Engineering Commons^™

Influence Of Adsorbed And Nonadsorbed Polymer Additives On The Viscosity Of Magnesium Oxide Suspensions, Lisa R. Murray, Jason E Bice, Emily G. Soltys, Christopher Perge, Sebastien Manneville, Kendra Erk

School of Materials Engineering Faculty Publications

Adsorbed polymer additives have been employed to reduce water content and improve cement workability through lowering viscosity, but the influence of over-dosage and the presence of nonadsorbed chains have yet to be fully understood. Model magnesium oxide (MgO) suspensions were used to investigate the potential processing effect of “free” chain concentration on cementitious mixtures. The rheological impact of the free chains was measured through incorporation of nonadsorbing poly(ethylene glycol) (PEG) to suspensions stabilized with an adsorbed comb-polymer superplasticizer. Analyses of the rheological data, that showed viscosity-increases and viscosity-reduction due to free PEG concentrations revealed a transition from depletion flocculation to …