Engineering Commons^™

Obtaining Some Thermodynamic Parameters Containing Metacrylate And Allyl Groups Containing In Composition, M.I. Abdukakhkharova, A.I. Ismailov, U.M. Mirzaev, R.I. Ismailov

Technical science and innovation

The article discusses the preparation of some thermodynamic parameters characterizing the final product of complex radical polymerization of amino alkyl acrylate derivatives containing both methacrylate and alkyl groups of low molecular weight compounds with electron acceptors - polymerization initiators at temperatures that exclude thermal decomposition of the initiators themselves. The equilibrium constant of the complication reaction and the molar extinction coefficient of the complex were determined by graphically solving the Bеneshe-Hildebrand equation, the heats of complex formation, entropy, Gibbs energy were found, and the elemental composition of low molecular weight and high molecular weight substances was determined. As can be …