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Structural And Diffusional Effects Of Hydrogen In Tini, Alan R. Pelton, Christine Trépanier, Xiao-Yan Gong, Andreas Wick, Katherine C. Chen May 2003

Structural And Diffusional Effects Of Hydrogen In Tini, Alan R. Pelton, Christine Trépanier, Xiao-Yan Gong, Andreas Wick, Katherine C. Chen

Materials Engineering

Hydrogen can be inadvertently added to Nitinol medical devices through electropolishing, caustic cleaning, or exposure to other acidic or basic solutions. Moderately high hydrogen concentrations can lead to embrittlement characterized by lowered ductility and changes in transformation behavior. The purpose of the present report is to discuss recent results on the effects of hydrogen in annealed TiNi. Samples are charged with hydrogen and analyzed with x-ray diffraction; these data indicate that even relatively small amounts of hydrogen can affect the crystal structure. Additions of up to 1000 wppm hydrogen increase the atomic volume by more than 2%, decrease peak intensity …