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Sensitive Detection Of Novel Effects And Characteristic Signal Structure Of Higher Harmonic Detection In Wavelength Modulation Spectroscopy, Mohammad Amir Khan

Electrical & Computer Engineering Theses & Dissertations

We discuss experimental and theoretical results of absorption features of the oxygen A-band transitions when synchronous detection at higher harmonics using Wavelength Modulation Spectroscopy (WMS) is performed. A key aspect of structure higher harmonic detection is discussed. It is shown that the signal magnitude and spectral locations of turning points and zero crossings of WMS signal demonstrate key signatures of collision dynamics of gaseous specie parameters and lineshape parameters. In addition, it is also shown that these salient features provide sensitive probes for any changes in the gas environment or lineshape parameters. We discuss several advantages and subtle physical effects …