoirs classified as non conventional oil reservoirs and needs special techniques for oil recovery. The primary aim of this study is to select a proper technique for oil recovery of low permeability carbonate oil reservoir. Different carbonated and non-carbonated brines were employed in this project. Formation brine (17500 ppm), carbonate formation brine, sea water, low salinity water, carbonated sea water (50000 ppm), and carbonated low salinity brine (5000 ppm) were used in this work. Core …

Optimization Of A New Array Noise Tool; Analysis & Interpretation Of Case Studies Of Down- Hole Leak Detection, Moustafa Mahmoud Hassan Ismail

Theses

This thesis is concerned with the optimization and analysis of new array noise tools. Various lab and field case studies are analyzed to test the capabilities and determine the optimum operating conditions of the new tool for leak detection purposes. The purpose of this study is to optimize the logging procedure of real-time array noise tool, selecting adequate gain parameters and frequency band in the processing phase, and to analyze the data acquired through multiple labs and field tests. The study methodology involved the following steps:

1. Performing lab and field tests for the tool in a range of different …

Experimental Study Of Low Salinity Water Flooding And Fracturing Effects In Low Permeability Carbonate Reservoir, Benny Arianto Harahap

Theses

In past decades, there were numerous research works demonstrated that salinity alteration of injected water could enhance the oil recovery. Low salinity water (LSW) injection is a type of Enhanced Oil Recovery (EOR) method, which attracts the industrial, and researchers because of its simplicity to use the implications,

Environment-friendly nature, and less cost. In addition to, hydraulic fracturing, also known as hydraulic stimulation, is another EOR method that improves hydrocarbon flow by creating fractures in the Low Permeability Formation (LPF) that connects the reservoir and wellbore. Fractures will increase the permeability of reservoir and give the flow path for hydrocarbon …

Oil Recovery By Surfactant Flooding; Sensitivity Analysis To Technical Parameters And Economic Analysis, Hadel Mohsen Moustafa

Theses

Various enhanced oil recovery methods including miscible gas injection, chemical, thermal and other methods are applied at the third phase of production after the primary and secondary recovery have been exhausted. Surfactant flooding is one of the chemical methods that is capable of recovering more oil by decreasing the IFT and/or wettability alteration.This piece of work aims to asses and select the development options using surfactant process that maximize oil recovery for a synthetic reservoir model by optimizing technical and economic analysis.

Reservoir simulation study using ECLIPSE 100 was used to study the different development options of surfactant flooding applied …

Evaluation Of Smart Water Flooding In A Selected Uae Carbonate Oil Reservoir, Mohammad Jasem Khalifi

Chemical and Petroleum Engineering Theses

Water flooding is by far the most common method of improved oil recovery applied in oil reservoirs. Water is the cheapest source of external energy that has been used over decades in water flooding schemes, provided that the damage does not adversely affect its injectivity. Displacement efficiency of water flooding can be significantly affected by crude oil/water/rock interactions. Historically, some consideration was given to such interactions in the practice of reservoir engineering. In recent years, extensive research in this area has documented that higher oil recoveries can be obtained when low-salinity water is injected in a formation with high salinity …

Contact Angle And Ift Measurements Of Smart Water At Elevated Temperatures And Pressures For Evaluating Wettability In A Selected Carbonate Reservoir In The Uae, Jassim Abubacker Ponnambathayil

Theses

Water flooding has been regarded as a well-known secondary oil recovery method. In the recent years, extensive research on crude oil, brine, and rock systems has acknowledged that the composition of the injected water can change wetting properties of the reservoir during a water flood in a promising way to improve oil recovery. Hence, injection of “smart water” with correct salinity and composition is considered as a tertiary recovery method. The mechanism behind wettability alteration that is promoted by smart water injection has been a topic of discussion in carbonate and sandstone formations. In this work, some key properties of …

Oil Recovery By Polymer Flooding; Sensitivity Analysis To Technical Parameters, Rana Osama Fahmi Saqer

Theses

Numerous enhanced oil recovery techniques including miscible gas injection, chemical, thermal and other methods are applied at the third phase of production after both primary and secondary recovery have been exhausted. Polymer flooding is one of the chemical methods that recover more oil by decreasing the mobility of the system; by increasing the viscosity of the injected water that results in an improvement in the volumetric sweep efficiency.

The objective of this work is to asses and select the development options using polymer process that maximize oil recovery for a synthetic reservoir model where technical parameters are optimized thoroughly.

Reservoir …

Oil Recovery By Flooding; Sensitivity Analysis To Technical Parameters, Rana Osama Fahmi Saqer

Theses

Numerous enhanced oil recovery techniques including miscible gas injection, chemical, thermal and other methods are applied at the third phase of production after both primary and secondary recovery have been exhausted. Polymer flooding is one of the chemical methods that recover more oil by decreasing the mobility of the system; by increasing the viscosity of the injected water that results in an improvement in the volumetric sweep efficiency.

The objective of this work is to asses and select the development options using polymer process that maximize oil recovery for a synthetic reservoir model where technical parameters are optimized thoroughly.

Reservoir …

Enzymatic Production Of Biodiesel From Fats Extracted From Lamb Meat Using Supercritical Co2, Hanifa Easa Taher

Theses

Due to the reduction in fossil fuel reserves and associated environmental impacts from using petroleum fuels, biodiesel has been presented as a feasible alternative because it is sustainable and environmentally friendly. In this study, it is proposed to investigate the feasibility of enzymatic production of biodiesel from waste animal fats using supercritical fluid technology for the extraction and reaction. The operating conditions that resulted in the optimum extraction and biodiesel production yield were identified. To the best of my knowledge of the investigators, the waste animal fat extracted by supercritical CO₂ (SC-CO₂) for the production of biodiesel …

Pvt Study Of Selected Uae Reservoir Fluids, Rashid Sher Mohammad

Theses

Phase behavior modeling in crude oil includes prediction of thermodynamic properties (such as saturation pressure, density, viscosity, thermal conductivity, etc.) for the vapor and liquid phases. The aim of phase behavior modeling is to establish the accuracy and reliability of the developed equation of state model to predict various other fluid phase behavior properties at high pressure and temperature conditions.

In the first part of this work, a new and reliable phase behavior apparatus designed in Brazil was used for the two-stage recombination process and phase behavior measurements. The recombination of the surface sample fluids (first-stage separator gas and stock-tank …

Optimization Of Co2 Wag Processes In A Selected Carbonate Reservoir: Laboratory Study, Mohamed Elwy Abdalla Amin

Theses

Miscible gas flooding using carbon dioxide is currently investigated as a possible EOR process for a number of United Arab Emirates (UAE) reservoirs. The major factors affecting the implementation of CO₂ floods are the availability of CO₂ at economic prices and the net utilization ratio of CO₂ per barrel of additional oil recovered.Minimizing net utilization requires controlling the high mobility ratio which causes lower sweep. To control the mobility ratio, the Water-Alternating CO₂-gas (WAG) technique is proposed.

The objective of this work is to experimentally assess the recovery of oil with CO₂ injection in …

Supercritical Co2 Extraction Of Oil From Henna Flower: Experimental, Mathematical Modeling, And Antioxidant Activity, Bushra Saeed Mohammed Dohai

Theses

Henna is a plant that has been used traditionally for coloring nail, skin, and hair, and as medicinal plant. The supercritical fluid technology offers a considerable promise as extraction media due to its advantages over other conventional extraction techniques. The extraction of volatile components from flowers of henna was studied using supercritical carbon dioxide at temperatures and pressures ranging from 35 to 55°C and 80 to 120 bar, respectively. A maximum extraction yield of 31 % from 2g of henna flowers was obtained at 45 °C and 120 bar. The composition of the extracts was investigated by gas chromatography technique. …

Recovery Of Carbon Dioxide From Flue Gases, Fahad Husain Al-Masabi

Theses

In this thesis, the modeling and simulation of the absorption of dilute CO₂ into falling film of aqueous solutions of a sterically hindered amine, 2-anino-2-methyl-1-propanol (AMP), was carried out using COMSOL Multiphysics Version 3.3. The operating cases were divided in two groups: (1) gas turbine operating cases (CO₂ 3 mol %) and (II) boiler operating cases (CO₂ 8.5 mol %). The key operating parameters for the studied cases are CO₂ partial pressure, operating temperature and amine concentration in the aqueous solution. The simulation focused on the following: (1) CO₂ Loading in aqueous AMP solution; (2) …

Carbon Dioxide Capture From Flue Gases, Mohamed Rashid Al Rashid

Theses

Global warming and climate change are believed to be caused by the greenhouse effect. CO₂ has been regarded as the main contributor to global climate change which directly results in serious environmental problems. Half of the anthropogenic CO₂ emission sources are emitted from the combustion of fossil fuels in industries and power plants worldwide. The absorption behavior of Carbon dioxide from flue gases can be studied using conventional absorber and polymeric hollow fiber membrane contractors. An industrial absorber data was compared with simulated data using hollow fiber membrane contractor using the gPROMs software package. In this analysis, with …

Optimum Non Hydrocarbon Gas Injection Development Process And Ultimate Recovery Maximization., Abdulla A.F. Abed

Theses

A multi layered heterogeneous reservoir was selected for this study. The integrated reservoir characterization model and the pertinent transformed reservoir simulation history matched model were quality assured and quality checked.

The development scheme was identified and selected where the pattern and completion of the wells were defined to fit the heterogeneity of the reservoir characterization model. Lateral and maximum block contact holes were investigated.

The development processes studied were mainly hydrogen sulphide, carbon dioxide, nitrogen and rich hydrocarbon gas. The Water Alternating Gas/ Simultaneous Water Alternating Gas (WAG/SWAG) processes were also assured. In addition to the main gas and WAG/SWAG …

Low Salinity Flooding In A Selected Carbonate Reservoir: Experimental Approach, Mohamed Yehia Mohamed Mahmoud

Theses

Low-salinity water flooding LoSal^TM has been used to improve oil recovery for many decades. Historically, the mechanisms behind this improvement in oil recovery were attributed to the pressure maintenance and displacement of oil by injected water, i.e. physical mechanism. Recently, evidence from laboratory and field tests indicated that water flooding also involves chemical processes and that modifying of the injection brine salinity and its ionic composition can significantly impact the oil recovery. Several theories regarding the mechanism of LoSal^TM flooding have been discussed in the literature. These include interfacial tension reduction, wettability alteration (cation exchange), change in pH …