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Articles 1 - 7 of 7
Full-Text Articles in Engineering
Electrophoretic Deposition Of Gallium With High Deposition Rate, Hanfei Zhang, Yiping Mao, Sunand Santhanagopalan, Dennis Desheng Meng
Electrophoretic Deposition Of Gallium With High Deposition Rate, Hanfei Zhang, Yiping Mao, Sunand Santhanagopalan, Dennis Desheng Meng
Michigan Tech Publications
In this work, electrophoretic deposition (EPD) is reported to form gallium thin film with high deposition rate and low cost while avoiding the highly toxic chemicals typically used in electroplating. A maximum deposition rate of ~0.6 μm/min, almost one order of magnitude higher than the typical value reported for electroplating, is obtained when employing a set of proper deposition parameters. The thickness of the film is shown to increase with deposition time when sequential deposition is employed. The concentration of Mg(NO3)2, the charging salt, is also found to be a critical factor to control the deposition …
Recent Advances In The Field Of Bionanotechnology: An Insight Into Optoelectric Bacteriorhodopsin, Quantum Dots, And Noble Metal Nanoclusters, Christopher Knoblauch, Mark Griep, Craig Friedrich
Recent Advances In The Field Of Bionanotechnology: An Insight Into Optoelectric Bacteriorhodopsin, Quantum Dots, And Noble Metal Nanoclusters, Christopher Knoblauch, Mark Griep, Craig Friedrich
Michigan Tech Publications
Molecular sensors and molecular electronics are a major component of a recent research area known as bionanotechnology, which merges biology with nanotechnology. This new class of biosensors and bioelectronics has been a subject of intense research over the past decade and has found application in a wide variety of fields. The unique characteristics of these biomolecular transduction systems has been utilized in applications ranging from solar cells and single-electron transistors (SETs) to fluorescent sensors capable of sensitive and selective detection of a wide variety of targets, both organic and inorganic. This review will discuss three major systems in the area …
Separation Of Ash And Sulfur Dioxide During The 2011 Grímsvötn Eruption, E. D. Moxnes, N. I. Kristiansen, A. Stohl, L. Clarisse, A. J. Durant, K. Weber, A. Vogel
Separation Of Ash And Sulfur Dioxide During The 2011 Grímsvötn Eruption, E. D. Moxnes, N. I. Kristiansen, A. Stohl, L. Clarisse, A. J. Durant, K. Weber, A. Vogel
Michigan Tech Publications
Modeling the transport of volcanic ash and gases released during volcanic eruptions is crucially dependent on knowledge of the source term of the eruption, that is, the source strength as a function of altitude and time. For the first time, an inversion method is used to estimate the source terms of both volcanic sulfur dioxide (SO2) and ash. It was applied to the explosive volcanic eruption of Grímsvötn, Iceland, in May 2011. The method uses input from the particle dispersion model, FLEXPART (flexible particle dispersion model), a priori source estimates, and satellite observations of SO2 or ash total columns from …
Absorption And Fluorescence Properties Of Chromophoric Dissolved Organic Matter Of The Eastern Bering Sea In The Summer With Special Reference To The Influence Of A Cold Pool, E. J. D'Sa, J. I. Goes, H. Gomes, C. Mouw
Absorption And Fluorescence Properties Of Chromophoric Dissolved Organic Matter Of The Eastern Bering Sea In The Summer With Special Reference To The Influence Of A Cold Pool, E. J. D'Sa, J. I. Goes, H. Gomes, C. Mouw
Michigan Tech Publications
The absorption and fluorescence properties of chromophoric dissolved organic matter (CDOM) are reported for the inner shelf, slope waters and outer shelf regions of the eastern Bering Sea during the summer of 2008, when a warm, thermally stratified surface mixed layer lay over a cold pool ( < 2 °C) that occupied the entire middle shelf. CDOM absorption at 355 nm (ag355) and its spectral slope (S) in conjunction with excitation-emission matrix (EEM) fluorescence and parallel factor analysis (PARAFAC) revealed large variability in the characteristics of CDOM in different regions of the Bering Sea. PARAFAC analysis aided in the identification of three humic-like (components one, two and five) and two protein-like (a tyrosine-like component three, and a tryptophan-like component four) components. In the extensive shelf region, average absorption coefficients at 355 nm (ag355, mg-1) and DOC concentrations (μM) were highest in the inner shelf (0.342 ± 0.11 mg-1, 92.67 ± 14.60 μM) and lower in the middle (0.226 ± 0.05 mg-1, 78.38 ± 10.64 μM) and outer (0.185 ± 0.05 mg-1, 79.24 ± 18.01 μM) shelves, respectively. DOC concentrations, however were not significantly different, suggesting CDOM sources and sinks to be uncoupled from DOC. Mean spectral slopes S were elevated in the middle shelf (24.38 ± 2.25 μmg-1) especially in the surface waters (26.87 ± 2.39 μmg-1) indicating high rates of photodegradation in the highly stratified surface mixed layer, which intensified northwards in the northern middle shelf likely contributing to greater light penetration and to phytoplankton blooms at deeper depths. The fluorescent humic-like components one, two, and five were most elevated in the inner shelf most likely from riverine inputs. Along the productive "green belt" in the outer shelf/slope region, absorption and fluorescence properties indicated the presence of fresh and degraded autochthonous DOM. Near the Unimak Pass region of the Aleutian Islands, low DOC and ag355 (mean 66.99 ± 7.94 μM; 0.182 ± 0.05 mg-1) and a high S (mean 25.95 ± 1.58 μmg-1) suggested substantial photobleaching of the Alaska Coastal Water, but high intensities of humic-like and protein-like fluorescence suggested sources of fluorescent DOM from coastal runoff and glacier meltwaters during the summer. The spectral slope S vs. ag355 relationship revealed terrestrial and oceanic end members along with intermediate water masses that were modeled using nonlinear regression equations that could allow water mass differentiation based on CDOM optical properties. Spectral slope S was negatively correlated (r2 = 0.79) with apparent oxygen utilization (AOU) for waters extending from the middle shelf into the deep Bering Sea indicating increasing microbial alteration of CDOM with depth. Although our data show that the CDOM photochemical environment of the Bering Sea is complex, our current information on its optical properties will aid in better understanding of the biogeochemical role of CDOM in carbon budgets in relation to the annual sea ice and phytoplankton dynamics, and to improved algorithms of ocean color remote sensing for this region.
Seasonal Variability And Long-Term Evolution Of Tropospheric Composition In The Tropics And Southern Hemisphere, K. M. Wai, S. Wu, A. Kumar, H. Liao
Seasonal Variability And Long-Term Evolution Of Tropospheric Composition In The Tropics And Southern Hemisphere, K. M. Wai, S. Wu, A. Kumar, H. Liao
Michigan Tech Publications
Impacts on tropospheric composition in the tropics and the Southern Hemisphere from biomass burning and other emission sources are studied using a global chemical transport model, surface measurements and satellite retrievals. Seasonal variations in observed CO at remote island sites are examined. Easter Island (eastern Pacific Ocean) is impacted indirectly by the hemispheric zonal transport of CO due to the burning in southern Africa/South America, via the westerlies. An increasing trend in CO by 0.33 ppb yr-1 in the past decade at Ascension Island is attributed to the combined effects of South American/southern Africa burnings and the increases in CH4 …
Effects Of Stratospheric Ozone Recovery On Photochemistry And Ozone Air Quality In The Troposphere, H. Zhang, Shiliang Wu, Y. Huang, Y. Wang
Effects Of Stratospheric Ozone Recovery On Photochemistry And Ozone Air Quality In The Troposphere, H. Zhang, Shiliang Wu, Y. Huang, Y. Wang
Michigan Tech Publications
There has been significant stratospheric ozone depletion since the late 1970s due to ozone-depleting substances (ODSs). With the implementation of the Montreal Protocol and its amendments and adjustments, stratospheric ozone is expected to recover towards its pre-1980 level in the coming decades. In this study, we examine the implications of stratospheric ozone recovery for the tropospheric chemistry and ozone air quality with a global chemical transport model (GEOS-Chem). With a full recovery of the stratospheric ozone, the projected increases in ozone column range from 1% over the low latitudes to more than 10% over the polar regions. The sensitivity factor …
Application Of Sub-Micrometer Vibrations To Mitigate Bacterial Adhesion, Will R. Paces, Hal Holmes, Eli Vlaisavljevich, Katherine L. Snyder, Ee Lim Tan, Rupak Rajachar, Keat Ghee Ong
Application Of Sub-Micrometer Vibrations To Mitigate Bacterial Adhesion, Will R. Paces, Hal Holmes, Eli Vlaisavljevich, Katherine L. Snyder, Ee Lim Tan, Rupak Rajachar, Keat Ghee Ong
Michigan Tech Publications
As a prominent concern regarding implantable devices, eliminating the threat of opportunistic bacterial infection represents a significant benefit to both patient health and device function. Current treatment options focus on chemical approaches to negate bacterial adhesion, however, these methods are in some ways limited. The scope of this study was to assess the efficacy of a novel means of modulating bacterial adhesion through the application of vibrations using magnetoelastic materials. Magnetoelastic materials possess unique magnetostrictive property that can convert a magnetic field stimulus into a mechanical deformation. In vitro experiments demonstrated that vibrational loads generated by the magnetoelastic materials significantly …