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Full-Text Articles in Engineering

Spectrum Sensing, Spectrum Monitoring, And Security In Cognitive Radios, Erfan Soltanmohammadi Jan 2014

Spectrum Sensing, Spectrum Monitoring, And Security In Cognitive Radios, Erfan Soltanmohammadi

LSU Doctoral Dissertations

Spectrum sensing is a key function of cognitive radios and is used to determine whether a primary user is present in the channel or not. In this dissertation, we formulate and solve the generalized likelihood ratio test (GLRT) for spectrum sensing when both primary user transmitter and the secondary user receiver are equipped with multiple antennas. We do not assume any prior information about the channel statistics or the primary user’s signal structure. Two cases are considered when the secondary user is aware of the energy of the noise and when it is not. The final test statistics derived from …


Meso-Scale Analysis Of Deformation Induced Heating In Granular Metalized Explosives By Piston Supported Waves, Sunada Srinath Nagamani Chakravarthy Jan 2014

Meso-Scale Analysis Of Deformation Induced Heating In Granular Metalized Explosives By Piston Supported Waves, Sunada Srinath Nagamani Chakravarthy

LSU Doctoral Dissertations

Shock sensitivity of heterogeneous explosive composites is dependent on the formation of hot-spots which are small regions of elevated temperatures within the material. Changes in the initial meso-structure (i.e. packing density, composition, particle size and shapes) of the explosives can significantly alter the hot-spot fields in the material and thereby affect its shock sensitivity. In this study, an explicit, 2D, Lagrangian finite and discrete element technique is used to numerically simulate the deformation induced heating of granular mixtures of explosive (HMX), and metal (Al) particles due to piston supported uniaxial deformation waves (400 ≤ Up ≤ 800 m/s). A number …


Synthesis And Characterization Of Novel Polyester Scaffolds From Sugarcane Industry By-Products For Use In Skin And Bone Tissue Engineering, Akanksha Kanitkar Jan 2014

Synthesis And Characterization Of Novel Polyester Scaffolds From Sugarcane Industry By-Products For Use In Skin And Bone Tissue Engineering, Akanksha Kanitkar

LSU Doctoral Dissertations

The aim of this work was to synthesize non-toxic, biodegradable polyesters of aconitic acid, cinnamic acid and glycerol from by-products of the sugarcane industry as scaffolds for skin and bone tissue engineering. Utilizing the by-products, molasses and sugarcane bagasse, not only add value to the cane industry, but also paves path for synthesizing novel bio-based materials from the isolated specialty chemicals. Molasses contain an economically recoverable quantity of aconitic acid and its extraction was studied in detail as a part of this work. The yields of recovered aconitic acid varied from 25–69% depending on the extraction conditions. Under all the …


Localization And Security Algorithms For Wireless Sensor Networks And The Usage Of Signals Of Opportunity, Gustavo Andres Chacon Rojas Jan 2014

Localization And Security Algorithms For Wireless Sensor Networks And The Usage Of Signals Of Opportunity, Gustavo Andres Chacon Rojas

LSU Doctoral Dissertations

In this dissertation we consider the problem of localization of wireless devices in environments and applications where GPS (Global Positioning System) is not a viable option. The _x000C_rst part of the dissertation studies a novel positioning system based on narrowband radio frequency (RF) signals of opportunity, and develops near optimum estimation algorithms for localization of a mobile receiver. It is assumed that a reference receiver (RR) with known position is available to aid with the positioning of the mobile receiver (MR). The new positioning system is reminiscent of GPS and involves two similar estimation problems. The _x000C_rst is localization using …


The Effects Of Concurrent Driving And In-Vehicle Tasks: A Multivariate Statistical Analysis Of Driver Distraction In A High-Fidelity Driving Simulator, Julius A. Codjoe Jan 2014

The Effects Of Concurrent Driving And In-Vehicle Tasks: A Multivariate Statistical Analysis Of Driver Distraction In A High-Fidelity Driving Simulator, Julius A. Codjoe

LSU Doctoral Dissertations

Distracted driving continues to remain a cause of concern for a number of bodies, including government agencies, traffic safety advocacy groups and law enforcement agencies, because of its traffic safety risks. The driving simulator continues to be popular with researchers in collecting data on performance variables that provide scientific knowledge of the effects of distracted driving. Several of these performance variables can be used to quantify a single distracting effect, resulting in a multivariate dataset. A literature review of related studies revealed that researchers overwhelmingly use univariate (single and multiple) tests to analyze the resulting dataset. Performing multiple univariate tests …


Electrochemical Reduction Of Co2 On Supported Cu2o Catalysts, Joel Niño Galvez Bugayong Jan 2014

Electrochemical Reduction Of Co2 On Supported Cu2o Catalysts, Joel Niño Galvez Bugayong

LSU Doctoral Dissertations

We have examined Cu-based catalyst materials that enable the conversion of CO2 to useful products such as fuels and chemical feedstocks by electrochemical reduction. In particular, we compared the electrocatalytic activity of supported Cu2O particles prepared using electrodeposition and wet chemical methods. The particles had cubic structure, ranging in size from 40 nm to 900 nm and consisting of low index planes. We observed significantly different product distribution on these catalysts compared to polycrystalline Cu, specifically for methane and ethylene formation. While Cu particles showed higher faradaic efficiency for methane formation compared to ethylene formation, we observed that Cu2O particles …


Rare Earth/Transition Metal Oxides For Syngas Cleanup, Rui Li Jan 2014

Rare Earth/Transition Metal Oxides For Syngas Cleanup, Rui Li

LSU Doctoral Dissertations

Syngas from gasification of biomass or biomass and coal is a potential source of renewable energy. However, byproducts such as H2S and tars must be removed before further utilization or processing of syngas. Rare earth oxides (REOs, e.g., Ce/LaOx (1.7< x <2)) mixed with transition metals (e.g., Mn, Fe) were synthesized by various methods, and in some cases supported on a thermally stable alumina. Both desulfurization and tar reforming experiments were conducted at high temperatures under similar conditions with synthetic effluents in order to achieve better heat integration and higher yield to desired products CO and H2. The sulfur capacities at temperatures from 900-1025 K with air regeneration were measured for repeat cycles until a stable, reversible capacity was obtained. The oxidized and sulfided (reduced) sorbents were characterized by XRD, XANES, XAFS, TPR and BET. Density functional theory calculations were used to aid in interpreting characterization data and in explaining the enhanced S adsorption capacities. The results showed that mixed REOs, such as Ce/Tb, and Ce/La synthesized by a templated sol-gel approach do not have high sulfur capacities. The presence of either CO2 or H2O inhibits the adsorption of H2S. However, addition of Mn to REOs effectively increased the sulfur capacity, and Mn-REO sorbents are regenerable even in the presence of air, although there is some sulfate formation. The formation of elemental sulfur during regeneration could be related to the oxygen vacancies promoted by doping Mn into the ceria lattice. DFT calculations suggested doping Mn into CeO2 decreased the vacancy formation energies and lowered the H2S adsorption energy. In contrast, for MnO-doped REOs supported on ã-Al2O3, although their surface areas remained high after multi-cycle usage, the probable formation of MnAl2O4 as observed by XANES reduces the sulfur capacities. Reforming experiments were carried out using synthetic syngas mixtures with C10H8 as a tar model compound, both with and without H2S. The results showed that CO2 and H2O inhibit the reforming activities to some extent. Fe- or Mn-doped supported REOs are promising tar cleanup catalysts. They exhibited higher sulfur tolerance, less coking, and less methanation than typical Ni-based high temperature reforming catalysts. This behavior is in part attributed to enhanced generation of oxygen vacancies in the doped REOs.


Damage Prediction Of Low-Rise Buildings Under Hurricane Winds, Fang Pan Jan 2014

Damage Prediction Of Low-Rise Buildings Under Hurricane Winds, Fang Pan

LSU Doctoral Dissertations

Low-rise buildings are defined as the buildings with a mean roof height less than the least horizontal dimension and less than 18.3 m in ASCE 7-10. They represent the majority of commercial, residential, and industrial buildings. Approximate 90% of the existing low-rise residential buildings are constructed as wood light-frame buildings that are not fully engineered and thus more vulnerable to extreme wind pressures, wind borne debris and rain water intrusion. The resulting hurricane-induced economic loss is primarily attributed to the insufficient performance of building envelope instead of the catastrophic failure of their main structural system for Category 1 to 4 …


Numerical Investigation Of Cryopreserved Zebrafish Sperm Cell Activation In Microchannels, Thomas Foster Scherr Jan 2014

Numerical Investigation Of Cryopreserved Zebrafish Sperm Cell Activation In Microchannels, Thomas Foster Scherr

LSU Doctoral Dissertations

This aim of this research project is to probe the activation process of zebrafish spermatozoa. Zebrafish are a model species for biological engineering applications, and the cryopreservation of their reproductive cells allows for inexpensive cataloging and maintenance of valuable biological material. Evaluation of cryopreservation protocols for aquatic sperm cells is typically accomplished by motility analysis after subjecting cells to a cryopreservation treatment. In zebrafish sperm cells, motility is initiated when cells come into contact with a hypo-osmotic environment. Subsequent activation analysis is currently done manually and brings with it an inherent difficulty and error. This process is slow and not …


Poroelastic Inhomogeneities: Applications In Reservoir Geomechanics, Houman Bedayat Jan 2014

Poroelastic Inhomogeneities: Applications In Reservoir Geomechanics, Houman Bedayat

LSU Doctoral Dissertations

The scarce amount of conventional hydrocarbon reservoirs and increase of fuel consumption in the world have made production from unconventional hydrocarbon resources inevitable. Because of the low permeability of unconventional formations, fractures are the main paths for the fluid to flow. Therefore, detailed knowledge of the size, orientation, and permeability of the fracture systems are essential for reservoir engineers. Permeability of the fractures is function of their volume and opening, and stress and fluid pore pressure distribution in the formation. Since reservoir pressure may change over the production life of the reservoir, studying stress redistribution and mechanical behavior of the …


Evaluation Of Triploid Oysters As A Tool To Assess Short- And Long-Term Seafood Contamination Of Oil Spill-Impacted Areas, Martin Scott Miles Jan 2014

Evaluation Of Triploid Oysters As A Tool To Assess Short- And Long-Term Seafood Contamination Of Oil Spill-Impacted Areas, Martin Scott Miles

LSU Doctoral Dissertations

Many of the organic components of oil have the capacity to persist in the environment, bioaccumulate in tissues, and are toxic to surrounding organisms. Since the early 1970s, environmental assessment programs have utilized bivalves as monitoring tools of chemical contaminants in the marine environment. Because of their sedentary and filter-feeding habit (bioaccumulation), mussels and oysters been employed as sentinel organisms in environmental quality monitoring studies in coastal ecosystems. The use of indigenous (diploid) bivalves for biomonitoring water quality is limited during the summer months due to high stress and changes in biochemical composition induced by reproductive development. In this work …


Tomographic Imaging Of Combustion Zones Using Tunable Diode Laser Absorption Spectroscopy (Tdlas), Avishek Guha Jan 2014

Tomographic Imaging Of Combustion Zones Using Tunable Diode Laser Absorption Spectroscopy (Tdlas), Avishek Guha

LSU Doctoral Dissertations

This work concentrates on enabling the usage of a specific variant of tunable diode laser absorption spectroscopy (abbr. TDLAS) for tomogaphically reconstructing spatially varying temperature and concentrations of gases with as few reconstruction artifacts as possible. The specific variant of TDLAS used here is known as wavelength modulation with second harmonic detection (abbr. WMS-2f) which uses the wavelength dependent absorbance information of two different spectroscopic transitions to determine temperature and concentration values. Traditionally, WMS-2f has generally been applied to domains where temperature although unknown, was spatially largely invariant while concentration was constant and known to a reasonable approximation (_x0006_+/- 10% …


Applications Of Cfd Simulations On Studying The Multiphase Flow In Microfluidic Devices, Yuehao Li Jan 2014

Applications Of Cfd Simulations On Studying The Multiphase Flow In Microfluidic Devices, Yuehao Li

LSU Doctoral Dissertations

Microfluidics has been extensively investigated as a unique platform to synthesize nanoparticles with desired properties, e.g., size and morphology. Compared to the conventional batch reactors, wet-chemical synthesis using continuous flow microfluidics provides better control over addition of reagents, heat and mass transfer, and reproducibility. Recently, millifluidics has emerged as an alternative since it offers similar control as microfluidics. With its dimensions scaled up to millimeter size, millifluidics saves fabrication efforts and potentially paves the way for industrial applications. Good designs and manipulations of microfluidic and millifluidic devices rely on solid understanding of fluid dynamics. Fluid flow plays an important role …


New Approaches To Smart Grid Security With Scada Systems, Bixiang Tang Jan 2014

New Approaches To Smart Grid Security With Scada Systems, Bixiang Tang

LSU Doctoral Dissertations

The use of information technology in electric power grid introduces the vulnerability problem looming the future smart grid. The supervisory control and data acquisition (SCADA)is the first defense, which itself is undermined by potential malicious attacks. This dissertation studies two particular security threats facing the smart grid and SCADA systems: the unobservable attack and the replay attack. The former is well known in fault detection of the power grid and has received renewed interest in the past a few years, while the latter is motivated by the Stuxnet worm allegedly used against the nuclear facilities in Iran. For unobservable attacks, …


Advanced And Novel Modeling Techniques For Simulation, Optimization And Monitoring Chemical Engineering Tasks With Refinery And Petrochemical Unit Applications, Gregory M. Robertson Jan 2014

Advanced And Novel Modeling Techniques For Simulation, Optimization And Monitoring Chemical Engineering Tasks With Refinery And Petrochemical Unit Applications, Gregory M. Robertson

LSU Doctoral Dissertations

Engineers predict, optimize, and monitor processes to improve safety and profitability. Models automate these tasks and determine precise solutions. This research studies and applies advanced and novel modeling techniques to automate and aid engineering decision-making. Advancements in computational ability have improved modeling software’s ability to mimic industrial problems. Simulations are increasingly used to explore new operating regimes and design new processes. In this work, we present a methodology for creating structured mathematical models, useful tips to simplify models, and a novel repair method to improve convergence by populating quality initial conditions for the simulation’s solver. A crude oil refinery application …


Piezoelectric Based Energy Harvesting On Low Frequency Vibrations Of Civil Infrastructures, Ye Zhang Jan 2014

Piezoelectric Based Energy Harvesting On Low Frequency Vibrations Of Civil Infrastructures, Ye Zhang

LSU Doctoral Dissertations

Piezoelectric-based energy harvesting is an efficient way to convert ambient vibration energy into usable electric energy. The piezoelectric harvester can work as a sustainable and green power source for different electric devices such as sensors and implanted medical devices. However, its application on civil infrastructures has not been fully studied yet. This dissertation aimed to study and improve the piezoelectric-based energy harvesting on civil infrastructures, especially on bridge structures. To reach the objective, a more accurate model for piezoelectric composite beams was built first, which can be adopted for the modeling of different kinds of energy harvesters. The model includes …


Novel Syntheses And Surface Modifications Of Electrode Materials For Superior Lithium-Ion Batteries, Jianqing Zhao Jan 2014

Novel Syntheses And Surface Modifications Of Electrode Materials For Superior Lithium-Ion Batteries, Jianqing Zhao

LSU Doctoral Dissertations

Rechargeable lithium-ion battery is one of the most promising energy conversion and storage systems that offers high energy and powder densities, long service life and assuring safety. Performance of lithium-ion batteries crucially relies on electrochemical characteristics of electrode materials, i.e., anode and cathode materials. This dissertation work aims at developing novel electrode materials with high capacity, excellent cycling stability and remarkable rate capability for next-generation lithium-ion batteries. The effects of surface modifications for LiMn2O4 cathode materials are studied by depositing ultrathin conformal amphoteric oxides via atomic layer deposition (ALD). In the case of ZnO coating, the thickness of ZnO ALD …


Image-Based Pore-Scale Modeling Of Inertial Flow In Porous Media And Propped Fractures, Yijie Shen Jan 2014

Image-Based Pore-Scale Modeling Of Inertial Flow In Porous Media And Propped Fractures, Yijie Shen

LSU Doctoral Dissertations

Non-Darcy flow is often observed near wellbores and in hydraulic fractures where relatively high velocities occur. Quantifying additional pressure drop caused by non-Darcy flow and fundamentally understanding the pore-scale inertial flow is important to oil and gas production in hydraulic fractures. Image-based pore-scale modeling is a powerful approach to obtain macroscopic transport properties of porous media, which are traditionally obtained from experiments and understand the relationship between fluid dynamics with complex pore geometries. In image-based modeling, flow simulations are conducted based on pore structures of real porous media from X-ray computed tomographic images. Rigorous pore-scale finite element modeling using unstructured …


Continuous Reservoir Modeling Updating By Integrating Experimental Data Using An Ensemble Kalman Filter, Ting Sun Jan 2014

Continuous Reservoir Modeling Updating By Integrating Experimental Data Using An Ensemble Kalman Filter, Ting Sun

LSU Doctoral Dissertations

The continuous researvoir model updating is widely used to calibrate reservoir simulation models to production data, but many challenges remain. First, few real field data are available to test the new history matching method, and most of the data sets are synthetic cases. Second, computational cost may be high when using non-Gaussian priors or nonlinear models. Third, with large complex models, the simulation runs and history matching method require huge memory allocations. This dissertation achieves a continuous reservoir model updating workflow with a meter-scale , two-phase flow experiment. Both production and seismic data are collected in the experiment. Because the …


Catalytic Active Site, Mechanistic And Kinetic Studies Of Dry (Co2) Reforming Of Methane Over Lanthanum Zirconate (La2zr2o7) Pyrochlores, Devendra Pakhare Jan 2014

Catalytic Active Site, Mechanistic And Kinetic Studies Of Dry (Co2) Reforming Of Methane Over Lanthanum Zirconate (La2zr2o7) Pyrochlores, Devendra Pakhare

LSU Doctoral Dissertations

Dry (CO2) reforming of CH4 (DRM) produces commercially important synthesis gas (H2 and CO) with H2/CO ≤ 1, which can be used for synthesis of higher alkanes and oxygenates. DRM is highly endothermic and requires temperatures as high as 800°C-1000°C to attain high equilibrium conversions. A major problem associated with DRM is catalyst deactivation due to carbon deposition. Thus it is imperative that the catalyst used for DRM must resist deactivation due to sintering and carbon deposition. DRM is well studied in the literature over various catalysts, however, there is no literature, except the Ashcroft (1993) article, for DRM over …


Energy And Thermodynamically Based Approaches For Analysis Of Damage In Contact Problems, Afshin Babaie Aghdam Jan 2014

Energy And Thermodynamically Based Approaches For Analysis Of Damage In Contact Problems, Afshin Babaie Aghdam

LSU Doctoral Dissertations

A novel methodology for analysis of damage in contact problems in presented. Two important categories of contact damage are studied, namely crack nucleation and adhesive wear. The proposed methodology is primarily based on the laws of energy and thermodynamics, and as such offers great advantages by unifying the analysis of damage in a variety of contact configurations. Crack nucleation is the first damage type analyzed. For this purpose, the line-contact fretting configuration is chosen. A thermodynamically-based continuum damage mechanics (CDM) approach is employed. Intense stress gradients in the contact region are found to be highly influential in the crack nucleation …


Novel Nanostructured Titania And Titania Nanocomposites For Photovoltaics And Photocatalysis, Xinning Luan Jan 2014

Novel Nanostructured Titania And Titania Nanocomposites For Photovoltaics And Photocatalysis, Xinning Luan

LSU Doctoral Dissertations

With the consumption of energy continually increasing around the world and the main source of this energy, fossil fuels, slowly being depleted, the need for alternate sources of energy is becoming more and more pertinent. Demand for solar energy has experienced exponential increase over the last decade. Nanostructured TiO2 has attracted significant attention due to its nontoxicity, low cost and wide applications in photovoltaics and photocatalysis. This research is focused on novel synthesis and surface modification of TiO2 nanotube arrays for applications in advanced dye-sensitized solar cells (DSSCs) and efficient photocatalysis. The first part of this work entails fast synthesis …


Multiscale Estimation Of Inertial Effects For Frac-Pack Completed Gas Reservoirs, Sultan Anbar Jan 2014

Multiscale Estimation Of Inertial Effects For Frac-Pack Completed Gas Reservoirs, Sultan Anbar

LSU Doctoral Dissertations

Accurate estimation of production from frac-pack completed gas wells requires reliable estimation of flow properties from reservoir rocks and proppants. This study is composed of three parts: core-scale, pore-scale and reservoir-scale analyses of this problem. In the core-scale analysis, simultaneous estimation of permeability, non-Darcy, and Klinkenberg coefficients of reservoir rock is conducted from steady-state and pulse-decay experiments. Confidence intervals of the estimated parameters are determined from the Bootstrap method. The duration of pulse-decay experiments has a large impact on confidence intervals; therefore, correlations are developed to estimate the experimental duration for both 1-tank and 2-tank set-ups from the core properties …


A System Approach To Investing In Uncertain Markets, Iman Khademi Jan 2014

A System Approach To Investing In Uncertain Markets, Iman Khademi

LSU Doctoral Dissertations

We consider the problem of trend-following in US stock market and propose a combined economic and technical model to approach this problem. A bank of linear and nonlinear, discrete-time, low-pass filters with different sampling rates is used to generate timing signals for US stock market indexes such as NASDAQ Composite and S&P 500. These timing signals help us find the appropriate times to step in or out of the market. Back-testing and real-time implementation results along with the risk analysis validate our model. According to the trend of the market, we may adopt a long or short position. If we …


The Effects Of Asymmetric Micro Ratchets On Pool Boiling Performance, Lance Austin Brumfield Jan 2014

The Effects Of Asymmetric Micro Ratchets On Pool Boiling Performance, Lance Austin Brumfield

LSU Doctoral Dissertations

Nucleate boiling is an attractive method for achieving high heat flux at low superheat temperatures. It is frequently used for industrial applications such as heat exchangers and is being considered to cool advanced central processing units (CPU) which produce heat fluxes on the order of 1 MW/m2 and are becoming increasingly less efficient to cool via forced conduction of air. The issue with implementing nucleate boiling as a cooling mechanism lies in the difficulty of quantifying the numerous and complex mechanisms which control the process. A comprehensive nucleate boiling model has yet to be formulated and will be required in …


Polycyclic Aromatic Hydrocarbon Degradation In Tidally Influenced Coastal Marsh Wetland Studied In Laboratory Mesocosm, Doorce S. Batubara Jan 2014

Polycyclic Aromatic Hydrocarbon Degradation In Tidally Influenced Coastal Marsh Wetland Studied In Laboratory Mesocosm, Doorce S. Batubara

LSU Doctoral Dissertations

The compact mesocosm which was designed for a laboratory scale was used for the kinetic study of refractory organic compounds in a tidally influenced coastal marsh wetland soil. The tidal cycles were controlled pneumatically using an air chamber inside the mesocosm tank. Phenanthrene as the test compound showed that its degradation in the intertidal wetland soil was faster than that in the subtidal wetland soil. Oxygen resupply during the tidal cycles to the intertidal wetland soil would enhance the degradation. Comparison of degradation rates of phenanthrene (Phe), pyrene (Pyr), and benzo[e]pyrene (BeP) were also studied using the mesocosm. The degradation …


Analysis And Modeling Of Manual Traffic Control For Signalized Intersections, Scott Alexander Skip Parr Jan 2014

Analysis And Modeling Of Manual Traffic Control For Signalized Intersections, Scott Alexander Skip Parr

LSU Doctoral Dissertations

Manual traffic control is a common intersection control strategy in which trained personnel, typically police law enforcement officers, allocate intersection right-of-way to approaching vehicles. Manual intersection control is a key part of managing traffic during emergencies and planned special events. It is widely assumed that the flow of traffic through intersections can be greatly improved by the direction given from police officers who can observe and respond to change conditions by allocating green time to the approaches that require it the most. Despite the long history of manual traffic control throughout the world and its assumed effectiveness, there have been …


Advanced Statistical Signal Processing Methods In Sensing, Detection, And Estimation For Communication Applications, Hongting Zhang Jan 2014

Advanced Statistical Signal Processing Methods In Sensing, Detection, And Estimation For Communication Applications, Hongting Zhang

LSU Doctoral Dissertations

The applications of wireless communications and digital signal processing have dramatically changed the way we live, work, and learn over decades. The requirement of higher throughput and ubiquitous connectivity for wireless communication systems has become prevalent nowadays. Signal sensing, detection and estimation have been prevalent in signal processing and communications for many years. The relevant studies deal with the processing of information-bearing signals for the purpose of information extraction. Nevertheless, new robust and efficient signal sensing, detection and estimation techniques are still in demand since there emerge more and more practical applications which rely on them. In this dissertation work, …


Crack Self-Healing In Sic/Spinel Nanocomposite, Fariborz Tavangarian Jan 2014

Crack Self-Healing In Sic/Spinel Nanocomposite, Fariborz Tavangarian

LSU Doctoral Dissertations

Spinel is one of the best known and widely used ceramic materials. It has good thermal shock resistance, high chemical inertness in both acidic and basic environments, excellent optical and dielectric properties, high strength at both elevated and normal temperatures, and has no phase transition up to the melting temperature (2135°C). Spinel is used in the metallurgical, electrochemical, and chemical industrial fields. It has also found some applications in dentistry, catalyst supports, humidity sensors, reinforcing fibers, photoluminescent materials, etc. One of the limitations of spinel ceramic is its brittleness. Furthermore, at high temperature applications, a rapid heating or cooling can …


Utilization Of Carbon Nanofibers Grown On Glass Microballoons (Nmbs) In Point-Of-Care Diagnostic Devices, Emmanuel Gikunoo Jan 2014

Utilization Of Carbon Nanofibers Grown On Glass Microballoons (Nmbs) In Point-Of-Care Diagnostic Devices, Emmanuel Gikunoo

LSU Doctoral Dissertations

The use of point-of-care (POC) diagnostic systems holds great promise for the early detection of various diseases. However, detection limits for commercially available POC systems have not been able to meet the lower cutoffs offered by the specialized laboratory testing methods. Research into the use of carbon nanofibers (CNFs) grown on glass microballoons in POC devices was studied. The growth of several millions of the CNFs on each microballoon (NMBs) presented a large surface area with high probability of capturing minute concentrations of biospecies. Functionalization of the NMBs with the carboxyl group needed for biospecies conjugation was achieved by air …