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Full-Text Articles in Engineering

Non-Steady-State Approach #11;To Steady-State Kinetics: #11;Case Study Of H2s Oxidation By Oxygen, Andrey N. Zagoruiko, Vladimir V. Mokrinskii Nov 2003

Non-Steady-State Approach #11;To Steady-State Kinetics: #11;Case Study Of H2s Oxidation By Oxygen, Andrey N. Zagoruiko, Vladimir V. Mokrinskii

Andrey N Zagoruiko

Non-steady-state kinetic models may be used for treatment of steady-state kinetic data in case when algebraic elaboration of steady-state kinetic equations is impossible or complicated. The proposed approach includes numerical integration of time-dependent differential equations until achievement of steady-state, resulting in possibility to numerically obtain the rate values for separate reaction stages for given composition of reaction mixture. The obtained non-steady-state model may be then applied in simulation of catalyst pellets and catalyst beds in research and engineering purposes. The case study demonstrates application of such approach for steady-state kinetic description of complicated reaction system of H2S oxidation by oxygen. …


Estimations Of Ammonia And Hydrogen Sulfide Fluxes From Cattle Feedlot Surfaces In Texas High Plains, Bok-Haeng Baek, Jacek A. Koziel, Jarett P. Spinhirne, David B. Parker, Nolan A. Cole Oct 2003

Estimations Of Ammonia And Hydrogen Sulfide Fluxes From Cattle Feedlot Surfaces In Texas High Plains, Bok-Haeng Baek, Jacek A. Koziel, Jarett P. Spinhirne, David B. Parker, Nolan A. Cole

Jacek A. Koziel

A dynamic flow-through chamber system and continuous analyzers were used for on-site measurements of ammonia-nitrogen (NH 3 -N) and hydrogen sulfide-sulfur (H 2 S-S) fluxes from commercial feedlot surfaces in northwestern Texas during two week period in the summer of 2002. Ambient air and air inside chamber temperatures, and manure pack temperature were measured continuously. Manure pack moisture content, pH, and TKN were measured daily to characterize its correlation with NH 3 -N fluxes. The preliminary average NH 3 -N flux from the feedlot surface for the entire measurement period was 1,669 ± 1,212 NH 3 -N µ g/m 2 …


Estimation Of Ammonia And Hydrogen Sulfide Emissions From Cattle Feedlots In Texas, Bok-Haeng Baek, Jacek A. Koziel, Jarett P. Spinhirne, David B. Parker, Nolan A. Cole Jul 2003

Estimation Of Ammonia And Hydrogen Sulfide Emissions From Cattle Feedlots In Texas, Bok-Haeng Baek, Jacek A. Koziel, Jarett P. Spinhirne, David B. Parker, Nolan A. Cole

Jacek A. Koziel

A dynamic flow-through chamber system and continuous analyzers were used for on-site measurements of ammonia-nitrogen (NH 3 -N) and hydrogen sulfide-sulfur (H 2 S-S) fluxes from commercial feedlot surfaces in northwestern Texas during two week period in the summer of 2002. Manure pack moisture content, pH, and TKN were measured daily to characterize its relation with NH 3 -N fluxes. The preliminary average NH 3 -N and H 2 S-S flux from the feedlot surface were 1,669 ± 1,212 NH 3 -N µ g/m 2 /min and 1.884 ± 1.497 H 2 S-S µ g S/m 2 /min. Manure pack …